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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H13ClN4OS2
    N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 6-Cyclohexylsulfanylhexan-3-amine —— C12H25NS
    6-Cyclohexylsulfanylhexan-3-amine
    —— 6-{[3-(trifluoromethyl)phenyl]sulfanyl}imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-methyloxime —— C14H10F3N3OS2
    6-{[3-(trifluoromethyl)phenyl]sulfanyl}imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-methyloxime
    —— (Z)-1-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]-N-[(2,4-dichlorophenyl)methoxy]methanimine —— C19H13Cl3F3N3OS
    (Z)-1-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]-N-[(2,4-dichlorophenyl)methoxy]methanimine
    —— 1-(3-Aminoprop-1-enylsulfanyl)butan-1-amine —— C7H16N2S
    1-(3-Aminoprop-1-enylsulfanyl)butan-1-amine
    —— Aniline;ethylcyclohexane;methanamine;methylsulfanylbenzene;methylsulfanylcyclohexane —— C29H50N2S2
    Aniline;ethylcyclohexane;methanamine;methylsulfanylbenzene;methylsulfanylcyclohexane
    —— 3-[3-(4-Ethenyloxan-4-yl)phenyl]sulfanylpropanoic acid —— C16H20O3S
    3-[3-(4-Ethenyloxan-4-yl)phenyl]sulfanylpropanoic acid
    —— 1-Ethylsulfanyl-8,8,8-trifluorooct-2-yne —— C10H15F3S
    1-Ethylsulfanyl-8,8,8-trifluorooct-2-yne
    —— 2-(5-Ethyl-2,6-dimethylcyclohepta-1,3,6-trien-1-yl)ethanethiol —— C13H20S
    2-(5-Ethyl-2,6-dimethylcyclohepta-1,3,6-trien-1-yl)ethanethiol
    —— 3-[(3-formyl-2-oxo-1,3-dihydroindol-6-yl)sulfanyl]-N-methylbenzamide —— C17H14N2O3S
    3-[(3-formyl-2-oxo-1,3-dihydroindol-6-yl)sulfanyl]-N-methylbenzamide
    —— 2-[(1S,5R)-5-(methylsulfanylmethoxy)-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalen-1-yl]propan-2-ol —— C15H28O2S
    2-[(1S,5R)-5-(methylsulfanylmethoxy)-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalen-1-yl]propan-2-ol
    —— 4-(5-chloropyridin-2-yl)-2-(4-furo[3,2-b]pyridin-7-ylsulfanylphenyl)-1H-phthalazin-1-amine —— C26H18ClN5OS
    4-(5-chloropyridin-2-yl)-2-(4-furo[3,2-b]pyridin-7-ylsulfanylphenyl)-1H-phthalazin-1-amine
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-1-thiophen-2-ylethylideneamino]acetamide —— C17H15ClN4OS4
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-1-thiophen-2-ylethylideneamino]acetamide
    —— Methyl-methylidene-(1-sulfanylpentan-2-yl)azanium —— C7H16NS+
    Methyl-methylidene-(1-sulfanylpentan-2-yl)azanium
    —— 3-[(2,6-dichlorophenyl)sulfanyl]-6-methoxy-2-(4-methoxyphenyl)-1H-1-benzothiophen-1-one —— C22H16Cl2O3S2
    3-[(2,6-dichlorophenyl)sulfanyl]-6-methoxy-2-(4-methoxyphenyl)-1H-1-benzothiophen-1-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(phenylsulfanyl)methyl]-N'-[(1E)-1-(thiophen-2-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C18H16N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(phenylsulfanyl)methyl]-N'-[(1E)-1-(thiophen-2-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-[2-[2-Fluoro-6-(4-methylphenyl)sulfanylphenyl]pyrimidin-4-yl]-1,5,6,7-tetrahydropyrrolo[3,2-c]pyridin-4-one —— C24H19FN4OS
    2-[2-[2-Fluoro-6-(4-methylphenyl)sulfanylphenyl]pyrimidin-4-yl]-1,5,6,7-tetrahydropyrrolo[3,2-c]pyridin-4-one
