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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,5,6-trichloro-4-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]pyridine-2-carboxylic acid —— C17H11Cl3N6O4S
    3,5,6-trichloro-4-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]pyridine-2-carboxylic acid
    —— 5-bromo-N-(3-methylphenyl)-4-methylsulfanylpyrimidin-2-amine —— C12H12BrN3S
    5-bromo-N-(3-methylphenyl)-4-methylsulfanylpyrimidin-2-amine
    —— 2-Fluoro-4-phenylsulfanylbut-2-en-1-amine —— C10H12FNS
    2-Fluoro-4-phenylsulfanylbut-2-en-1-amine
    —— N,5-dimethyl-6-[(6-methyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)sulfanyl]-1,3-benzothiazol-2-amine —— C15H14N6S2
    N,5-dimethyl-6-[(6-methyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)sulfanyl]-1,3-benzothiazol-2-amine
    —— Amino(penta-1,3-dienoxy)methanethiol —— C6H11NOS
    Amino(penta-1,3-dienoxy)methanethiol
    —— 4-Hexa-2,4-dien-2-yl-12-methylsulfanyl-5,6,11,13-tetrazatricyclo[7.4.0.02,6]trideca-1(13),2,4,9,11-pentaene —— C16H18N4S
    4-Hexa-2,4-dien-2-yl-12-methylsulfanyl-5,6,11,13-tetrazatricyclo[7.4.0.02,6]trideca-1(13),2,4,9,11-pentaene
    —— 2-Ethynylsulfanylethanol —— C4H6OS
    2-Ethynylsulfanylethanol
    —— 2,5-dimethyl-3-(2-methylsulfanylphenyl)-3H-pyrrolo[3,4-d][1,2]oxazole-4,6-diol —— C14H16N2O3S
    2,5-dimethyl-3-(2-methylsulfanylphenyl)-3H-pyrrolo[3,4-d][1,2]oxazole-4,6-diol
    —— 4-[5-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]-7,7-dimethyl-4,4a,6,8-tetrahydro-1H-pyrazolo[3,4-b]quinolin-5-one —— C23H19ClN4O2S2
    4-[5-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]-7,7-dimethyl-4,4a,6,8-tetrahydro-1H-pyrazolo[3,4-b]quinolin-5-one
    —— 1-[2-Bis(phenylmethoxy)phosphorylethyl]-5-methyl-6-phenylsulfanylpyrimidine-2,4-dione;ethane —— C29H33N2O5PS
    1-[2-Bis(phenylmethoxy)phosphorylethyl]-5-methyl-6-phenylsulfanylpyrimidine-2,4-dione;ethane
    —— Cycloocta-2,4-diene-1-thione —— C8H10S
    Cycloocta-2,4-diene-1-thione
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-thiophen-3-ylmethylideneamino]triazole-4-carboxamide —— C14H13N11O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-thiophen-3-ylmethylideneamino]triazole-4-carboxamide
    —— (2Z,5E)-5-({4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-[(4-fluorophenyl)imino]-1,3-thiazolidin-4-one —— C20H11BrClFN2O2S2
    (2Z,5E)-5-({4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-[(4-fluorophenyl)imino]-1,3-thiazolidin-4-one
    —— tert-butyl N-[[(2-methylpropan-2-yl)oxycarbonylamino]-[(5-methylsulfanylpyridin-2-yl)amino]methyl]carbamate —— C17H28N4O4S
    tert-butyl N-[[(2-methylpropan-2-yl)oxycarbonylamino]-[(5-methylsulfanylpyridin-2-yl)amino]methyl]carbamate
    —— 2,6-dimethyl-4-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,5-dien-1-one —— C21H18N2O3S
    2,6-dimethyl-4-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,5-dien-1-one
    —— (6E)-4-bromo-6-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,4-dien-1-one —— C19H13BrN2O3S
    (6E)-4-bromo-6-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,4-dien-1-one
    —— (6Z)-6-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,4-dien-1-one —— C19H14N2O3S
    (6Z)-6-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,4-dien-1-one
