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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [4-[4-[Heptyl(prop-2-enylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate —— C27H36N2O3S
    [4-[4-[Heptyl(prop-2-enylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 3-(1,3-Benzothiazol-2-ylsulfanyl)-1-[6-[3-(1,3-benzothiazol-2-ylsulfanyl)-2,5-dihydroxypyrrol-1-yl]hexyl]pyrrole-2,5-diol —— C28H26N4O4S4
    3-(1,3-Benzothiazol-2-ylsulfanyl)-1-[6-[3-(1,3-benzothiazol-2-ylsulfanyl)-2,5-dihydroxypyrrol-1-yl]hexyl]pyrrole-2,5-diol
    —— (5Z)-5-[[5-(4-chlorophenyl)sulfanylthiophen-2-yl]methylidene]-3-cyclohexyl-2-cyclohexylimino-1,3-thiazolidin-4-one —— C26H29ClN2OS3
    (5Z)-5-[[5-(4-chlorophenyl)sulfanylthiophen-2-yl]methylidene]-3-cyclohexyl-2-cyclohexylimino-1,3-thiazolidin-4-one
    —— N-cycloheptyl-5-[1-(dimethylamino)-2-methyl-1-oxopropan-2-yl]sulfanyl-2-(4-methylpentanoyl)-1,3,4-oxadiazol-3-ium-3-carboxamide —— C22H37N4O4S+
    N-cycloheptyl-5-[1-(dimethylamino)-2-methyl-1-oxopropan-2-yl]sulfanyl-2-(4-methylpentanoyl)-1,3,4-oxadiazol-3-ium-3-carboxamide
    —— [2-(10-Bromodecoxy)-1,1-difluoro-2-oxoethyl]sulfonyl-[cyclopentyl-methyl-(2-oxocyclohexyl)-lambda4-sulfanyl]oxidanium —— C24H42BrF2O6S2+
    [2-(10-Bromodecoxy)-1,1-difluoro-2-oxoethyl]sulfonyl-[cyclopentyl-methyl-(2-oxocyclohexyl)-lambda4-sulfanyl]oxidanium
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(2,5-dimethylthiophen-3-yl)ethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C21H22N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(2,5-dimethylthiophen-3-yl)ethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 4,4,5,5,6,6,6-Heptafluoro-1-methylsulfanylhex-2-ene —— C7H7F7S
    4,4,5,5,6,6,6-Heptafluoro-1-methylsulfanylhex-2-ene
    —— 3-(2-Methoxyethoxy)-1-[2-(1-methylsulfanylethoxy)ethoxy]butane —— C12H26O4S
    3-(2-Methoxyethoxy)-1-[2-(1-methylsulfanylethoxy)ethoxy]butane
    —— 3,5,5-Trimethylhex-3-ene-2-thione —— C9H16S
    3,5,5-Trimethylhex-3-ene-2-thione
    —— 7-Propan-2-yl-2,3,4,5-tetrahydrothiepine 1,1-dioxide —— C9H16O2S
    7-Propan-2-yl-2,3,4,5-tetrahydrothiepine 1,1-dioxide
    —— 1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-(3,3,5-trimethylcyclohexylidene)amino]thiourea —— C17H23F2N3S2
    1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-(3,3,5-trimethylcyclohexylidene)amino]thiourea
    —— (E)-3-amino-2-[2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]acetyl]but-2-enenitrile —— C8H10N6OS
    (E)-3-amino-2-[2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]acetyl]but-2-enenitrile
    —— 2-hydroxy-N'-[(Z)-{3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl}methylidene]benzohydrazide —— C21H13N5O6S2
    2-hydroxy-N'-[(Z)-{3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl}methylidene]benzohydrazide
    —— 3-Chloro-2-(4-chloro-2-methylsulfanyl-2,3-dihydro-1-benzothiophene-5-carbonyl)cyclohex-2-en-1-one —— C16H14Cl2O2S2
    3-Chloro-2-(4-chloro-2-methylsulfanyl-2,3-dihydro-1-benzothiophene-5-carbonyl)cyclohex-2-en-1-one
