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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(1R)-1-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]aniline —— C10H12N4S
    3-[(1R)-1-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]aniline
    —— 4-[(1S)-1-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]aniline —— C11H14N4S
    4-[(1S)-1-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]aniline
    —— 3-[(1R)-1-(1-methyltetrazol-5-yl)sulfanylethyl]aniline —— C10H13N5S
    3-[(1R)-1-(1-methyltetrazol-5-yl)sulfanylethyl]aniline
    —— 4-[(1S)-1-pyrimidin-2-ylsulfanylethyl]aniline —— C12H13N3S
    4-[(1S)-1-pyrimidin-2-ylsulfanylethyl]aniline
    —— N-[[(2S)-butan-2-yl]carbamothioyl]-2-methylpropanamide —— C9H18N2OS
    N-[[(2S)-butan-2-yl]carbamothioyl]-2-methylpropanamide
    —— N-[[(2R)-2-ethylhexyl]carbamothioyl]-2-methylpropanamide —— C13H26N2OS
    N-[[(2R)-2-ethylhexyl]carbamothioyl]-2-methylpropanamide
    —— 3-[(1R)-1-(1-methylimidazol-2-yl)sulfanylethyl]aniline —— C12H15N3S
    3-[(1R)-1-(1-methylimidazol-2-yl)sulfanylethyl]aniline
    —— (2R)-2-pyrimidin-4-ylsulfanylpropanoic acid —— C7H8N2O2S
    (2R)-2-pyrimidin-4-ylsulfanylpropanoic acid
    —— (4S)-2-amino-7-methyl-5-oxo-4-[4-(trifluoromethylsulfanyl)phenyl]-4H-pyrano[3,2-c]pyran-3-carbonitrile —— C17H11F3N2O3S
    (4S)-2-amino-7-methyl-5-oxo-4-[4-(trifluoromethylsulfanyl)phenyl]-4H-pyrano[3,2-c]pyran-3-carbonitrile
    —— ethyl (4R)-6-amino-5-cyano-2-[(3-cyano-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl)sulfanylmethyl]-4-phenyl-4H-pyran-3-carboxylate —— C25H22N4O3S
    ethyl (4R)-6-amino-5-cyano-2-[(3-cyano-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl)sulfanylmethyl]-4-phenyl-4H-pyran-3-carboxylate
    —— (1R,4R)-4,7,7-trimethyl-3-oxo-N-(2-phenylsulfanylphenyl)-2-oxabicyclo[2.2.1]heptane-1-carboxamide —— C22H23NO3S
    (1R,4R)-4,7,7-trimethyl-3-oxo-N-(2-phenylsulfanylphenyl)-2-oxabicyclo[2.2.1]heptane-1-carboxamide
    —— 4-N-[(1R)-1-phenylethyl]-6-quinolin-8-ylsulfanylpyrimidine-4,5-diamine —— C21H19N5S
    4-N-[(1R)-1-phenylethyl]-6-quinolin-8-ylsulfanylpyrimidine-4,5-diamine
    —— (2S)-2-(6-propan-2-ylpyrimidin-4-yl)sulfanylpropanoic acid —— C10H14N2O2S
    (2S)-2-(6-propan-2-ylpyrimidin-4-yl)sulfanylpropanoic acid
    —— 4-quinolin-8-ylsulfanyl-6-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]pyrimidin-5-amine —— C23H27N5S
    4-quinolin-8-ylsulfanyl-6-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]pyrimidin-5-amine
    —— ethyl (3S)-1-(5-amino-6-quinolin-8-ylsulfanylpyrimidin-4-yl)piperidine-3-carboxylate —— C21H23N5O2S
    ethyl (3S)-1-(5-amino-6-quinolin-8-ylsulfanylpyrimidin-4-yl)piperidine-3-carboxylate
    —— 4-[(2S)-2-ethylpiperidin-1-yl]-6-phenylsulfanylpyrimidin-5-amine —— C17H22N4S
    4-[(2S)-2-ethylpiperidin-1-yl]-6-phenylsulfanylpyrimidin-5-amine
