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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[(1S)-1-(5-methylthiophen-2-yl)ethyl]propanamide —— C16H21N3O2S2
    3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[(1S)-1-(5-methylthiophen-2-yl)ethyl]propanamide
    —— 3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[(1R)-1-(5-methylthiophen-2-yl)ethyl]propanamide —— C16H21N3O2S2
    3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[(1R)-1-(5-methylthiophen-2-yl)ethyl]propanamide
    —— 2-(difluoromethylsulfanyl)-N-[[(2S)-1-methylpiperidin-2-yl]methyl]aniline —— C14H20F2N2S
    2-(difluoromethylsulfanyl)-N-[[(2S)-1-methylpiperidin-2-yl]methyl]aniline
    —— (3S)-1-[2-(4-fluorophenyl)sulfanylethyl]piperidine-3-carbaldehyde —— C14H18FNOS
    (3S)-1-[2-(4-fluorophenyl)sulfanylethyl]piperidine-3-carbaldehyde
    —— 1-methyl-3-(2-phenylsulfanylethyl)-1-[(1R)-1-thiophen-2-ylethyl]urea —— C16H20N2OS2
    1-methyl-3-(2-phenylsulfanylethyl)-1-[(1R)-1-thiophen-2-ylethyl]urea
    —— 2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)-N-methoxyethenamine —— C14H16N4OS
    2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)-N-methoxyethenamine
    —— 3-(4-chlorophenyl)sulfanyl-2-(nitrosomethylidene)-5-(trifluoromethyl)-1H-pyridine —— C13H8ClF3N2OS
    3-(4-chlorophenyl)sulfanyl-2-(nitrosomethylidene)-5-(trifluoromethyl)-1H-pyridine
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[3-(furan-2-yl)prop-2-enylideneamino]acetamide —— C18H16N4O2S3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[3-(furan-2-yl)prop-2-enylideneamino]acetamide
    —— (1S,2S)-1-(3-chlorophenyl)sulfanyl-1-pyridin-3-ylpropan-2-amine —— C14H15ClN2S
    (1S,2S)-1-(3-chlorophenyl)sulfanyl-1-pyridin-3-ylpropan-2-amine
    —— (1R,2R)-2-(3-chlorophenyl)sulfanylcyclohexane-1-carbonitrile —— C13H14ClNS
    (1R,2R)-2-(3-chlorophenyl)sulfanylcyclohexane-1-carbonitrile
    —— (2S)-3-(3-chlorophenyl)sulfanyl-2-methylpropan-1-amine —— C10H14ClNS
    (2S)-3-(3-chlorophenyl)sulfanyl-2-methylpropan-1-amine
    —— (1S,2S)-2-(3-chlorophenyl)sulfanylcycloheptane-1-carbonitrile —— C14H16ClNS
    (1S,2S)-2-(3-chlorophenyl)sulfanylcycloheptane-1-carbonitrile
    —— (1S,2R)-1-(3-chlorophenyl)sulfanyl-1-pyridin-3-ylpropan-2-amine —— C14H15ClN2S
    (1S,2R)-1-(3-chlorophenyl)sulfanyl-1-pyridin-3-ylpropan-2-amine
    —— (2S)-2-amino-4-(3-chlorophenyl)sulfanyl-2-methylbutanenitrile —— C11H13ClN2S
    (2S)-2-amino-4-(3-chlorophenyl)sulfanyl-2-methylbutanenitrile
    —— (2R,5S)-5-[(3-chlorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H13ClO3S
    (2R,5S)-5-[(3-chlorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S)-3-(3-chlorophenyl)sulfanyl-2-methyl-2-(propylamino)propanenitrile —— C13H17ClN2S
    (2S)-3-(3-chlorophenyl)sulfanyl-2-methyl-2-(propylamino)propanenitrile
    —— (1S,2S)-2-(3-chlorophenyl)sulfanylcyclohexane-1-carbonitrile —— C13H14ClNS
    (1S,2S)-2-(3-chlorophenyl)sulfanylcyclohexane-1-carbonitrile
