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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(4-bromophenyl)sulfanylcyclohexan-1-one —— C12H13BrOS
    (2S)-2-(4-bromophenyl)sulfanylcyclohexan-1-one
    —— (2R)-2-methyl-3-(4-methylphenyl)sulfanylpropan-1-amine —— C11H17NS
    (2R)-2-methyl-3-(4-methylphenyl)sulfanylpropan-1-amine
    —— 1-[(3R,3aR,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C21H21N5O3S
    1-[(3R,3aR,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— [(3R)-1-(3-phenylsulfanylpyrazin-2-yl)piperidin-3-yl]-pyrrolidin-1-ylmethanone —— C20H24N4OS
    [(3R)-1-(3-phenylsulfanylpyrazin-2-yl)piperidin-3-yl]-pyrrolidin-1-ylmethanone
    —— (2S)-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]butanedioate —— C6H4N2O4S3-2
    (2S)-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]butanedioate
    —— (1R)-3-morpholin-4-yl-1-(4-phenylsulfanylphenyl)propan-1-ol —— C19H23NO2S
    (1R)-3-morpholin-4-yl-1-(4-phenylsulfanylphenyl)propan-1-ol
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-heptan-2-yl]acetamide —— C17H22BrN3O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-heptan-2-yl]acetamide
    —— (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C12H12BrN3O2S
    (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(2-methylphenyl)ethyl]acetamide —— C25H33N5OS
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(2-methylphenyl)ethyl]acetamide
    —— N-[(2R)-heptan-2-yl]-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H30N4O2S2
    N-[(2R)-heptan-2-yl]-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[(S)-phenyl(pyridin-2-yl)methyl]acetamide —— C20H16F2N2OS
    2-(3,4-difluorophenyl)sulfanyl-N-[(S)-phenyl(pyridin-2-yl)methyl]acetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[(R)-phenyl(pyridin-2-yl)methyl]acetamide —— C20H16F2N2OS
    2-(3,4-difluorophenyl)sulfanyl-N-[(R)-phenyl(pyridin-2-yl)methyl]acetamide
    —— (1S)-N-[2-(4-chlorophenyl)sulfanylethyl]-1-methyl-3,4-dihydro-1H-pyrrolo[1,2-a]pyrazine-2-carbothioamide —— C17H20ClN3S2
    (1S)-N-[2-(4-chlorophenyl)sulfanylethyl]-1-methyl-3,4-dihydro-1H-pyrrolo[1,2-a]pyrazine-2-carbothioamide
    —— 2-[[5-cyclopropyl-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(S)-(4-methylphenyl)-thiophen-2-ylmethyl]acetamide —— C24H24N4O2S2
    2-[[5-cyclopropyl-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(S)-(4-methylphenyl)-thiophen-2-ylmethyl]acetamide
    —— 1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-1-yl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]ethanone —— C20H25N3O3S3
    1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-1-yl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]ethanone
    —— ethyl 4-[(2R)-2-[(4-fluorophenyl)sulfanylmethyl]-1,3-thiazolidin-3-yl]-4-oxobutanoate —— C16H20FNO3S2
    ethyl 4-[(2R)-2-[(4-fluorophenyl)sulfanylmethyl]-1,3-thiazolidin-3-yl]-4-oxobutanoate
    —— 1-(5-ethylthiophen-2-yl)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C19H21N3O2S3
    1-(5-ethylthiophen-2-yl)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— 2-[3-(Trifluoromethylsulfanyl)phenyl]acetate —— C9H6F3O2S-
    2-[3-(Trifluoromethylsulfanyl)phenyl]acetate
    —— 4-[(1R)-1-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]pyrimidin-2-amine —— C12H10ClF3N4S
    4-[(1R)-1-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]pyrimidin-2-amine
    —— methyl (5R)-5-bromo-4-(4-chlorophenyl)sulfanyl-2,5-dihydrothiophene-3-carboxylate —— C12H10BrClO2S2
    methyl (5R)-5-bromo-4-(4-chlorophenyl)sulfanyl-2,5-dihydrothiophene-3-carboxylate
    —— 3-{[(3,5-dimethyl-4-nitro-1H-pyrazol-1-yl)methyl]sulfanyl}-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine —— C9H10F3N7O2S
    3-{[(3,5-dimethyl-4-nitro-1H-pyrazol-1-yl)methyl]sulfanyl}-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine
    —— 3-(ethylsulfanyl)-4H-1,2,4-triazol-4-amine —— C4H8N4S
    3-(ethylsulfanyl)-4H-1,2,4-triazol-4-amine
    —— 3-{[(3,5-dimethyl-4-nitro-1H-pyrazol-1-yl)methyl]sulfanyl}-4H-1,2,4-triazol-4-amine —— C8H11N7O2S
    3-{[(3,5-dimethyl-4-nitro-1H-pyrazol-1-yl)methyl]sulfanyl}-4H-1,2,4-triazol-4-amine
