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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2-oxo-2-pyrrolidin-1-ylethyl) 3-(4-methylphenyl)sulfanylpropanoate —— C16H21NO3S
    (2-oxo-2-pyrrolidin-1-ylethyl) 3-(4-methylphenyl)sulfanylpropanoate
    —— (2S)-N-(cyclohexylmethyl)-2-pyridin-2-ylsulfanylpropanamide —— C15H22N2OS
    (2S)-N-(cyclohexylmethyl)-2-pyridin-2-ylsulfanylpropanamide
    —— 2-((4,6-Dimethylpyrimidin-2-yl)thio)-N'-(1-phenylethylidene)acetohydrazide 60458-66-4 C16H18N4OS
    2-((4,6-Dimethylpyrimidin-2-yl)thio)-N'-(1-phenylethylidene)acetohydrazide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C14H17F2NO3S2
    2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— 2-[(1R)-1-(3,4-dimethylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C16H16N2OS2
    2-[(1R)-1-(3,4-dimethylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 3-(2-fluorophenyl)-N-[2-(4-methylphenyl)sulfanylethyl]propanamide —— C18H20FNOS
    3-(2-fluorophenyl)-N-[2-(4-methylphenyl)sulfanylethyl]propanamide
    —— N-(2-methylphenyl)-N-{(Z)-[4-(methylsulfanyl)phenyl]methylidene}amine oxide —— C15H15NOS
    N-(2-methylphenyl)-N-{(Z)-[4-(methylsulfanyl)phenyl]methylidene}amine oxide
    —— [(2S)-oxan-2-yl]methyl 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C16H24N2O3S
    [(2S)-oxan-2-yl]methyl 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— N-[2-(4-methylphenyl)sulfanylethyl]cyclopentanecarboxamide —— C15H21NOS
    N-[2-(4-methylphenyl)sulfanylethyl]cyclopentanecarboxamide
    —— 3-(2-chlorophenyl)-N-[2-(4-methylphenyl)sulfanylethyl]propanamide —— C18H20ClNOS
    3-(2-chlorophenyl)-N-[2-(4-methylphenyl)sulfanylethyl]propanamide
    —— 2-[(1R)-1-(4-fluorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C14H11FN2OS2
    2-[(1R)-1-(4-fluorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— (1R)-N-[2-(4-methylphenyl)sulfanylethyl]cyclohex-3-ene-1-carboxamide —— C16H21NOS
    (1R)-N-[2-(4-methylphenyl)sulfanylethyl]cyclohex-3-ene-1-carboxamide
    —— (2S)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide —— C14H18N4OS3
    (2S)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide
    —— 2-[(1S)-1-(2-fluorophenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C16H13FN2OS
    2-[(1S)-1-(2-fluorophenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-2-methylpropanamide —— C12H16ClNOS
    N-[2-(4-chlorophenyl)sulfanylethyl]-2-methylpropanamide
    —— N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-4,5,6,7-tetrahydro-1H-indazole-3-carboxamide —— C16H18N4OS
    N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-4,5,6,7-tetrahydro-1H-indazole-3-carboxamide
    —— 2-[(1R)-1-(4-methylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C15H14N2OS2
    2-[(1R)-1-(4-methylphenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-[(1R)-1-(2,5-dimethylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C18H18N2OS
    2-[(1R)-1-(2,5-dimethylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[(1S)-cyclopent-2-en-1-yl]-N-(3-phenylsulfanylpropyl)acetamide —— C16H21NOS
    2-[(1S)-cyclopent-2-en-1-yl]-N-(3-phenylsulfanylpropyl)acetamide
    —— 2-[(2R)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C14H21N3O2S
    2-[(2R)-1-oxo-1-pyrrolidin-1-ylpropan-2-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— 2-[(1R)-1-(3,4-dimethylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C18H18N2OS
    2-[(1R)-1-(3,4-dimethylphenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[(1R)-1-(1-methylimidazol-2-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C14H14N4OS
    2-[(1R)-1-(1-methylimidazol-2-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-3-(4-fluorophenyl)propanamide —— C17H17ClFNOS
    N-[2-(4-chlorophenyl)sulfanylethyl]-3-(4-fluorophenyl)propanamide
    —— 2-(1-methyl-1H-pyrrol-2-yl)-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}acetohydrazide —— C15H17N3OS
    2-(1-methyl-1H-pyrrol-2-yl)-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}acetohydrazide
    —— 2-[(4,6-dimethyl-2-pyrimidinyl)thio]-N'-[(3-methyl-2-thienyl)methylene]acetohydrazide —— C14H16N4OS2
    2-[(4,6-dimethyl-2-pyrimidinyl)thio]-N'-[(3-methyl-2-thienyl)methylene]acetohydrazide
