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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-(cyclopentylamino)-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C21H23NO3S
    [2-(cyclopentylamino)-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— (3R,5R)-1-[4-(furan-2-ylmethyl)-5-propan-2-ylsulfanyl-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine —— C17H26N4OS
    (3R,5R)-1-[4-(furan-2-ylmethyl)-5-propan-2-ylsulfanyl-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine
    —— [2-[[(1S)-1-(1-adamantyl)ethyl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C23H31NO3S
    [2-[[(1S)-1-(1-adamantyl)ethyl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— [2-(cyclopentylamino)-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C21H23NO3S
    [2-(cyclopentylamino)-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C24H23NO3S
    [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C23H21N5OS
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— (2-amino-2-oxoethyl) (2R)-2-phenyl-2-phenylsulfanylacetate —— C16H15NO3S
    (2-amino-2-oxoethyl) (2R)-2-phenyl-2-phenylsulfanylacetate
    —— 3-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanenitrile —— C18H14N4S
    3-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanenitrile
    —— [(2R)-1-amino-1-oxopropan-2-yl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C17H17NO3S
    [(2R)-1-amino-1-oxopropan-2-yl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— (5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl (2R)-2-phenyl-2-phenylsulfanylacetate —— C21H16N2O3S2
    (5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [(2R)-1-amino-1-oxopropan-2-yl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C17H17NO3S
    [(2R)-1-amino-1-oxopropan-2-yl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C24H23NO3S
    [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [(2S)-1-amino-1-oxopropan-2-yl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C17H17NO3S
    [(2S)-1-amino-1-oxopropan-2-yl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C24H23NO3S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— 3-(Cyclohexylmethylsulfanyl)-5,6-diphenyl-1,2,4-triazine —— C22H23N3S
    3-(Cyclohexylmethylsulfanyl)-5,6-diphenyl-1,2,4-triazine
    —— [2-oxo-2-(propylamino)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C19H21NO3S
    [2-oxo-2-(propylamino)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C20H19NO4S
    [2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— 3-[(4-Methylsulfanylphenyl)methylsulfanyl]-5,6-diphenyl-1,2,4-triazine —— C23H19N3S2
    3-[(4-Methylsulfanylphenyl)methylsulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— (5-phenyl-1,3,4-oxadiazol-2-yl)methyl (2R)-2-phenyl-2-phenylsulfanylacetate —— C23H18N2O3S
    (5-phenyl-1,3,4-oxadiazol-2-yl)methyl (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [2-(2-methylpropylamino)-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C20H23NO3S
    [2-(2-methylpropylamino)-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— 3-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-5,6-diphenyl-1,2,4-triazine —— C23H18ClN3S
    3-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-5,6-diphenyl-1,2,4-triazine
    —— [2-[(1-methylpyrrole-2-carbonyl)amino]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C22H20N2O4S
    [2-[(1-methylpyrrole-2-carbonyl)amino]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— 3-[(3-Methylphenyl)methylsulfanyl]-5,6-diphenyl-1,2,4-triazine —— C23H19N3S
    3-[(3-Methylphenyl)methylsulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C24H26N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— 5,6-Diphenyl-3-(3-phenylpropylsulfanyl)-1,2,4-triazine —— C24H21N3S
    5,6-Diphenyl-3-(3-phenylpropylsulfanyl)-1,2,4-triazine
    —— 3-Benzylsulfanyl-5,6-diphenyl-1,2,4-triazine —— C22H17N3S
    3-Benzylsulfanyl-5,6-diphenyl-1,2,4-triazine
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C24H26N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— [2-(ethoxycarbonylamino)-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C19H19NO5S
    [2-(ethoxycarbonylamino)-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— [2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C20H19NO4S
    [2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— (5-phenyl-1,3,4-oxadiazol-2-yl)methyl (2S)-2-phenyl-2-phenylsulfanylacetate —— C23H18N2O3S
    (5-phenyl-1,3,4-oxadiazol-2-yl)methyl (2S)-2-phenyl-2-phenylsulfanylacetate
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C24H26N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— 3-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-5,6-diphenyl-1,2,4-triazine —— C23H18FN3S
    3-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-5,6-diphenyl-1,2,4-triazine
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide —— C24H26N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C23H21N5OS
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— 3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-5,6-diphenyl-1,2,4-triazine —— C23H18FN3S
    3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-5,6-diphenyl-1,2,4-triazine
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 3-phenoxypropanoate —— C23H21NO4S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 3-phenoxypropanoate
    —— [2-[4-(2,5-dimethylphenyl)sulfanylanilino]-2-oxoethyl] N,N-diethylcarbamodithioate —— C21H26N2OS3
    [2-[4-(2,5-dimethylphenyl)sulfanylanilino]-2-oxoethyl] N,N-diethylcarbamodithioate
    —— [2-(Cycloheptylamino)-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C18H24ClNO3S
    [2-(Cycloheptylamino)-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-[[(1R)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C19H19Cl2NO3S
    [2-[[(1R)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C17H19ClN2O3S
    [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-[[(1S)-1-(2-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C19H19Cl2NO3S
    [2-[[(1S)-1-(2-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [(2S)-1-(cyclohexylmethylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C19H26ClNO3S
    [(2S)-1-(cyclohexylmethylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C17H22ClNO3S
    [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-[(3-Chlorophenyl)methylamino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C18H17Cl2NO3S
    [2-[(3-Chlorophenyl)methylamino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-[(4-Methylcyclohexyl)amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C18H24ClNO3S
    [2-[(4-Methylcyclohexyl)amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-[[(1S)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C19H19Cl2NO3S
    [2-[[(1S)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C15H18ClNO3S
    [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— (2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C10H11F3N2O2S
    (2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C17H22ClNO3S
    [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [(2R)-1-oxo-1-[[(2R)-4-phenylbutan-2-yl]amino]propan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C22H26ClNO3S
    [(2R)-1-oxo-1-[[(2R)-4-phenylbutan-2-yl]amino]propan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate