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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanenitrile —— C13H14N4S2
    (2S)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanenitrile
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide —— C18H20N4OS3
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide
    —— N-(2,4-dimethylphenyl)-5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C16H21N3OS2
    N-(2,4-dimethylphenyl)-5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— Propan-2-yl 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C15H19N3O2S2
    Propan-2-yl 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H23N5OS2
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 4-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-diethylbutanamide —— C18H26N4OS2
    4-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-diethylbutanamide
    —— (2R)-N-cyclopentyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H24N4OS2
    (2R)-N-cyclopentyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-(2,4-dimethylphenyl)-5-(2-methylsulfanylethylsulfanyl)-1,3,4-thiadiazol-2-amine —— C13H17N3S3
    N-(2,4-dimethylphenyl)-5-(2-methylsulfanylethylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— (2S)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)propanamide —— C18H20N4O2S2
    (2S)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)propanamide
    —— 1-[[5-(2,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3,3-dimethylbutan-2-one —— C16H21N3OS2
    1-[[5-(2,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3,3-dimethylbutan-2-one
    —— N-(2,4-dimethylphenyl)-5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C15H19N3O2S2
    N-(2,4-dimethylphenyl)-5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2S)-N-benzyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H22N4OS2
    (2S)-N-benzyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C15H20N4O2S2
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— N'-acetyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetohydrazide —— C14H17N5O2S2
    N'-acetyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetohydrazide
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-diethylacetamide —— C16H22N4OS2
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-diethylacetamide
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)acetamide —— C18H26N4OS2
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)acetamide
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide —— C19H19FN4OS2
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide
    —— N-(2-cyanoethyl)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H17N5OS2
    N-(2-cyanoethyl)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-N-benzyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H22N4OS2
    (2R)-N-benzyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)acetamide —— C16H22N4O2S2
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)acetamide
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C18H20N4OS3
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— N-[(2S)-butan-2-yl]-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H22N4OS2
    N-[(2S)-butan-2-yl]-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-(2,4-dimethylphenyl)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C14H15N5OS2
    N-(2,4-dimethylphenyl)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)acetamide —— C18H24N4OS2
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)acetamide
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C16H20N4O3S3
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[[5-(2,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-thiophen-2-ylethanone —— C16H15N3OS3
    2-[[5-(2,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-thiophen-2-ylethanone
    —— 1-[2-[[5-(2,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]pyrrolidin-2-one —— C16H18N4O2S2
    1-[2-[[5-(2,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]pyrrolidin-2-one
    —— 4-[[5-(2,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile —— C14H16N4S2
    4-[[5-(2,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C17H24N4OS2
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— N-benzyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide —— C20H22N4OS2
    N-benzyl-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C16H20N4O3S3
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— (2R)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanenitrile —— C13H14N4S2
    (2R)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanenitrile
    —— 6-(2,5-dimethylphenyl)-3-[(2R)-2-phenylpropyl]-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C21H22N4S
    6-(2,5-dimethylphenyl)-3-[(2R)-2-phenylpropyl]-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— N-[(R)-(4-chlorophenyl)sulfanyl-[4-(dimethylamino)phenyl]methyl]pyridin-3-amine —— C20H20ClN3S
    N-[(R)-(4-chlorophenyl)sulfanyl-[4-(dimethylamino)phenyl]methyl]pyridin-3-amine
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylpropanamide —— C16H23NO3S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylpropanamide
    —— (2R)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-propan-2-ylpropanamide —— C11H16N2O2S
    (2R)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-propan-2-ylpropanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylpropanamide —— C16H23NO3S2
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylpropanamide
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylpropanamide —— C16H23NO3S2
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylpropanamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylpropanamide —— C16H23NO3S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-(4-methylphenyl)sulfanylpropanamide
    —— (2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-propan-2-ylpropanamide —— C11H16N2O2S
    (2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-propan-2-ylpropanamide
    —— (3R,5R)-1-[4-(furan-2-ylmethyl)-5-(2-methylprop-2-enylsulfanyl)-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine —— C18H26N4OS
    (3R,5R)-1-[4-(furan-2-ylmethyl)-5-(2-methylprop-2-enylsulfanyl)-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine
    —— [(2R)-oxan-2-yl]methyl 3-(3,4-dimethylphenyl)sulfanylpropanoate —— C17H24O3S
    [(2R)-oxan-2-yl]methyl 3-(3,4-dimethylphenyl)sulfanylpropanoate
    —— 1-[4-[(2S)-6-methyl-2,3-dihydro-1-benzothiophene-2-carbonyl]piperazin-1-yl]ethanone —— C16H20N2O2S
    1-[4-[(2S)-6-methyl-2,3-dihydro-1-benzothiophene-2-carbonyl]piperazin-1-yl]ethanone
    —— 1-[4-[(2R)-6-methyl-2,3-dihydro-1-benzothiophene-2-carbonyl]piperazin-1-yl]ethanone —— C16H20N2O2S
    1-[4-[(2R)-6-methyl-2,3-dihydro-1-benzothiophene-2-carbonyl]piperazin-1-yl]ethanone
    —— (2S)-2-[[5-[4-(diethylamino)phenyl]-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one —— C20H28N4OS
    (2S)-2-[[5-[4-(diethylamino)phenyl]-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one
    —— 3-(3,4-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-propylpropanamide —— C18H27NO3S2
    3-(3,4-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-propylpropanamide