    —— Methoxy(methylsulfanyl)methane;2-methylsulfanylacetaldehyde —— C6H14O2S2
    Methoxy(methylsulfanyl)methane;2-methylsulfanylacetaldehyde
    —— 1-[4-[4-[4-[2-(3,3-Dimethylbutoxy)-2-methylpropyl]triazol-1-yl]-2-methylbutan-2-yl]oxy-2-methylbutan-2-yl]-3-ethylsulfanylpyrrole-2,5-diol —— C28H50N4O4S
    1-[4-[4-[4-[2-(3,3-Dimethylbutoxy)-2-methylpropyl]triazol-1-yl]-2-methylbutan-2-yl]oxy-2-methylbutan-2-yl]-3-ethylsulfanylpyrrole-2,5-diol
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-fluorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C20H17FN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-fluorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— Tributyl(methyl)-lambda4-sulfane —— C13H30S
    Tributyl(methyl)-lambda4-sulfane
    —— 3-[(Z)-N-[[1-(4-azaniumyl-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)triazole-4-carbonyl]amino]-C-methylcarbonimidoyl]phenolate —— C20H18N8O3S
    3-[(Z)-N-[[1-(4-azaniumyl-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)triazole-4-carbonyl]amino]-C-methylcarbonimidoyl]phenolate
    —— N-[(Z)-(4-methoxyphenyl)methylideneamino]-N-methyl-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine —— C24H21N3OS2
    N-[(Z)-(4-methoxyphenyl)methylideneamino]-N-methyl-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine
    —— 2-Tert-butylsulfanyl-1,5-difluoro-3-prop-2-enylbenzene —— C13H16F2S
    2-Tert-butylsulfanyl-1,5-difluoro-3-prop-2-enylbenzene
    —— 2-Hydroxyheptane-4-thione —— C7H14OS
    2-Hydroxyheptane-4-thione
    —— (Z)-2-(2,3-dihydro-1H-benzimidazol-2-yl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enenitrile —— C20H15N3OS
    (Z)-2-(2,3-dihydro-1H-benzimidazol-2-yl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enenitrile
    —— 2-Amino-8-chloro-5,5-dioxo[1,2,4]triazolo[2,3-b][1,4,2]benzodithiazine —— C8H5ClN4O2S2
    2-Amino-8-chloro-5,5-dioxo[1,2,4]triazolo[2,3-b][1,4,2]benzodithiazine
    —— 3-[4-[(E)-2-(2,4-dichlorophenyl)ethenyl]pyrimidin-2-yl]sulfanyl-5-(trifluoromethyl)pyridine-2-carboxamide —— C19H11Cl2F3N4OS
    3-[4-[(E)-2-(2,4-dichlorophenyl)ethenyl]pyrimidin-2-yl]sulfanyl-5-(trifluoromethyl)pyridine-2-carboxamide
    —— N-[(1S,2S,3S,4R)-3-pentyl-2-bicyclo[2.2.1]heptanyl]-5-thiophen-2-ylsulfanylthiophene-2-carboxamide —— C21H27NOS3
    N-[(1S,2S,3S,4R)-3-pentyl-2-bicyclo[2.2.1]heptanyl]-5-thiophen-2-ylsulfanylthiophene-2-carboxamide
    —— 8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-[2-(2-nitrophenyl)ethyl]-7H-purin-3-ium-6-amine —— C20H16BrN6O4S+
    8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-[2-(2-nitrophenyl)ethyl]-7H-purin-3-ium-6-amine
    —— 3-[5-Bromo-2-[4-[(methyl-methylidene-oxo-lambda6-sulfanyl)amino]anilino]pyrimidin-4-yl]sulfanylpropan-1-ol —— C15H19BrN4O2S2
    3-[5-Bromo-2-[4-[(methyl-methylidene-oxo-lambda6-sulfanyl)amino]anilino]pyrimidin-4-yl]sulfanylpropan-1-ol
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-{(E)-[4-(dimethylamino)phenyl]methylidene}acetohydrazide —— C20H20ClN5OS3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-{(E)-[4-(dimethylamino)phenyl]methylidene}acetohydrazide
    —— (E)-4-[2-[2-nitro-4-(trifluoromethyl)phenyl]sulfanylanilino]-4-oxobut-2-enoic acid —— C17H11F3N2O5S
