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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2,6-Dichloro-4-[4-(trifluoromethoxy)phenyl]sulfanylphenyl]hydrazine —— C13H9Cl2F3N2OS
    [2,6-Dichloro-4-[4-(trifluoromethoxy)phenyl]sulfanylphenyl]hydrazine
    —— 1,3-Dichloro-5-(2,6-dichlorophenyl)sulfanyl-2-nitrobenzene —— C12H5Cl4NO2S
    1,3-Dichloro-5-(2,6-dichlorophenyl)sulfanyl-2-nitrobenzene
    —— 1,3-Dichloro-2-nitro-5-[4-(trifluoromethoxy)phenyl]sulfanylbenzene —— C13H6Cl2F3NO3S
    1,3-Dichloro-2-nitro-5-[4-(trifluoromethoxy)phenyl]sulfanylbenzene
    —— [2,6-Dichloro-4-(3,5-dimethylphenyl)sulfanylphenyl]hydrazine —— C14H14Cl2N2S
    [2,6-Dichloro-4-(3,5-dimethylphenyl)sulfanylphenyl]hydrazine
    —— 2,6-Dichloro-4-(2-chloro-4-fluorophenyl)sulfanylaniline —— C12H7Cl3FNS
    2,6-Dichloro-4-(2-chloro-4-fluorophenyl)sulfanylaniline
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2,5-difluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C19H14F2N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2,5-difluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 3-Ethylsulfanyl-4-methyl-1,2-thiazole —— C6H9NS2
    3-Ethylsulfanyl-4-methyl-1,2-thiazole
    —— 3-Ethylsulfanyl-5-methyl-1,2-thiazole —— C6H9NS2
    3-Ethylsulfanyl-5-methyl-1,2-thiazole
    —— (3Z)-1-(disulfanyl)hexa-3,5-dien-1-amine —— C6H11NS2
    (3Z)-1-(disulfanyl)hexa-3,5-dien-1-amine
    —— Methyl 6-[2-(3-chloro-5-methylpyridin-2-yl)sulfanylethyl]-2-hydroxy-4-oxocyclohex-2-ene-1-carboxylate —— C16H18ClNO4S
    Methyl 6-[2-(3-chloro-5-methylpyridin-2-yl)sulfanylethyl]-2-hydroxy-4-oxocyclohex-2-ene-1-carboxylate
    —— [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-3-oxocyclohexen-1-yl] 2,2-dimethylpropanoate —— C30H39NO3S
    [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-3-oxocyclohexen-1-yl] 2,2-dimethylpropanoate
    —— 2-(2-Chlorophenyl)-3-hydroxy-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]cyclohex-2-en-1-one —— C20H20ClNO2S
    2-(2-Chlorophenyl)-3-hydroxy-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]cyclohex-2-en-1-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-bromophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C19H15BrN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-bromophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-3-oxocyclohexen-1-yl] propanoate —— C28H35NO3S
    [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-3-oxocyclohexen-1-yl] propanoate
    —— [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-3-oxocyclohexen-1-yl] ethyl carbonate —— C28H35NO4S
    [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-3-oxocyclohexen-1-yl] ethyl carbonate
    —— 2,2-Dimethyl-3-(4-methylphenyl)sulfanylpropan-1-ol —— C12H18OS
    2,2-Dimethyl-3-(4-methylphenyl)sulfanylpropan-1-ol
    —— Methyl 2-hydroxy-6-[1-[(4-methylphenyl)sulfanylmethyl]cyclopropyl]-4-oxocyclohex-2-ene-1-carboxylate —— C19H22O4S
    Methyl 2-hydroxy-6-[1-[(4-methylphenyl)sulfanylmethyl]cyclopropyl]-4-oxocyclohex-2-ene-1-carboxylate
    —— (E)-4-[1-[(4-methylphenyl)sulfanylmethyl]cyclopropyl]but-3-en-2-one —— C15H18OS