    —— 6-[[3-ethyl-5-(4-fluorophenyl)-3H-pyrrol-2-yl]sulfanyl]-5-methyl-1H-pyridin-2-one —— C18H17FN2OS
    6-[[3-ethyl-5-(4-fluorophenyl)-3H-pyrrol-2-yl]sulfanyl]-5-methyl-1H-pyridin-2-one
    —— 3-Hydroxy-4-methoxy-6-pyridin-2-ylsulfanylpyridine-2-carboxylic acid —— C12H10N2O4S
    3-Hydroxy-4-methoxy-6-pyridin-2-ylsulfanylpyridine-2-carboxylic acid
    —— 3-[(2,4-dimethylphenyl)sulfamoyl]-N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]benzamide —— C26H22N6O5S2
    3-[(2,4-dimethylphenyl)sulfamoyl]-N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]benzamide
    —— 11-Methyltricosane-11-thiol —— C24H50S
    11-Methyltricosane-11-thiol
    —— 3-(3-Cyano-6-methylpyridin-2-yl)sulfanylpentyl-methylcarbamic acid —— C14H19N3O2S
    3-(3-Cyano-6-methylpyridin-2-yl)sulfanylpentyl-methylcarbamic acid
    —— N-hexylsulfanylhydroxylamine —— C6H15NOS
    N-hexylsulfanylhydroxylamine
    —— 1-ethyl-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C16H21N3S
    1-ethyl-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— 4-[5-[(6-methoxy-1H-benzimidazol-2-yl)sulfanyl]furan-2-yl]-5,6,7,8-tetrahydro-1H-pyrazolo[3,4-b][1,7]naphthyridin-5-ol —— C21H18N6O3S
    4-[5-[(6-methoxy-1H-benzimidazol-2-yl)sulfanyl]furan-2-yl]-5,6,7,8-tetrahydro-1H-pyrazolo[3,4-b][1,7]naphthyridin-5-ol
    —— (1-Methoxy-2-methylpropyl) carbamodithioate —— C6H13NOS2
    (1-Methoxy-2-methylpropyl) carbamodithioate
    —— 3-[4-(2-Cyanoethylsulfonyl)buta-1,3-dienylsulfonyl]propanenitrile —— C10H12N2O4S2
    3-[4-(2-Cyanoethylsulfonyl)buta-1,3-dienylsulfonyl]propanenitrile
    —— 1,2,3-Tris(icosylsulfanyl)-5-methylbenzene —— C67H128S3
    1,2,3-Tris(icosylsulfanyl)-5-methylbenzene
    —— tert-butyl N-[4-(3-cyano-6-methylpyridin-2-yl)sulfanyl-4-(1,2-oxazol-5-yl)butyl]carbamate —— C19H24N4O3S
    tert-butyl N-[4-(3-cyano-6-methylpyridin-2-yl)sulfanyl-4-(1,2-oxazol-5-yl)butyl]carbamate
    —— 2-(2-cyanophenoxy)-N-hydroxy-N-methylpropanamide;(4-hydroxyphenyl) 4-[1-[2-(4-butan-2-ylphenyl)hydrazinyl]-1-oxododecan-2-yl]oxybenzenesulfinate;2-methyl-5-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]benzene-1,4-diol —— C55H68N6O10S4
    2-(2-cyanophenoxy)-N-hydroxy-N-methylpropanamide;(4-hydroxyphenyl) 4-[1-[2-(4-butan-2-ylphenyl)hydrazinyl]-1-oxododecan-2-yl]oxybenzenesulfinate;2-methyl-5-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]benzene-1,4-diol
    —— (2Z,5E)-5-{[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-2-[(4-methylphenyl)imino]-1,3-thiazolidin-4-one —— C22H16N4O2S2
    (2Z,5E)-5-{[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-2-[(4-methylphenyl)imino]-1,3-thiazolidin-4-one
    —— 2,3-bis(sulfanylidene)propanethioic S-acid —— C3H2OS3
    2,3-bis(sulfanylidene)propanethioic S-acid
    —— 1,1,1-Trifluoro-4-propylsulfanylbut-2-yne —— C7H9F3S
    1,1,1-Trifluoro-4-propylsulfanylbut-2-yne
    —— tert-butyl N-benzyl-N-[2-[4-(2-hydroxyphenyl)sulfanylphenyl]ethyl]carbamate —— C26H29NO3S
    tert-butyl N-benzyl-N-[2-[4-(2-hydroxyphenyl)sulfanylphenyl]ethyl]carbamate
    —— 3-Cyclopentyl-3-methoxy-2-(5-methylsulfanylpyridin-2-yl)butanamide —— C16H24N2O2S
    3-Cyclopentyl-3-methoxy-2-(5-methylsulfanylpyridin-2-yl)butanamide
    —— 5-[(3,5-Dimethylphenyl)sulfanylmethyl]-1,2-dimethylpyrazol-3-one —— C14H18N2OS