    (E)-4-[2-[2-nitro-4-(trifluoromethyl)phenyl]sulfanylanilino]-4-oxobut-2-enoic acid
    —— 1-Methyl-2-propan-2-yl-3-prop-1-en-2-yl-1-[3-(3,3,4-trimethylpentylsulfanyl)propyl]cyclopropane —— C21H40S
    1-Methyl-2-propan-2-yl-3-prop-1-en-2-yl-1-[3-(3,3,4-trimethylpentylsulfanyl)propyl]cyclopropane
    —— 3-[2-(4-Fluorophenyl)ethyl]-2-piperidin-4-ylsulfanylpyridine —— C18H21FN2S
    3-[2-(4-Fluorophenyl)ethyl]-2-piperidin-4-ylsulfanylpyridine
    —— (2E)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2-cyano-N-(4-methoxyphenyl)prop-2-enamide —— C22H16N4O3S
    (2E)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2-cyano-N-(4-methoxyphenyl)prop-2-enamide
    —— 3-(2,6-dimethyl-3-pentylphenyl)sulfanyl-4,5,6-trimethyl-1H-pyrazolo[3,4-b]pyridine —— C22H29N3S
    3-(2,6-dimethyl-3-pentylphenyl)sulfanyl-4,5,6-trimethyl-1H-pyrazolo[3,4-b]pyridine
    —— Cyclopropyl(trimethyl)-lambda4-sulfane —— C6H14S
    Cyclopropyl(trimethyl)-lambda4-sulfane
    —— 8-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-11-oxa-2,4,5-triazatricyclo[7.3.0.03,7]dodeca-1,3(7),5-trien-10-one —— C19H13N5O3S
    8-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-11-oxa-2,4,5-triazatricyclo[7.3.0.03,7]dodeca-1,3(7),5-trien-10-one
    —— 3-(5-Butylsulfanylcyclohexa-1,5-dien-1-yl)butan-1-amine —— C14H25NS
    3-(5-Butylsulfanylcyclohexa-1,5-dien-1-yl)butan-1-amine
    —— 2,4-dimethyl-N-[(1E)-3,4,4-trichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl]aniline —— C18H15Cl3N2O2S
    2,4-dimethyl-N-[(1E)-3,4,4-trichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl]aniline
    —— N-[1-(2-amino-5-chlorophenyl)sulfanylethyl]-2-sulfanylacetamide —— C10H13ClN2OS2
    N-[1-(2-amino-5-chlorophenyl)sulfanylethyl]-2-sulfanylacetamide
    —— [2-[(4-Fluoro-1-benzothiophen-3-yl)sulfanyl]phenyl]methanol —— C15H11FOS2
    [2-[(4-Fluoro-1-benzothiophen-3-yl)sulfanyl]phenyl]methanol
    —— (3-methylphenyl)methyl N-phenyl-3-phenylsulfanylprop-2-enimidate —— C23H21NOS
    (3-methylphenyl)methyl N-phenyl-3-phenylsulfanylprop-2-enimidate
    —— [6-[2-Chloro-4-(3-phenylmethoxyphenyl)sulfanylphenyl]-3-[(2-methylpropan-2-yl)oxycarbonylimino]hexyl]phosphonic acid —— C30H35ClNO6PS
    [6-[2-Chloro-4-(3-phenylmethoxyphenyl)sulfanylphenyl]-3-[(2-methylpropan-2-yl)oxycarbonylimino]hexyl]phosphonic acid
    —— N-[1-(3-chlorophenyl)-3-(2-chlorophenylthio)-2-propenylidene]aniline 1140913-57-0 C21H15Cl2NS
    N-[1-(3-chlorophenyl)-3-(2-chlorophenylthio)-2-propenylidene]aniline
    —— 1-(Dihydroxymethyl)-1-prop-2-enylthiourea —— C5H10N2O2S
    1-(Dihydroxymethyl)-1-prop-2-enylthiourea
    —— 3-[(4-fluorophenyl)sulfanyl]-6-methoxy-2-(4-methoxyphenyl)-1H-1-benzothiophen-1-one —— C22H17FO3S2
    3-[(4-fluorophenyl)sulfanyl]-6-methoxy-2-(4-methoxyphenyl)-1H-1-benzothiophen-1-one
    —— (2,5-Diethyl-4-methyloctyl)-tetramethyl-(5-methylhexyl)-lambda6-sulfane —— C24H54S
    (2,5-Diethyl-4-methyloctyl)-tetramethyl-(5-methylhexyl)-lambda6-sulfane
    —— N,N-dimethyl-1-[(E)-3-phenylsulfanylprop-2-enyl]pyridin-1-ium-4-amine —— C16H19N2S+
    N,N-dimethyl-1-[(E)-3-phenylsulfanylprop-2-enyl]pyridin-1-ium-4-amine