    —— Ethoxyethane;ethylperoxyethane;2-methylsulfonylacetonitrile —— C11H25NO5S
    Ethoxyethane;ethylperoxyethane;2-methylsulfonylacetonitrile
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C21H20N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 4-Methyl-3-methylidene-5-methylsulfanylhexa-1,4-diene —— C9H14S
    4-Methyl-3-methylidene-5-methylsulfanylhexa-1,4-diene
    —— (+/-)-Ethyl {8-bromo-9-[(4-chlorophenyl)thio]-6-fluoro-2,3-dihydro-1h-pyrrolo[1,2-a]indol-1-yl}(difluoro)acetate —— C21H16BrClF3NO2S
    (+/-)-Ethyl {8-bromo-9-[(4-chlorophenyl)thio]-6-fluoro-2,3-dihydro-1h-pyrrolo[1,2-a]indol-1-yl}(difluoro)acetate
    —— N-(1-azabicyclo[2.2.2]octan-2-yl)-5-pyridin-2-ylsulfanylthiophene-2-carboxamide —— C17H19N3OS2
    N-(1-azabicyclo[2.2.2]octan-2-yl)-5-pyridin-2-ylsulfanylthiophene-2-carboxamide
    —— 1,3-Bis(hexylsulfanyl)-5-methylbenzene —— C19H32S2
    1,3-Bis(hexylsulfanyl)-5-methylbenzene
    —— 2-Hydroxy-4,4,5,5-tetramethyl-1-oxa-2lambda6-thiacyclopent-2-ene 2-oxide —— C7H14O3S
    2-Hydroxy-4,4,5,5-tetramethyl-1-oxa-2lambda6-thiacyclopent-2-ene 2-oxide
    —— 2,5-Dimethyl-4-(4-methylphenyl)sulfanylbenzenediazonium;trifluoroborane;fluoride —— C15H15BF4N2S
    2,5-Dimethyl-4-(4-methylphenyl)sulfanylbenzenediazonium;trifluoroborane;fluoride
    —— N-(2-amino-2-sulfanylideneethanethioyl)formamide —— C3H4N2OS2
    N-(2-amino-2-sulfanylideneethanethioyl)formamide
    —— N,N-dimethylcarbamothioyl chloride;methylimino(sulfanylidene)methane —— C5H9ClN2S2
    N,N-dimethylcarbamothioyl chloride;methylimino(sulfanylidene)methane
    —— 4-fluoro-N-[(Z)-[5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]methylideneamino]benzamide —— C19H11FN4O4S2
    4-fluoro-N-[(Z)-[5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]methylideneamino]benzamide
    —— 1-(Difluoromethylsulfanyl)propane —— C4H8F2S
    1-(Difluoromethylsulfanyl)propane
    —— 2-Hexyl-2-phenyl-1,3-dithian-4-ol —— C16H24OS2
    2-Hexyl-2-phenyl-1,3-dithian-4-ol
    —— 1-[5-(Cyclopropylmethyl)-2-(cyclopropylmethylsulfanyl)cyclohexyl]-2,2,2-trifluoroethanamine —— C16H26F3NS
    1-[5-(Cyclopropylmethyl)-2-(cyclopropylmethylsulfanyl)cyclohexyl]-2,2,2-trifluoroethanamine
    —— 9-(Trifluoromethylsulfonyl)nonan-1-amine —— C10H20F3NO2S
    9-(Trifluoromethylsulfonyl)nonan-1-amine
    —— 1-Carbamoyl-3-methyl-1,2-thiazole-2-carboxylic acid —— C6H8N2O3S
    1-Carbamoyl-3-methyl-1,2-thiazole-2-carboxylic acid
    —— Methyl 5-(phenylsulfanylmethyl)cyclohex-3-ene-1-carboxylate —— C15H18O2S
    Methyl 5-(phenylsulfanylmethyl)cyclohex-3-ene-1-carboxylate
    —— 1-(Fluoromethylsulfinyl)-4-methylidenecyclohexane —— C8H13FOS
    1-(Fluoromethylsulfinyl)-4-methylidenecyclohexane
    —— 3-Hepta-1,3,5-trien-2-ylsulfanylcyclohepta-1,3,5-triene —— C14H16S
    3-Hepta-1,3,5-trien-2-ylsulfanylcyclohepta-1,3,5-triene
    —— 5-[4-[(5-methyl-1H-pyrazol-3-yl)amino]-6-(3-morpholin-4-ylazetidin-1-yl)pyrimidin-2-yl]sulfanyl-2-(2,2,2-trifluoroethyl)isoindol-1-ol —— C25H27F3N8O2S