    —— (1S,2S)-1-(5-bromothiophen-2-yl)-1-(3-chlorophenyl)sulfanylpropan-2-amine —— C13H13BrClNS2
    (1S,2S)-1-(5-bromothiophen-2-yl)-1-(3-chlorophenyl)sulfanylpropan-2-amine
    —— (1R,2S)-1-(3-chlorophenyl)sulfanyl-1-(5-methylthiophen-2-yl)butan-2-amine —— C15H18ClNS2
    (1R,2S)-1-(3-chlorophenyl)sulfanyl-1-(5-methylthiophen-2-yl)butan-2-amine
    —— 5-chloro-2-(3-chlorophenyl)sulfanyl-N'-hydroxybenzenecarboximidamide —— C13H10Cl2N2OS
    5-chloro-2-(3-chlorophenyl)sulfanyl-N'-hydroxybenzenecarboximidamide
    —— (2S)-1-(3-chlorophenyl)sulfanyl-2-phenylpropan-2-ol —— C15H15ClOS
    (2S)-1-(3-chlorophenyl)sulfanyl-2-phenylpropan-2-ol
    —— (1R,2R)-2-(3-chlorophenyl)sulfanylcycloheptane-1-carbonitrile —— C14H16ClNS
    (1R,2R)-2-(3-chlorophenyl)sulfanylcycloheptane-1-carbonitrile
    —— (2S)-3-(3-chlorophenyl)sulfanyl-2-methyl-2-(methylamino)propanenitrile —— C11H13ClN2S
    (2S)-3-(3-chlorophenyl)sulfanyl-2-methyl-2-(methylamino)propanenitrile
    —— (2R)-3-(3-chlorophenyl)sulfanyl-2-(methylamino)propanenitrile —— C10H11ClN2S
    (2R)-3-(3-chlorophenyl)sulfanyl-2-(methylamino)propanenitrile
    —— (2S)-2-(3-chlorophenyl)sulfanyl-3-hydroxypropanoic acid —— C9H9ClO3S
    (2S)-2-(3-chlorophenyl)sulfanyl-3-hydroxypropanoic acid
    —— (2S,5S)-5-[(3-chlorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H13ClO3S
    (2S,5S)-5-[(3-chlorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S)-2-(3-chlorophenyl)sulfanylpropan-1-amine —— C9H12ClNS
    (2S)-2-(3-chlorophenyl)sulfanylpropan-1-amine
    —— (2R)-2-(3-chlorophenyl)sulfanyl-3-hydroxypropanoic acid —— C9H9ClO3S
    (2R)-2-(3-chlorophenyl)sulfanyl-3-hydroxypropanoic acid
    —— (2R)-2-amino-3-(3-chlorophenyl)sulfanylpropanenitrile —— C9H9ClN2S
    (2R)-2-amino-3-(3-chlorophenyl)sulfanylpropanenitrile
    —— 2-(3-chlorophenyl)sulfanyl-N-[(3R)-2-methyl-4-oxopentan-3-yl]acetamide —— C14H18ClNO2S
    2-(3-chlorophenyl)sulfanyl-N-[(3R)-2-methyl-4-oxopentan-3-yl]acetamide
    —— (2R)-3-(3-chlorophenyl)sulfanyl-2-methyl-2-(propylamino)propanenitrile —— C13H17ClN2S
    (2R)-3-(3-chlorophenyl)sulfanyl-2-methyl-2-(propylamino)propanenitrile
    —— N-[(4-fluorophenyl)methoxy]-2-(6-methyl-3-prop-2-enylsulfanyl-1,2,4-triazin-5-yl)ethenamine —— C16H17FN4OS
    N-[(4-fluorophenyl)methoxy]-2-(6-methyl-3-prop-2-enylsulfanyl-1,2,4-triazin-5-yl)ethenamine
    —— N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C16H21F3N2O3S2
    N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— N-[(3S)-1-amino-1-sulfanylidenepentan-3-yl]-2-cyclohexylacetamide —— C13H24N2OS
    N-[(3S)-1-amino-1-sulfanylidenepentan-3-yl]-2-cyclohexylacetamide
    —— 2-[3-[(4-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-yl]-N-[(4-fluorophenyl)methoxy]ethenamine —— C20H18ClFN4OS
    2-[3-[(4-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-yl]-N-[(4-fluorophenyl)methoxy]ethenamine