    —— Methyl 2-((4-methyl-5-((3-methyl-1H-pyrazol-1-yl)methyl)-4H-1,2,4-triazol-3-yl)thio)acetate —— C11H15N5O2S
    Methyl 2-((4-methyl-5-((3-methyl-1H-pyrazol-1-yl)methyl)-4H-1,2,4-triazol-3-yl)thio)acetate
    —— 3-[(4-chlorobenzyl)sulfanyl]-4-ethyl-5-(thiophen-2-yl)-4H-1,2,4-triazole —— C15H14ClN3S2
    3-[(4-chlorobenzyl)sulfanyl]-4-ethyl-5-(thiophen-2-yl)-4H-1,2,4-triazole
    —— Methyl ([4-ethyl-5-(1-methyl-1H-pyrazol-5-YL)-4H-1,2,4-triazol-3-YL]thio)+ 1001519-15-8 C11H15N5O2S
    Methyl ([4-ethyl-5-(1-methyl-1H-pyrazol-5-YL)-4H-1,2,4-triazol-3-YL]thio)+
    —— 2-{[4-amino-5-(trifluoromethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetic acid 832738-11-1 C5H5F3N4O2S
    2-{[4-amino-5-(trifluoromethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetic acid
    —— 3-{[(3,5-dimethyl-4-nitro-1H-pyrazol-1-yl)methyl]sulfanyl}-5-methyl-4H-1,2,4-triazol-4-amine 1001519-09-0 C9H13N7O2S
    3-{[(3,5-dimethyl-4-nitro-1H-pyrazol-1-yl)methyl]sulfanyl}-5-methyl-4H-1,2,4-triazol-4-amine
    —— 2-[[4-Amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C5H4F3N4O2S-
    2-[[4-Amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[5-(1-ethylpyrazol-3-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C14H19N5O3S
    2-[[5-(1-ethylpyrazol-3-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[4-(1-Ethyl-3-methylpyrazol-4-yl)pyrimidin-2-yl]sulfanylacetate —— C12H13N4O2S-
    2-[4-(1-Ethyl-3-methylpyrazol-4-yl)pyrimidin-2-yl]sulfanylacetate
    —— 2-[[5-(1-ethylpyrazol-3-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C14H18N5O3S-
    2-[[5-(1-ethylpyrazol-3-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 1-(2-Methylbutylsulfanyl)propane-2-thiol —— C8H18S2
    1-(2-Methylbutylsulfanyl)propane-2-thiol
    —— (2R)-2-(1-methyltetrazol-5-yl)sulfanylpropanoate —— C5H7N4O2S-
    (2R)-2-(1-methyltetrazol-5-yl)sulfanylpropanoate
    —— 2-(Oxiran-2-ylidenemethylsulfonyl)propanedinitrile —— C6H4N2O3S
    2-(Oxiran-2-ylidenemethylsulfonyl)propanedinitrile
    —— [4-[3-[Butylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C29H34N2O3S
    [4-[3-[Butylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 3-((4-(Furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl)thio)propanoyl chloride —— C12H8ClF3N2O2S
    3-((4-(Furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl)thio)propanoyl chloride
    —— 2,6-Bis[(6-methylpyridin-2-yl)sulfanylmethyl]pyridine —— C19H19N3S2
    2,6-Bis[(6-methylpyridin-2-yl)sulfanylmethyl]pyridine
    —— 2-[(4-Bromocyclohexa-1,3-dien-5-yn-1-yl)-phenylmethyl]sulfanyl-3-(chloromethyl)pyridine —— C19H13BrClNS
    2-[(4-Bromocyclohexa-1,3-dien-5-yn-1-yl)-phenylmethyl]sulfanyl-3-(chloromethyl)pyridine
    —— [(1R)-3-hydroxy-1-(4-methylsulfanylphenyl)propyl]azanium —— C10H16NOS+
    [(1R)-3-hydroxy-1-(4-methylsulfanylphenyl)propyl]azanium
    —— 2-{[5-(1,5-Dimethyl-1H-pyrazol-3-YL)-4-isobutyl-4H-1,2,4-triazol-3-YL]thio}acetohydrazide —— C13H21N7OS
    2-{[5-(1,5-Dimethyl-1H-pyrazol-3-YL)-4-isobutyl-4H-1,2,4-triazol-3-YL]thio}acetohydrazide
    —— 1-Sulfonylhex-3-ene —— C6H10O2S
    1-Sulfonylhex-3-ene
    —— (3-methyl-4-methylsulfanyl-N-propan-2-ylanilino)phosphonic acid —— C11H18NO3PS
    (3-methyl-4-methylsulfanyl-N-propan-2-ylanilino)phosphonic acid
    —— methyl (3R)-3-isocyanato-3-(4-methylsulfanylphenyl)propanoate —— C12H13NO3S
    methyl (3R)-3-isocyanato-3-(4-methylsulfanylphenyl)propanoate
    —— 5-ethyl-4-methylsulfanyl-3H-1,3-oxazol-2-one —— C6H9NO2S
    5-ethyl-4-methylsulfanyl-3H-1,3-oxazol-2-one
    —— (2S)-1,2-dibromo-3-isothiocyanatopropane —— C4H5Br2NS
    (2S)-1,2-dibromo-3-isothiocyanatopropane
    —— (S)-(+)-2-Octyl isothiocyanate 737761-98-7 C9H17NS
    (S)-(+)-2-Octyl isothiocyanate
    —— (2R)-1-(4-chlorophenyl)sulfanylpropan-2-ol —— C9H11ClOS
    (2R)-1-(4-chlorophenyl)sulfanylpropan-2-ol
    —— (2S)-2-isothiocyanatopentane —— C6H11NS
    (2S)-2-isothiocyanatopentane
    —— [3-(3-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H17ClNS+
    [3-(3-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium