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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (5E)-2-methyl-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1H-pyrrole-3-carboxylate —— C15H15NO3S
    methyl (5E)-2-methyl-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1H-pyrrole-3-carboxylate
    —— 6-[2-[[(E)-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino]phenyl]-3-methylsulfanyl-2H-1,2,4-triazin-5-one —— C21H18N6O2S
    6-[2-[[(E)-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino]phenyl]-3-methylsulfanyl-2H-1,2,4-triazin-5-one
    —— (Z)-2-(1H-benzimidazol-2-yl)-3-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]prop-2-enenitrile —— C20H11BrClN3OS
    (Z)-2-(1H-benzimidazol-2-yl)-3-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]prop-2-enenitrile
    —— Octane-1,6,7,7-tetrathiol —— C8H18S4
    Octane-1,6,7,7-tetrathiol
    —— 3-(Cyclopenten-1-ylsulfinyl)propan-1-amine —— C8H15NOS
    3-(Cyclopenten-1-ylsulfinyl)propan-1-amine
    —— 1-(2-Methylcyclopropyl)ethane-1-thiol —— C6H12S
    1-(2-Methylcyclopropyl)ethane-1-thiol
    —— [Methanethioyl(methyl)amino] ethylsulfanylformate —— C5H9NO2S2
    [Methanethioyl(methyl)amino] ethylsulfanylformate
    —— 3-Methylazapentane-1,5-dithiol —— C5H13NS2
    3-Methylazapentane-1,5-dithiol
    —— 3,4-dihydro-2H-pyrido[3,2-b][1,4]thiazine;ethane —— C9H14N2S
    3,4-dihydro-2H-pyrido[3,2-b][1,4]thiazine;ethane
    —— 6-Methyl-2-methylsulfanylnon-1-ene —— C11H22S
    6-Methyl-2-methylsulfanylnon-1-ene
    —— 2-[3-(2,3-Dimethylpentan-3-yloxy)propoxy]ethanethial —— C12H24O2S
    2-[3-(2,3-Dimethylpentan-3-yloxy)propoxy]ethanethial
    —— 4-[[6-(4-fluorophenyl)-7,8-dihydro-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulfanyl]-N-(2-methylbutyl)-1,3-benzothiazol-2-amine —— C23H23FN6S2
    4-[[6-(4-fluorophenyl)-7,8-dihydro-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulfanyl]-N-(2-methylbutyl)-1,3-benzothiazol-2-amine
    —— (6Z)-5-imino-6-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-2-(propan-2-yl)-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C20H18N4O2S2
    (6Z)-5-imino-6-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-2-(propan-2-yl)-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— N-methyl-3,3-bis[(4-methylphenyl)sulfanyl]propanamide —— C18H21NOS2
    N-methyl-3,3-bis[(4-methylphenyl)sulfanyl]propanamide
    —— 1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidine-4-carboximidamide —— C17H20N6S
    1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidine-4-carboximidamide
    —— N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-(thiophen-2-yl)acetohydrazide —— C14H14N2OS2
    N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-(thiophen-2-yl)acetohydrazide
    —— 2-((4,6-Dimethyl-2-pyrimidinyl)thio)N'-((3-ME-2-thienyl)methylene)acetohydrazide —— C14H16N4OS2
    2-((4,6-Dimethyl-2-pyrimidinyl)thio)N'-((3-ME-2-thienyl)methylene)acetohydrazide
    —— Ethane;2,2,3,3,4-pentamethyl-1-benzothiophene-5-carboxylic acid —— C16H24O2S
    Ethane;2,2,3,3,4-pentamethyl-1-benzothiophene-5-carboxylic acid
    —— 2-[(4-Fluorophenyl)methylsulfanyl]-5-methylsulfanylpyrimidine —— C12H11FN2S2
    2-[(4-Fluorophenyl)methylsulfanyl]-5-methylsulfanylpyrimidine
    —— Methyl(tripentyl)-lambda4-sulfane —— C16H36S
    Methyl(tripentyl)-lambda4-sulfane
    —— 2-[2-[4-[5-(Cyclohexa-1,3-dien-1-ylmethyl)-1,4-dioxin-2-yl]piperazin-1-yl]ethylsulfanyl]-4-methoxypyridine-3-carbonitrile —— C24H28N4O3S
    2-[2-[4-[5-(Cyclohexa-1,3-dien-1-ylmethyl)-1,4-dioxin-2-yl]piperazin-1-yl]ethylsulfanyl]-4-methoxypyridine-3-carbonitrile
    —— Hexane-1,2,3,3,4,4-hexathiol —— C6H14S6
    Hexane-1,2,3,3,4,4-hexathiol
    —— 4,6-Dimethyl-2-[[3-(2-methylpropyl)imidazol-4-yl]methylsulfanyl]pyrimidine —— C14H20N4S
    4,6-Dimethyl-2-[[3-(2-methylpropyl)imidazol-4-yl]methylsulfanyl]pyrimidine
    —— 2-Propyl-3-sulfanylcyclopropane-1-thione —— C6H10S2
    2-Propyl-3-sulfanylcyclopropane-1-thione
    —— Butane;1-(methylsulfanylmethylsulfanyl)butane —— C10H24S2
    Butane;1-(methylsulfanylmethylsulfanyl)butane
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-bromophenyl)methanimine —— C16H13BrN4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-bromophenyl)methanimine
    —— ethyl (2Z)-2-[(4-hydroxyphenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H22N2O4S2
    ethyl (2Z)-2-[(4-hydroxyphenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 3-Sulfanyloctadecan-1-ol —— C18H38OS
    3-Sulfanyloctadecan-1-ol
    —— 3-(2-bromoethyl)-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine —— C15H17BrN5O2S+
    3-(2-bromoethyl)-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine
    —— 4-(4-Methylsulfanylphenyl)pentan-2-yl formate —— C13H18O2S
    4-(4-Methylsulfanylphenyl)pentan-2-yl formate
    —— 1,3-Bis[4-(4-pyridyl)pyrimidin-2-ylsulfanyl]propane —— C21H18N6S2
    1,3-Bis[4-(4-pyridyl)pyrimidin-2-ylsulfanyl]propane
    —— (2R)-2-hydroxy-4-phenylsulfanylbutanenitrile —— C10H11NOS
    (2R)-2-hydroxy-4-phenylsulfanylbutanenitrile
    —— 2-Tert-butyl-1,1-dioxo-5-phenyl-4-(3-phenylsulfanylpropylimino)-1,2-thiazolidin-3-one —— C22H26N2O3S2
    2-Tert-butyl-1,1-dioxo-5-phenyl-4-(3-phenylsulfanylpropylimino)-1,2-thiazolidin-3-one
    —— N-[1-(2-chloro-3-pyridyl)-3-(4-fluorophenylthio)-2-propenylidene]-4-methylaniline 1140915-80-5 C21H16ClFN2S
    N-[1-(2-chloro-3-pyridyl)-3-(4-fluorophenylthio)-2-propenylidene]-4-methylaniline
    —— N-[4-[4-[(1-amino-3-iminobutylidene)amino]-6-(4-ethyl-4-hydroxypiperidin-1-yl)pyrimidin-2-yl]sulfanylphenyl]propanamide —— C24H33N7O2S
    N-[4-[4-[(1-amino-3-iminobutylidene)amino]-6-(4-ethyl-4-hydroxypiperidin-1-yl)pyrimidin-2-yl]sulfanylphenyl]propanamide
    —— Oxo-propyl-propylidyne-lambda6-sulfane —— C6H12OS
    Oxo-propyl-propylidyne-lambda6-sulfane
    —— Ethyl 2-(6-chloro-5-cyano-1-methyl-2-methylsulfanylpyrimidin-1-ium-4-yl)sulfanylacetate —— C11H13ClN3O2S2+
    Ethyl 2-(6-chloro-5-cyano-1-methyl-2-methylsulfanylpyrimidin-1-ium-4-yl)sulfanylacetate
    —— 3-(3-Methylbut-1-en-2-ylsulfanyl)pent-2-ene —— C10H18S
    3-(3-Methylbut-1-en-2-ylsulfanyl)pent-2-ene
    —— 4-Ethyl-3-methyl-1-methylsulfanyldodecane —— C16H34S
    4-Ethyl-3-methyl-1-methylsulfanyldodecane
    —— 3-ethyl-2-[[7-[[3-ethyl-5-[(3-ethyl-2,4-dihydroimidazol-2-yl)sulfanyl]-1,3-benzothiazol-3-ium-2-yl]methylidene]-4,4a,5,6-tetrahydro-3H-naphthalen-2-yl]methylidene]-5-(1-ethylimidazol-2-yl)sulfanyl-1,3-benzothiazole —— C40H45N6S4+
    3-ethyl-2-[[7-[[3-ethyl-5-[(3-ethyl-2,4-dihydroimidazol-2-yl)sulfanyl]-1,3-benzothiazol-3-ium-2-yl]methylidene]-4,4a,5,6-tetrahydro-3H-naphthalen-2-yl]methylidene]-5-(1-ethylimidazol-2-yl)sulfanyl-1,3-benzothiazole
    —— O-(3-methyl-4-oxopentan-2-yl) N,N-dimethylcarbamothioate —— C9H17NO2S
    O-(3-methyl-4-oxopentan-2-yl) N,N-dimethylcarbamothioate
    —— (2,2-dimethyl-3-methylsulfonylpropyl) N-tert-butylcarbamate —— C11H23NO4S
    (2,2-dimethyl-3-methylsulfonylpropyl) N-tert-butylcarbamate
    —— 1,1,1-Trifluoro-2-methyl-4-methylsulfanylbut-2-ene —— C6H9F3S
    1,1,1-Trifluoro-2-methyl-4-methylsulfanylbut-2-ene
    —— 2-Methylsulfanylethylcyclodecapentaene —— C13H16S
    2-Methylsulfanylethylcyclodecapentaene
    —— 3-Methyl-4,4-dioxo-1-oxa-4lambda6-thiaspiro[4.5]decan-2-one —— C9H14O4S
    3-Methyl-4,4-dioxo-1-oxa-4lambda6-thiaspiro[4.5]decan-2-one
    —— N-methyl-N-(3-methylbutylsulfanylmethyl)propan-1-amine —— C10H23NS
    N-methyl-N-(3-methylbutylsulfanylmethyl)propan-1-amine
    —— 2-[2-phenyl-1-(1,2,5-thiadiazol-3-ylamino)ethylidene]-1-benzothiophen-3-one —— C18H13N3OS2
    2-[2-phenyl-1-(1,2,5-thiadiazol-3-ylamino)ethylidene]-1-benzothiophen-3-one
    —— 1-(4-Chlorophenyl)-5-[[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylidene]-2-sulfanylidene-1,3-diazinane-4,6-dione —— C22H12Cl2N4O2S3
    1-(4-Chlorophenyl)-5-[[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylidene]-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— 5-ethyl-3-fluoro-N-(2-fluoro-4-methylsulfanylphenyl)-4-(3-oxa-7-azabicyclo[3.3.1]nonan-9-yloxy)pyridin-2-amine —— C21H25F2N3O2S
    5-ethyl-3-fluoro-N-(2-fluoro-4-methylsulfanylphenyl)-4-(3-oxa-7-azabicyclo[3.3.1]nonan-9-yloxy)pyridin-2-amine
    —— 3H-pyrido[3,4-b][1,4]thiazine —— C7H6N2S
    3H-pyrido[3,4-b][1,4]thiazine