    (E)-4-[1-[(4-methylphenyl)sulfanylmethyl]cyclopropyl]but-3-en-2-one
    —— (E)-5,5-dimethyl-6-(4-methylphenyl)sulfanylhex-3-en-2-one —— C15H20OS
    (E)-5,5-dimethyl-6-(4-methylphenyl)sulfanylhex-3-en-2-one
    —— [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(4-methylphenyl)sulfanylethyl]-3-oxocyclohexen-1-yl] propanoate —— C29H36O3S
    [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(4-methylphenyl)sulfanylethyl]-3-oxocyclohexen-1-yl] propanoate
    —— 3-Hydroxy-5-[1-[(4-methylphenyl)sulfanylmethyl]cyclopropyl]cyclohex-2-en-1-one —— C17H20O2S
    3-Hydroxy-5-[1-[(4-methylphenyl)sulfanylmethyl]cyclopropyl]cyclohex-2-en-1-one
    —— [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(4-methylphenyl)sulfanylethyl]-3-oxocyclohexen-1-yl] ethyl carbonate —— C29H36O4S
    [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(4-methylphenyl)sulfanylethyl]-3-oxocyclohexen-1-yl] ethyl carbonate
    —— [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-3-oxocyclohexen-1-yl] prop-2-enyl carbonate —— C29H35NO4S
    [2-(2,6-Diethyl-4-methylphenyl)-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-3-oxocyclohexen-1-yl] prop-2-enyl carbonate
    —— Methyl 2-hydroxy-6-[2-(5-methylpyridin-2-yl)sulfanylethyl]-4-oxocyclohex-2-ene-1-carboxylate —— C16H19NO4S
    Methyl 2-hydroxy-6-[2-(5-methylpyridin-2-yl)sulfanylethyl]-4-oxocyclohex-2-ene-1-carboxylate
    —— Methyl 6-[2-(4-chlorophenyl)sulfanylethyl]-2-hydroxy-4-oxocyclohex-2-ene-1-carboxylate —— C16H17ClO4S
    Methyl 6-[2-(4-chlorophenyl)sulfanylethyl]-2-hydroxy-4-oxocyclohex-2-ene-1-carboxylate
    —— 2-(2-Cyclopropylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one —— C24H26O2S
    2-(2-Cyclopropylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— 2-(2-Ethynyl-4,6-dimethylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one —— C25H26O2S
    2-(2-Ethynyl-4,6-dimethylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— Methyl 2-hydroxy-4-oxo-6-(2-phenylsulfanylethyl)cyclohex-2-ene-1-carboxylate —— C16H18O4S
    Methyl 2-hydroxy-4-oxo-6-(2-phenylsulfanylethyl)cyclohex-2-ene-1-carboxylate
    —— phenyl 3-amino-1-methyl-2-(2-methylpropyl)-5-oxo-N-[(1-propan-2-ylpiperidin-4-yl)methyl]pyrazole-4-carboximidothioate —— C24H37N5OS
    phenyl 3-amino-1-methyl-2-(2-methylpropyl)-5-oxo-N-[(1-propan-2-ylpiperidin-4-yl)methyl]pyrazole-4-carboximidothioate
    —— phenyl 3-amino-N-[[4-(dimethylamino)phenyl]methyl]-1-methyl-2-(2-methylpropyl)-5-oxopyrazole-4-carboximidothioate —— C24H31N5OS
    phenyl 3-amino-N-[[4-(dimethylamino)phenyl]methyl]-1-methyl-2-(2-methylpropyl)-5-oxopyrazole-4-carboximidothioate
    —— (E)-5-[(5-methylpyridin-2-yl)sulfanylmethyl]hept-3-en-2-one —— C14H19NOS
    (E)-5-[(5-methylpyridin-2-yl)sulfanylmethyl]hept-3-en-2-one
    —— 2-(2-Bromophenyl)-3-hydroxy-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]cyclohex-2-en-1-one —— C20H20BrNO2S
    2-(2-Bromophenyl)-3-hydroxy-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]cyclohex-2-en-1-one
    —— 2-(2,6-Diethyl-4-methylphenyl)-3-(methoxymethoxy)-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one —— C28H36O3S
