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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(3,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-propylpropanamide —— C18H27NO3S2
    3-(3,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-propylpropanamide
    —— [(2S)-oxan-2-yl]methyl 3-(3,4-dimethylphenyl)sulfanylpropanoate —— C17H24O3S
    [(2S)-oxan-2-yl]methyl 3-(3,4-dimethylphenyl)sulfanylpropanoate
    —— N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-2-pyrimidin-2-ylsulfanylacetamide —— C12H12N4OS2
    N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-2-pyrimidin-2-ylsulfanylacetamide
    —— 1-amino-3-[(Z)-octan-2-ylideneamino]thiourea —— C9H20N4S
    1-amino-3-[(Z)-octan-2-ylideneamino]thiourea
    —— 1-amino-3-[(Z)-heptan-2-ylideneamino]thiourea —— C8H18N4S
    1-amino-3-[(Z)-heptan-2-ylideneamino]thiourea
    —— (NZ)-N-(3,3-dimethyl-1-methylsulfonylbutan-2-ylidene)hydroxylamine —— C7H15NO3S
    (NZ)-N-(3,3-dimethyl-1-methylsulfonylbutan-2-ylidene)hydroxylamine
    —— 3-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C17H17ClN2OS2
    3-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— (2R)-2-benzylsulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C18H20N2OS2
    (2R)-2-benzylsulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— (2S)-2-benzylsulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C18H20N2OS2
    (2S)-2-benzylsulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-3-phenylsulfanylpropanamide —— C16H14ClFN2OS
    N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-3-phenylsulfanylpropanamide
    —— N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-3-phenylsulfanylpropanamide —— C15H16N2OS2
    N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-3-phenylsulfanylpropanamide
    —— N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-3-(4-chlorophenyl)sulfanylpropanamide —— C16H13Cl2FN2OS
    N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-3-(4-chlorophenyl)sulfanylpropanamide
    —— N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-phenylsulfanylpropanamide —— C17H18N2OS2
    N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-phenylsulfanylpropanamide
    —— N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-3-phenylsulfanylpropanamide —— C17H17FN2OS
    N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-3-phenylsulfanylpropanamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]propanamide —— C17H16ClFN2OS
    3-(4-chlorophenyl)sulfanyl-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]propanamide
    —— N-[(Z)-(2-bromophenyl)methylideneamino]-3-phenylsulfanylpropanamide —— C16H15BrN2OS
    N-[(Z)-(2-bromophenyl)methylideneamino]-3-phenylsulfanylpropanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]propanamide —— C15H15ClN2OS2
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]propanamide
    —— (2S)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C16H14ClFN2OS
    (2S)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— 2-[(3-bromophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C17H17BrN2OS2
    2-[(3-bromophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— (2R)-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-2-phenylsulfanylpropanamide —— C15H16N2OS2
    (2R)-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-2-phenylsulfanylpropanamide
    —— (2S)-N-[(Z)-(2-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C16H15BrN2OS
    (2S)-N-[(Z)-(2-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— (2S)-N-[(Z)-(2-bromophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide —— C16H14BrClN2OS
    (2S)-N-[(Z)-(2-bromophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide
    —— (2R)-N-[(Z)-(2-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C16H15BrN2OS
    (2R)-N-[(Z)-(2-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]propanamide —— C17H16ClFN2OS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]propanamide
    —— N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylsulfanylacetamide —— C16H16N2OS2
    N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylsulfanylacetamide
    —— (2S)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C17H18N2OS2
    (2S)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— (2S)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide —— C16H13Cl2FN2OS
    (2S)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C17H17ClN2OS2
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-phenylsulfanylacetamide —— C16H15FN2OS
    N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-phenylsulfanylacetamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C17H17ClN2OS2
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]propanamide —— C17H16ClFN2OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]propanamide
    —— 2-benzylsulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C17H18N2OS2
    2-benzylsulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-2-phenylsulfanylacetamide —— C14H14N2OS2
    N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-2-phenylsulfanylacetamide
    —— (2R)-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-phenylsulfanylpropanamide —— C17H17FN2OS
    (2R)-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-phenylsulfanylpropanamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]propanamide —— C15H15ClN2OS2
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]propanamide
    —— 2-[(4-methylphenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C18H20N2OS2
    2-[(4-methylphenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— (2R)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C16H14ClFN2OS
    (2R)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— (2R)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide —— C16H13Cl2FN2OS
    (2R)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide
    —— (2S)-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-phenylsulfanylpropanamide —— C17H17FN2OS
    (2S)-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-phenylsulfanylpropanamide
    —— (2R)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C17H18N2OS2
    (2R)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-phenylsulfanylacetamide —— C15H12ClFN2OS
    N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-phenylsulfanylacetamide
    —— 2-[(2-methylphenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C18H20N2OS2
    2-[(2-methylphenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— (2S)-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-2-phenylsulfanylpropanamide —— C15H16N2OS2
    (2S)-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]-2-phenylsulfanylpropanamide
    —— 2-[(2-bromophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C17H17BrN2OS2
    2-[(2-bromophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— (2R)-N-[(Z)-(2-bromophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide —— C16H14BrClN2OS
    (2R)-N-[(Z)-(2-bromophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide
    —— 2-[(4-chlorophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C17H17ClN2OS2
    2-[(4-chlorophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 2-[(3-chlorophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C17H17ClN2OS2
    2-[(3-chlorophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 2-[(2-chlorophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C17H17ClN2OS2
    2-[(2-chlorophenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 2-[(3,5-dimethylphenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C19H22N2OS2
    2-[(3,5-dimethylphenyl)methylsulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— (4R)-4-hydroxy-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-4-phenylbutanamide —— C18H20N2O2S
    (4R)-4-hydroxy-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-4-phenylbutanamide