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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-[(2R)-1-methylpyrrolidin-2-yl]pyrrolidin-1-yl]methanone —— C18H24N2O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-[(2R)-1-methylpyrrolidin-2-yl]pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(2R)-1-methylpyrrolidin-2-yl]pyrrolidin-1-yl]methanone —— C18H24N2OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(2R)-1-methylpyrrolidin-2-yl]pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-[(3,5-dimethylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C19H23N3OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-[(3,5-dimethylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-[(2S)-1-methylpyrrolidin-2-yl]pyrrolidin-1-yl]methanone —— C18H24N2O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-[(2S)-1-methylpyrrolidin-2-yl]pyrrolidin-1-yl]methanone
    —— (2S)-2-[[5-[(2S)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C8H12N4O2S3
    (2S)-2-[[5-[(2S)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-[(2R)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C8H12N4O2S3
    (2S)-2-[[5-[(2R)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C16H22N4OS
    (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C16H22N4OS
    (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— 2-[[5-[2-oxo-2-[[(2R)-pentan-2-yl]amino]ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-pentan-2-yl]acetamide —— C16H28N4O2S3
    2-[[5-[2-oxo-2-[[(2R)-pentan-2-yl]amino]ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-pentan-2-yl]acetamide
    —— 2-[[5-[2-oxo-2-[[(2R)-pentan-2-yl]amino]ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-pentan-2-yl]acetamide —— C16H28N4O2S3
    2-[[5-[2-oxo-2-[[(2R)-pentan-2-yl]amino]ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-pentan-2-yl]acetamide
    —— (7S)-3-tert-butyl-6-(4-chlorophenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C15H17ClN4S
    (7S)-3-tert-butyl-6-(4-chlorophenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— N-[(2S)-butan-2-yl]-2-(2-chlorophenyl)sulfanylpyridine-3-carboxamide —— C16H17ClN2OS
    N-[(2S)-butan-2-yl]-2-(2-chlorophenyl)sulfanylpyridine-3-carboxamide
    —— (7R)-3-tert-butyl-6-(4-chlorophenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C15H17ClN4S
    (7R)-3-tert-butyl-6-(4-chlorophenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(3,5-dimethylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C19H23N3OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(3,5-dimethylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(3,5-dimethylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C19H23N3OS
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(3,5-dimethylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 2-amino-4-chlorobenzoate —— C21H17ClN2O3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 2-amino-4-chlorobenzoate
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]acetamide —— C13H23N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]acetamide
    —— N-[(2S)-butan-2-yl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C13H17F3N2OS
    N-[(2S)-butan-2-yl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 2-[[4-(4-fluorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide —— C16H19FN2OS2
    2-[[4-(4-fluorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— (7R)-3-cyclohexyl-6-(3,4-difluorophenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C17H18F2N4S
    (7R)-3-cyclohexyl-6-(3,4-difluorophenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]acetamide —— C13H23N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]acetamide —— C13H23N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]acetamide
    —— N-[(2R)-butan-2-yl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C13H17F3N2OS
    N-[(2R)-butan-2-yl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 2-[[4-(4-fluorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C16H19FN2OS2
    2-[[4-(4-fluorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— N-(2-methoxyethyl)-5-[(1S)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C13H15N5O2S3
    N-(2-methoxyethyl)-5-[(1S)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— (3-Cyano-4-imino-2-oxopentyl) 2-(4-bromophenyl)sulfanylacetate —— C14H13BrN2O3S
    (3-Cyano-4-imino-2-oxopentyl) 2-(4-bromophenyl)sulfanylacetate
    —— 3-(2-fluorophenyl)sulfanyl-N-[(2S)-2-(4-methylpiperazin-1-yl)propyl]propanamide —— C17H26FN3OS
    3-(2-fluorophenyl)sulfanyl-N-[(2S)-2-(4-methylpiperazin-1-yl)propyl]propanamide
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(furan-2-yl)ethyl]-N-methylacetamide —— C19H22N4O2S
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(furan-2-yl)ethyl]-N-methylacetamide
    —— 3-(2-fluorophenyl)sulfanyl-N-[(2R)-2-(4-methylpiperazin-1-yl)propyl]propanamide —— C17H26FN3OS
    3-(2-fluorophenyl)sulfanyl-N-[(2R)-2-(4-methylpiperazin-1-yl)propyl]propanamide
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(furan-2-yl)ethyl]-N-methylacetamide —— C19H22N4O2S
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(furan-2-yl)ethyl]-N-methylacetamide
    —— N-[(1S)-1-(furan-2-yl)ethyl]-N-methyl-2-phenylsulfanylacetamide —— C15H17NO2S
    N-[(1S)-1-(furan-2-yl)ethyl]-N-methyl-2-phenylsulfanylacetamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[(2R)-2-(4-methylpiperazin-1-yl)propyl]propanamide —— C17H26FN3OS
    3-(4-fluorophenyl)sulfanyl-N-[(2R)-2-(4-methylpiperazin-1-yl)propyl]propanamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[(2S)-2-(4-methylpiperazin-1-yl)propyl]propanamide —— C17H26FN3OS
    3-(4-fluorophenyl)sulfanyl-N-[(2S)-2-(4-methylpiperazin-1-yl)propyl]propanamide
    —— N-[(1R)-1-(furan-2-yl)ethyl]-N-methyl-2-phenylsulfanylacetamide —— C15H17NO2S
    N-[(1R)-1-(furan-2-yl)ethyl]-N-methyl-2-phenylsulfanylacetamide
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2R)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone —— C17H19N3OS
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone —— C17H19N3OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone —— C17H19N3OS
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone —— C17H19N3OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(pyrazol-1-ylmethyl)pyrrolidin-1-yl]methanone
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-3-(4-fluorophenyl)sulfanyl-N-methylpropanamide —— C18H19ClFNOS
    N-[(1R)-1-(3-chlorophenyl)ethyl]-3-(4-fluorophenyl)sulfanyl-N-methylpropanamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[(1S,3S)-3-methylcyclohexyl]propanamide —— C16H22FNOS
    3-(4-fluorophenyl)sulfanyl-N-[(1S,3S)-3-methylcyclohexyl]propanamide
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-3-(4-fluorophenyl)sulfanyl-N-methylpropanamide —— C18H19ClFNOS
    N-[(1S)-1-(3-chlorophenyl)ethyl]-3-(4-fluorophenyl)sulfanyl-N-methylpropanamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[(1R,3R)-3-methylcyclohexyl]propanamide —— C16H22FNOS
    3-(4-fluorophenyl)sulfanyl-N-[(1R,3R)-3-methylcyclohexyl]propanamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[(1S,3R)-3-methylcyclohexyl]propanamide —— C16H22FNOS
    3-(4-fluorophenyl)sulfanyl-N-[(1S,3R)-3-methylcyclohexyl]propanamide