    5-[(3,5-Dimethylphenyl)sulfanylmethyl]-1,2-dimethylpyrazol-3-one
    —— 4-[2,5-dihydroxy-3-[2-methyl-3-(methylamino)-4-oxopentan-2-yl]sulfanylpyrrol-1-yl]-2,2,4-trimethyl-N-(2,4,4-trimethylpentan-2-yl)pentanamide —— C27H49N3O4S
    4-[2,5-dihydroxy-3-[2-methyl-3-(methylamino)-4-oxopentan-2-yl]sulfanylpyrrol-1-yl]-2,2,4-trimethyl-N-(2,4,4-trimethylpentan-2-yl)pentanamide
    —— 5-(2-methylbutylsulfanyl)-3H-1,3,4-thiadiazole-2-thione;5-pentan-3-ylsulfanyl-3H-1,3,4-thiadiazole-2-thione —— C14H24N4S6
    5-(2-methylbutylsulfanyl)-3H-1,3,4-thiadiazole-2-thione;5-pentan-3-ylsulfanyl-3H-1,3,4-thiadiazole-2-thione
    —— 8-(2,5-dimethoxyphenyl)sulfanyl-3-(2-morpholin-4-ylethyl)-7H-purin-3-ium-6-amine —— C19H25N6O3S+
    8-(2,5-dimethoxyphenyl)sulfanyl-3-(2-morpholin-4-ylethyl)-7H-purin-3-ium-6-amine
    —— 3-[[2-(2-ethylaziridin-1-yl)-6-methyl-1H-benzimidazol-5-yl]sulfanyl]-6,7-dimethyl-8,9-dihydro-7H-[1,2,4]triazolo[4,3-b]diazepine —— C20H25N7S
    3-[[2-(2-ethylaziridin-1-yl)-6-methyl-1H-benzimidazol-5-yl]sulfanyl]-6,7-dimethyl-8,9-dihydro-7H-[1,2,4]triazolo[4,3-b]diazepine
    —— 2-Methyl-2-[[3-[1-(2-methyl-2-adamantyl)ethyl]-5-methylsulfanylphenyl]methyl]adamantane —— C32H46S
    2-Methyl-2-[[3-[1-(2-methyl-2-adamantyl)ethyl]-5-methylsulfanylphenyl]methyl]adamantane
    —— [4-[3-[Cyclohexylcarbamoyl(3-phenylpropyl)amino]phenyl]sulfanylphenyl] butanoate —— C32H38N2O3S
    [4-[3-[Cyclohexylcarbamoyl(3-phenylpropyl)amino]phenyl]sulfanylphenyl] butanoate
    —— tert-butyl N-[3-(4-chloro-1,3-thiazol-5-yl)-3-(5-cyano-2-methylpyridin-4-yl)sulfanylpropyl]carbamate —— C18H21ClN4O2S2
    tert-butyl N-[3-(4-chloro-1,3-thiazol-5-yl)-3-(5-cyano-2-methylpyridin-4-yl)sulfanylpropyl]carbamate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-pyridin-3-ylmethylideneamino]triazole-4-carboxamide —— C18H14ClN9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-pyridin-3-ylmethylideneamino]triazole-4-carboxamide
    —— 4-[5-(1-methylbenzimidazol-2-yl)sulfanylfuran-2-yl]-5,6,7,8-tetrahydro-1H-pyrazolo[3,4-b][1,7]naphthyridin-5-ol —— C21H18N6O2S
    4-[5-(1-methylbenzimidazol-2-yl)sulfanylfuran-2-yl]-5,6,7,8-tetrahydro-1H-pyrazolo[3,4-b][1,7]naphthyridin-5-ol
    —— ethyl 2-[[(E)-2-cyano-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoyl]amino]-4,5,6,7-tetrahydro-1-benzothiophene-3-carboxylate —— C25H22N2O4S2
    ethyl 2-[[(E)-2-cyano-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoyl]amino]-4,5,6,7-tetrahydro-1-benzothiophene-3-carboxylate
    —— amino-[[2-[2-(carbamimidoylsulfanylmethyl)-4-fluorophenyl]sulfanyl-3-nitrophenyl]methyl]carbamothioic S-acid —— C16H16FN5O3S3
    amino-[[2-[2-(carbamimidoylsulfanylmethyl)-4-fluorophenyl]sulfanyl-3-nitrophenyl]methyl]carbamothioic S-acid
    —— 4,6-dimethyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]pyrimidin-2-amine —— C14H16N4S
    4,6-dimethyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]pyrimidin-2-amine
    —— 4-Ethyl-2-imino-5-methylthiolane-3-carbonitrile —— C8H12N2S
    4-Ethyl-2-imino-5-methylthiolane-3-carbonitrile
    —— 8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-(2-piperidin-4-ylethyl)-7H-purin-3-ium-6-amine —— C19H22BrN6O2S+
    8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-(2-piperidin-4-ylethyl)-7H-purin-3-ium-6-amine