    —— 4-(4-methylphenyl)sulfanyl-6-[(2S)-2-methylpiperidin-1-yl]pyrimidin-5-amine —— C17H22N4S
    4-(4-methylphenyl)sulfanyl-6-[(2S)-2-methylpiperidin-1-yl]pyrimidin-5-amine
    —— 4-N-[(2S)-butan-2-yl]-6-(4-chlorophenyl)sulfanylpyrimidine-4,5-diamine —— C14H17ClN4S
    4-N-[(2S)-butan-2-yl]-6-(4-chlorophenyl)sulfanylpyrimidine-4,5-diamine
    —— 4-[(2S)-2-ethylpiperidin-1-yl]-6-(4-methylphenyl)sulfanylpyrimidin-5-amine —— C18H24N4S
    4-[(2S)-2-ethylpiperidin-1-yl]-6-(4-methylphenyl)sulfanylpyrimidin-5-amine
    —— 4-[(3S)-3-methylpiperidin-1-yl]-6-quinolin-8-ylsulfanylpyrimidin-5-amine —— C19H21N5S
    4-[(3S)-3-methylpiperidin-1-yl]-6-quinolin-8-ylsulfanylpyrimidin-5-amine
    —— 6-(4-chlorophenyl)sulfanyl-4-N-[(1R)-1-phenylethyl]pyrimidine-4,5-diamine —— C18H17ClN4S
    6-(4-chlorophenyl)sulfanyl-4-N-[(1R)-1-phenylethyl]pyrimidine-4,5-diamine
    —— 4-(4-chlorophenyl)sulfanyl-6-[(3S)-3-methylpiperidin-1-yl]pyrimidin-5-amine —— C16H19ClN4S
    4-(4-chlorophenyl)sulfanyl-6-[(3S)-3-methylpiperidin-1-yl]pyrimidin-5-amine
    —— 4-[(3S)-3-methylpiperidin-1-yl]-6-phenylsulfanylpyrimidin-5-amine —— C16H20N4S
    4-[(3S)-3-methylpiperidin-1-yl]-6-phenylsulfanylpyrimidin-5-amine
    —— 6-(4-methylphenyl)sulfanyl-4-N-[[(2R)-oxolan-2-yl]methyl]pyrimidine-4,5-diamine —— C16H20N4OS
    6-(4-methylphenyl)sulfanyl-4-N-[[(2R)-oxolan-2-yl]methyl]pyrimidine-4,5-diamine
    —— 2-[(2S)-3-oxobutan-2-yl]sulfanyl-4-(trifluoromethyl)-5,6,7,8,9,10-hexahydrocycloocta[b]pyridine-3-carbonitrile —— C17H19F3N2OS
    2-[(2S)-3-oxobutan-2-yl]sulfanyl-4-(trifluoromethyl)-5,6,7,8,9,10-hexahydrocycloocta[b]pyridine-3-carbonitrile
    —— 4-[(2R)-2-ethylpiperidin-1-yl]-6-(4-methylphenyl)sulfanylpyrimidin-5-amine —— C18H24N4S
    4-[(2R)-2-ethylpiperidin-1-yl]-6-(4-methylphenyl)sulfanylpyrimidin-5-amine
    —— 6-(4-chlorophenyl)sulfanyl-4-N-[(2S)-1-methoxypropan-2-yl]pyrimidine-4,5-diamine —— C14H17ClN4OS
    6-(4-chlorophenyl)sulfanyl-4-N-[(2S)-1-methoxypropan-2-yl]pyrimidine-4,5-diamine
    —— 4-N-[[(2S)-oxolan-2-yl]methyl]-6-quinolin-8-ylsulfanylpyrimidine-4,5-diamine —— C18H19N5OS
    4-N-[[(2S)-oxolan-2-yl]methyl]-6-quinolin-8-ylsulfanylpyrimidine-4,5-diamine
    —— 6-(4-methylphenyl)sulfanyl-4-N-[[(2S)-oxolan-2-yl]methyl]pyrimidine-4,5-diamine —— C16H20N4OS
    6-(4-methylphenyl)sulfanyl-4-N-[[(2S)-oxolan-2-yl]methyl]pyrimidine-4,5-diamine
    —— [(1R,2R)-2-(1,3-thiazol-2-ylsulfanyl)cycloheptyl]methanamine —— C11H18N2S2
    [(1R,2R)-2-(1,3-thiazol-2-ylsulfanyl)cycloheptyl]methanamine
    —— N-[(2S)-butan-2-yl]-5-nitro-6-phenylsulfanylpyrimidin-4-amine —— C14H16N4O2S
    N-[(2S)-butan-2-yl]-5-nitro-6-phenylsulfanylpyrimidin-4-amine
    —— 4-N-[[(2R)-oxolan-2-yl]methyl]-6-phenylsulfanylpyrimidine-4,5-diamine —— C15H18N4OS
    4-N-[[(2R)-oxolan-2-yl]methyl]-6-phenylsulfanylpyrimidine-4,5-diamine