    5-[4-[(5-methyl-1H-pyrazol-3-yl)amino]-6-(3-morpholin-4-ylazetidin-1-yl)pyrimidin-2-yl]sulfanyl-2-(2,2,2-trifluoroethyl)isoindol-1-ol
    —— (E)-3-amino-2-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]but-2-enenitrile —— C9H11N5OS
    (E)-3-amino-2-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]but-2-enenitrile
    —— 1-(1-Chloroprop-2-ynyl)-4-[4-(1-chloroprop-2-ynyl)phenyl]sulfanylbenzene —— C18H12Cl2S
    1-(1-Chloroprop-2-ynyl)-4-[4-(1-chloroprop-2-ynyl)phenyl]sulfanylbenzene
    —— 1-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-propan-2-ylthiourea —— C12H17N3S2
    1-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-propan-2-ylthiourea
    —— N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]pyridine-3-carboxamide —— C17H12ClN3O2S
    N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]pyridine-3-carboxamide
    —— Methyl-oxo-(3,3,6-trimethyl-6-propanethioylcycloocta-1,4,7-trien-1-yl)azanium —— C15H22NOS+
    Methyl-oxo-(3,3,6-trimethyl-6-propanethioylcycloocta-1,4,7-trien-1-yl)azanium
    —— 4,6-Dichloro-2-methylsulfanyl-5-(nitrosomethyl)pyrimidine —— C6H5Cl2N3OS
    4,6-Dichloro-2-methylsulfanyl-5-(nitrosomethyl)pyrimidine
    —— 4-(4-hydroxyphenyl)sulfanyl-N-[(2-methylphenyl)methyl]pentanamide —— C19H23NO2S
    4-(4-hydroxyphenyl)sulfanyl-N-[(2-methylphenyl)methyl]pentanamide
    —— 8-(2,5-dimethoxyphenyl)sulfanyl-3-[2-[4-(dimethylamino)phenyl]ethyl]-7H-purin-3-ium-6-amine —— C23H27N6O2S+
    8-(2,5-dimethoxyphenyl)sulfanyl-3-[2-[4-(dimethylamino)phenyl]ethyl]-7H-purin-3-ium-6-amine
    —— (E)-2-benzoyl-3-(4-bromo-5-phenylsulfanylfuran-2-yl)prop-2-enenitrile —— C20H12BrNO2S
    (E)-2-benzoyl-3-(4-bromo-5-phenylsulfanylfuran-2-yl)prop-2-enenitrile
    —— 1-(3-chloro-4-methylphenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C21H22ClN3S
    1-(3-chloro-4-methylphenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— N-methyl-6-[(6-methyl-[1,2,4]triazolo[4,3-a]pyridin-3-yl)sulfanyl]-1,3-benzothiazol-2-amine —— C15H13N5S2
    N-methyl-6-[(6-methyl-[1,2,4]triazolo[4,3-a]pyridin-3-yl)sulfanyl]-1,3-benzothiazol-2-amine
    —— 3-{(5Z)-5-[4-(methylsulfanyl)benzylidene]-4-oxo-2-thioxo-1,3-thiazolidin-3-yl}propanoic acid —— C14H13NO3S3
    3-{(5Z)-5-[4-(methylsulfanyl)benzylidene]-4-oxo-2-thioxo-1,3-thiazolidin-3-yl}propanoic acid
    —— 5-Methyl-1-(phenylmethoxymethyl)-6-pyridin-2-ylsulfanylpyrimidine-2,4-dione —— C18H17N3O3S
    5-Methyl-1-(phenylmethoxymethyl)-6-pyridin-2-ylsulfanylpyrimidine-2,4-dione
    —— 2-[[3-amino-5-(furan-2-yl)-1H-pyrazol-4-yl]sulfanyl]phenol —— C13H11N3O2S
    2-[[3-amino-5-(furan-2-yl)-1H-pyrazol-4-yl]sulfanyl]phenol
    —— N-[2-(3-chlorophenyl)sulfanylethyl]-2,2,2-trifluoroacetamide —— C10H9ClF3NOS
    N-[2-(3-chlorophenyl)sulfanylethyl]-2,2,2-trifluoroacetamide
    —— 5-Fluoro-6-[(6-methyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)sulfanyl]-1,3-benzothiazol-2-amine —— C13H9FN6S2
    5-Fluoro-6-[(6-methyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)sulfanyl]-1,3-benzothiazol-2-amine