    —— 6-Oxo-5-[[4-[4-[2-(2-oxo-6-sulfonaphthalen-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2-sulfonic acid —— C32H22N4O8S3
    6-Oxo-5-[[4-[4-[2-(2-oxo-6-sulfonaphthalen-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2-sulfonic acid
    —— 2-[(1H-1,2,4-triazol-5-ylamino)methylidene]-1-benzothiophen-3-one —— C11H8N4OS
    2-[(1H-1,2,4-triazol-5-ylamino)methylidene]-1-benzothiophen-3-one
    —— 2-[(4-cyclopropyl-5-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-methylphenyl)methyl]-N-propylacetamide —— C21H30N4OS
    2-[(4-cyclopropyl-5-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-methylphenyl)methyl]-N-propylacetamide
    —— (2R)-N-(furan-2-ylmethyl)-2-[[4-(furan-2-ylmethyl)-5-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C18H22N4O3S
    (2R)-N-(furan-2-ylmethyl)-2-[[4-(furan-2-ylmethyl)-5-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-2-[[4-(furan-2-ylmethyl)-5-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]propanamide —— C21H26N4O2S
    (2S)-2-[[4-(furan-2-ylmethyl)-5-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]propanamide
    —— 2-[(1S)-1-[[4-(furan-2-ylmethyl)-5-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole —— C21H23N5O2S
    2-[(1S)-1-[[4-(furan-2-ylmethyl)-5-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole
    —— (2R)-1-(4-ethylpiperazin-1-yl)-2-[[4-(furan-2-ylmethyl)-5-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C19H29N5O2S
    (2R)-1-(4-ethylpiperazin-1-yl)-2-[[4-(furan-2-ylmethyl)-5-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— 2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-methylmorpholin-4-yl]ethanone —— C18H24N4O2S
    2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-methylmorpholin-4-yl]ethanone
    —— 2-[(3-methylanilino)methylidene]-1-benzothiophen-3-one —— C16H13NOS
    2-[(3-methylanilino)methylidene]-1-benzothiophen-3-one
    —— N-[(1R)-1-(furan-2-yl)propyl]-2-prop-2-enylsulfanylaniline —— C16H19NOS
    N-[(1R)-1-(furan-2-yl)propyl]-2-prop-2-enylsulfanylaniline
    —— 2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-methylmorpholin-4-yl]ethanone —— C18H24N4O2S
    2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-methylmorpholin-4-yl]ethanone
    —— N-[(3-fluorophenyl)methoxy]-2-(6-methyl-3-methylsulfanyl-1,2,4-triazin-5-yl)ethenamine —— C14H15FN4OS
    N-[(3-fluorophenyl)methoxy]-2-(6-methyl-3-methylsulfanyl-1,2,4-triazin-5-yl)ethenamine
    —— 2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)-N-[(4-fluorophenyl)methoxy]ethenamine —— C20H19FN4OS
    2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)-N-[(4-fluorophenyl)methoxy]ethenamine
    —— 6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2,4-dinitrocyclohexa-2,4-dien-1-one —— C18H15N5O5S
    6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2,4-dinitrocyclohexa-2,4-dien-1-one
    —— 2-[1-(2-methylanilino)ethylidene]-1-benzothiophen-3-one —— C17H15NOS
    2-[1-(2-methylanilino)ethylidene]-1-benzothiophen-3-one