    —— N-[(2R)-1-methoxypropan-2-yl]-5-nitro-6-phenylsulfanylpyrimidin-4-amine —— C14H16N4O3S
    N-[(2R)-1-methoxypropan-2-yl]-5-nitro-6-phenylsulfanylpyrimidin-4-amine
    —— 6-(4-chlorophenyl)sulfanyl-4-N-[[(2R)-oxolan-2-yl]methyl]pyrimidine-4,5-diamine —— C15H17ClN4OS
    6-(4-chlorophenyl)sulfanyl-4-N-[[(2R)-oxolan-2-yl]methyl]pyrimidine-4,5-diamine
    —— (2S)-N-[(2-methylphenyl)methyl]-2-(4-methylphenyl)sulfanylpropanamide —— C18H21NOS
    (2S)-N-[(2-methylphenyl)methyl]-2-(4-methylphenyl)sulfanylpropanamide
    —— ethyl (3R)-1-[6-(4-methylphenyl)sulfanyl-5-nitropyrimidin-4-yl]piperidine-3-carboxylate —— C19H22N4O4S
    ethyl (3R)-1-[6-(4-methylphenyl)sulfanyl-5-nitropyrimidin-4-yl]piperidine-3-carboxylate
    —— 4-[(2S)-2-ethylpiperidin-1-yl]-6-(4-methylphenyl)sulfanyl-5-nitropyrimidine —— C18H22N4O2S
    4-[(2S)-2-ethylpiperidin-1-yl]-6-(4-methylphenyl)sulfanyl-5-nitropyrimidine
    —— N-[(2S)-butan-2-yl]-6-(4-chlorophenyl)sulfanyl-5-nitropyrimidin-4-amine —— C14H15ClN4O2S
    N-[(2S)-butan-2-yl]-6-(4-chlorophenyl)sulfanyl-5-nitropyrimidin-4-amine
    —— (1R,5S)-6-[6-(4-chlorophenyl)sulfanyl-5-nitropyrimidin-4-yl]-1,3,3-trimethyl-6-azabicyclo[3.2.1]octane —— C20H23ClN4O2S
    (1R,5S)-6-[6-(4-chlorophenyl)sulfanyl-5-nitropyrimidin-4-yl]-1,3,3-trimethyl-6-azabicyclo[3.2.1]octane
    —— 4-(4-chlorophenyl)sulfanyl-6-[(3R)-3-methylpiperidin-1-yl]-5-nitropyrimidine —— C16H17ClN4O2S
    4-(4-chlorophenyl)sulfanyl-6-[(3R)-3-methylpiperidin-1-yl]-5-nitropyrimidine
    —— (1R)-3-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine —— C15H21N3OS
    (1R)-3-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine
    —— (1R)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine —— C14H19N3OS
    (1R)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine
    —— (2R)-4-(4-bromophenyl)sulfanylbutan-2-amine —— C10H14BrNS
    (2R)-4-(4-bromophenyl)sulfanylbutan-2-amine
    —— (1S)-6-bromo-1,5-dimethyl-1-oxo-1λ6-thia-2-azacyclohexa-1,3,5-triene-4-carboxylic acid —— C7H8BrNO3S
    (1S)-6-bromo-1,5-dimethyl-1-oxo-1λ6-thia-2-azacyclohexa-1,3,5-triene-4-carboxylic acid
    —— (2S)-2-chloro-1-methylsulfanylpropane —— C4H9ClS
    (2S)-2-chloro-1-methylsulfanylpropane
    —— (3R)-1-(4-bromophenyl)sulfanylpentan-3-amine —— C11H16BrNS
    (3R)-1-(4-bromophenyl)sulfanylpentan-3-amine
    —— (2S)-4-(4-chlorophenyl)sulfanylbutan-2-amine —— C10H14ClNS
    (2S)-4-(4-chlorophenyl)sulfanylbutan-2-amine
    —— (3S)-1-(4-bromophenyl)sulfanylpentan-3-amine —— C11H16BrNS
    (3S)-1-(4-bromophenyl)sulfanylpentan-3-amine
    —— (3R)-1-phenylsulfanylhexan-3-amine —— C12H19NS
    (3R)-1-phenylsulfanylhexan-3-amine
    —— (1S)-4-amino-5-cyano-2-methylsulfanyl-3-azaspiro[5.5]undeca-2,4-diene-1-carboxamide —— C13H18N4OS
    (1S)-4-amino-5-cyano-2-methylsulfanyl-3-azaspiro[5.5]undeca-2,4-diene-1-carboxamide