    2-(2,6-Diethyl-4-methylphenyl)-3-(methoxymethoxy)-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— 2-(2-Ethylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one —— C23H26O2S
    2-(2-Ethylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— Methyl 2-hydroxy-6-[2-(4-methylphenyl)sulfanylethyl]-4-oxocyclohex-2-ene-1-carboxylate —— C17H20O4S
    Methyl 2-hydroxy-6-[2-(4-methylphenyl)sulfanylethyl]-4-oxocyclohex-2-ene-1-carboxylate
    —— 3-Hydroxy-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-2-(2,4,6-trimethylphenyl)cyclohex-2-en-1-one —— C23H27NO2S
    3-Hydroxy-5-[2-(5-methylpyridin-2-yl)sulfanylethyl]-2-(2,4,6-trimethylphenyl)cyclohex-2-en-1-one
    —— 2-[(5-Methylpyridin-2-yl)sulfanylmethyl]butanal —— C11H15NOS
    2-[(5-Methylpyridin-2-yl)sulfanylmethyl]butanal
    —— 2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[1-[(5-methylpyridin-2-yl)sulfanylmethyl]cyclopropyl]cyclohex-2-en-1-one —— C27H33NO2S
    2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[1-[(5-methylpyridin-2-yl)sulfanylmethyl]cyclopropyl]cyclohex-2-en-1-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-fluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C19H15FN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-fluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[2-(4-hydroxyphenyl)sulfanylethyl]cyclohex-2-en-1-one 1415577-28-4 C25H30O3S
    2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[2-(4-hydroxyphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— 3-Hydroxy-5-[1-(5-methylpyridin-2-yl)sulfanylpropan-2-yl]cyclohex-2-en-1-one —— C15H19NO2S
    3-Hydroxy-5-[1-(5-methylpyridin-2-yl)sulfanylpropan-2-yl]cyclohex-2-en-1-one
    —— (E)-6-(4-methylphenyl)sulfanylhept-3-en-2-one —— C14H18OS
    (E)-6-(4-methylphenyl)sulfanylhept-3-en-2-one
    —— 2-(2-Bromophenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one —— C21H21BrO2S
    2-(2-Bromophenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— 2-(2-Ethynylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one —— C23H22O2S
    2-(2-Ethynylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— 3-(5-Methylpyridin-2-yl)sulfanylpropanal —— C9H11NOS
    3-(5-Methylpyridin-2-yl)sulfanylpropanal
    —— 3-Hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]-2-(2,4,6-trimethylphenyl)cyclohex-2-en-1-one —— C24H28O2S
    3-Hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]-2-(2,4,6-trimethylphenyl)cyclohex-2-en-1-one
    —— 6-O-butyl 1-O-methyl 2-(pyridin-2-ylsulfanylmethyl)hexanedioate —— C17H25NO4S
    6-O-butyl 1-O-methyl 2-(pyridin-2-ylsulfanylmethyl)hexanedioate
    —— 2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[1-[(4-methylphenyl)sulfanylmethyl]cyclopropyl]cyclohex-2-en-1-one —— C28H34O2S
    2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[1-[(4-methylphenyl)sulfanylmethyl]cyclopropyl]cyclohex-2-en-1-one
    —— 2-Methyl-3-(5-methylpyridin-2-yl)sulfanylpropanal —— C10H13NOS
    2-Methyl-3-(5-methylpyridin-2-yl)sulfanylpropanal
    —— 2-Sulfanyloxybut-1-ene —— C4H8OS
    2-Sulfanyloxybut-1-ene