    —— N'-[(Z)-[4-(Methylsulfanyl)phenyl]methylidene]-2-(thiophen-2-YL)acetohydrazide —— C14H14N2OS2
    N'-[(Z)-[4-(Methylsulfanyl)phenyl]methylidene]-2-(thiophen-2-YL)acetohydrazide
    —— N-[(Z)-1-(4-methylphenyl)ethylideneamino]-2-pyrimidin-2-ylsulfanylacetamide —— C15H16N4OS
    N-[(Z)-1-(4-methylphenyl)ethylideneamino]-2-pyrimidin-2-ylsulfanylacetamide
    —— (Z)-1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C13H11N7O2S
    (Z)-1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— (3S,5S)-3-(2,5-dimethylphenyl)sulfanyl-5-methyloxolan-2-one —— C13H16O2S
    (3S,5S)-3-(2,5-dimethylphenyl)sulfanyl-5-methyloxolan-2-one
    —— (3R,5S)-3-(2-fluorophenyl)sulfanyl-5-methyloxolan-2-one —— C11H11FO2S
    (3R,5S)-3-(2-fluorophenyl)sulfanyl-5-methyloxolan-2-one
    —— 2-(4-bromophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C14H18BrNO3S2
    2-(4-bromophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— 2-(4-bromophenyl)sulfanyl-1-[1-[(2S)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C18H22BrNO2S
    2-(4-bromophenyl)sulfanyl-1-[1-[(2S)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— N-[(Z)-(4-methylphenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C15H15N3OS
    N-[(Z)-(4-methylphenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— [(3S,5S)-5-methyl-2-oxooxolan-3-yl] 2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylbenzoate —— C20H18N2O4S2
    [(3S,5S)-5-methyl-2-oxooxolan-3-yl] 2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylbenzoate
    —— (2R)-N-(cyclohexylmethyl)-2-(4-methylphenyl)sulfanylpropanamide —— C17H25NOS
    (2R)-N-(cyclohexylmethyl)-2-(4-methylphenyl)sulfanylpropanamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylacetamide —— C15H21NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H17N3OS
    N-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide —— C17H25NO3S2
    N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide
    —— N-butyl-3-(4-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C17H24ClNO3S2
    N-butyl-3-(4-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— (1S,2S)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylcyclopropane-1-carboxamide —— C18H18N2OS
    (1S,2S)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylcyclopropane-1-carboxamide
    —— N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]pyridine-4-carboxamide —— C17H13N3O2S
    N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]pyridine-4-carboxamide
    —— N-[(Z)-benzylideneamino]-3-(4-chlorophenyl)sulfanylpropanamide —— C16H15ClN2OS
    N-[(Z)-benzylideneamino]-3-(4-chlorophenyl)sulfanylpropanamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-(3-hydroxyphenyl)methylideneamino]acetamide —— C15H16N4O2S
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-(3-hydroxyphenyl)methylideneamino]acetamide
    —— N-[(Z)-furan-2-ylmethylideneamino]-2-pyrimidin-2-ylsulfanylacetamide —— C11H10N4O2S
    N-[(Z)-furan-2-ylmethylideneamino]-2-pyrimidin-2-ylsulfanylacetamide
    —— (Z)-N-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-thiophen-2-ylmethanimine —— C9H8N6S2
    (Z)-N-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-thiophen-2-ylmethanimine
    —— N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-phenylpropanamide —— C17H18N2OS
    N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-phenylpropanamide
    —— (2R)-1-methyl-2-[2-(1-methyltetrazol-5-yl)sulfanylethyl]piperidine —— C10H19N5S
    (2R)-1-methyl-2-[2-(1-methyltetrazol-5-yl)sulfanylethyl]piperidine
    —— (2S)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-(1-methyltetrazol-5-yl)sulfanylpropan-1-one —— C11H19N5O2S
    (2S)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-(1-methyltetrazol-5-yl)sulfanylpropan-1-one
    —— (2R)-2-[[5-[(1R)-1-cyano-2-(4-methylphenyl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile —— C22H20N4S3
    (2R)-2-[[5-[(1R)-1-cyano-2-(4-methylphenyl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— 2-(3,5-dimethylphenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-oxadiazole —— C15H18N2O2S
    2-(3,5-dimethylphenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-oxadiazole