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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide —— C22H21NO3S2
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide
    —— 3-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanylmethyl)-5-(furan-2-yl)-1,2-oxazole —— C17H15NO4S
    3-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanylmethyl)-5-(furan-2-yl)-1,2-oxazole
    —— N-(1-adamantyl)-N-(2-cyanoethyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C24H30N2O3S
    N-(1-adamantyl)-N-(2-cyanoethyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— N-[2-(3-chlorophenyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C19H20ClNO3S
    N-[2-(3-chlorophenyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[2-(2-fluorophenyl)ethyl]acetamide —— C19H20FNO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[2-(2-fluorophenyl)ethyl]acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(2-fluorophenyl)methyl]acetamide —— C18H18FNO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(2-fluorophenyl)methyl]acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[2-(2-methylphenyl)ethyl]acetamide —— C20H23NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[2-(2-methylphenyl)ethyl]acetamide
    —— 2-(5,6,7,8-Tetrahydro-1,2,4-benzotriazin-3-ylsulfanyl)-1-thiophen-2-ylethanone —— C13H13N3OS2
    2-(5,6,7,8-Tetrahydro-1,2,4-benzotriazin-3-ylsulfanyl)-1-thiophen-2-ylethanone
    —— 4-benzyl-3-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazole —— C17H15Cl2N3OS
    4-benzyl-3-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazole
    —— N-[2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]acetamide —— C17H18N4O2S
    N-[2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]acetamide
    —— N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H24N6OS2
    N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-benzyl-3-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazole —— C17H15Cl2N3S2
    4-benzyl-3-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazole
    —— N-[2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]acetamide —— C17H18N4OS2
    N-[2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]acetamide
    —— 2-(2,5-Dimethylfuran-3-yl)-5-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C17H17N5O2S2
    2-(2,5-Dimethylfuran-3-yl)-5-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— [2-[2-(2-methylphenyl)ethylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C20H23NO3S
    [2-[2-(2-methylphenyl)ethylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— 2-(4-cyano-1,3-dioxo-6,7-dihydro-5H-pyrrolo[1,2-c]pyrimidin-2-yl)-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C19H20N4O3S
    2-(4-cyano-1,3-dioxo-6,7-dihydro-5H-pyrrolo[1,2-c]pyrimidin-2-yl)-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— 2-(4-cyano-1,3-dioxo-6,7-dihydro-5H-pyrrolo[1,2-c]pyrimidin-2-yl)-N-(3-phenylsulfanylpropyl)acetamide —— C19H20N4O3S
    2-(4-cyano-1,3-dioxo-6,7-dihydro-5H-pyrrolo[1,2-c]pyrimidin-2-yl)-N-(3-phenylsulfanylpropyl)acetamide
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide —— C17H22N2OS
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide
    —— [2-oxo-2-[[(S)-phenyl(thiophen-2-yl)methyl]amino]ethyl] (2R)-2-phenylsulfanylpropanoate —— C22H21NO3S2
    [2-oxo-2-[[(S)-phenyl(thiophen-2-yl)methyl]amino]ethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[[4-(dimethylamino)phenyl]methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C20H24N2O3S
    [2-[[4-(dimethylamino)phenyl]methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-[[4-(dimethylamino)phenyl]methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C20H24N2O3S
    [2-[[4-(dimethylamino)phenyl]methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[(2-methylphenyl)methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C19H21NO3S
    [2-[(2-methylphenyl)methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-oxo-2-[[(S)-phenyl(thiophen-2-yl)methyl]amino]ethyl] (2S)-2-phenylsulfanylpropanoate —— C22H21NO3S2
    [2-oxo-2-[[(S)-phenyl(thiophen-2-yl)methyl]amino]ethyl] (2S)-2-phenylsulfanylpropanoate
    —— [5-(furan-2-yl)-1,2-oxazol-3-yl]methyl (2S)-2-phenylsulfanylpropanoate —— C17H15NO4S
    [5-(furan-2-yl)-1,2-oxazol-3-yl]methyl (2S)-2-phenylsulfanylpropanoate
    —— [2-[[4-(dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C21H26N2O3S
    [2-[[4-(dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[1-adamantyl(2-cyanoethyl)amino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C24H30N2O3S
    [2-[1-adamantyl(2-cyanoethyl)amino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-[[4-(dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C21H26N2O3S
    [2-[[4-(dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-[(2-methylphenyl)methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C19H21NO3S
    [2-[(2-methylphenyl)methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[1-adamantyl(2-cyanoethyl)amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C24H30N2O3S
    [2-[1-adamantyl(2-cyanoethyl)amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-(2-fluorophenyl)sulfanylacetamide —— C14H15FN2OS
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-(2-fluorophenyl)sulfanylacetamide
    —— (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dimethylphenyl)sulfanylpropanamide —— C17H24N2OS
    (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dimethylphenyl)sulfanylpropanamide
    —— (2R)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(4-fluorophenyl)sulfanylpropanamide —— C15H19FN2OS
    (2R)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(4-fluorophenyl)sulfanylpropanamide
    —— [2-[2-(3-Chlorophenyl)ethylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C18H17ClFNO3S
    [2-[2-(3-Chlorophenyl)ethylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[(2-Fluorophenyl)methylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C17H15F2NO3S
    [2-[(2-Fluorophenyl)methylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C19H21FN2O3S
    [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[[(1R)-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C15H18FNO3S
    [2-[[(1R)-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— (2S)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dimethylphenyl)sulfanylpropanamide —— C17H24N2OS
    (2S)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dimethylphenyl)sulfanylpropanamide
    —— [2-oxo-2-[[(R)-phenyl(thiophen-2-yl)methyl]amino]ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C21H18FNO3S2
    [2-oxo-2-[[(R)-phenyl(thiophen-2-yl)methyl]amino]ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[[(1S)-1-(furan-2-yl)ethyl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C18H21NO4S
    [2-[[(1S)-1-(furan-2-yl)ethyl]amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[(2-Methylphenyl)methylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C18H18FNO3S
    [2-[(2-Methylphenyl)methylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C15H18FNO3S
    [2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C21H26N2O3S
    [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[(2-Fluorophenyl)methylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C19H20FNO3S
    [2-[(2-Fluorophenyl)methylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— 3-benzylsulfanyl-4-[(Z)-(3-methylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C17H16N4S2
    3-benzylsulfanyl-4-[(Z)-(3-methylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(4-fluorophenyl)sulfanylpropanamide —— C15H19FN2OS
    (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(4-fluorophenyl)sulfanylpropanamide
    —— [2-[2-(2-Methylphenyl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C21H25NO3S
    [2-[2-(2-Methylphenyl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— (2S)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(4-fluorophenyl)sulfanylpropanamide —— C15H19FN2OS
    (2S)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(4-fluorophenyl)sulfanylpropanamide
    —— [2-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C19H17FO5S
    [2-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-Oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C19H20FNO3S2
    [2-Oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[[(1R)-1-(furan-2-yl)ethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C16H16FNO4S
    [2-[[(1R)-1-(furan-2-yl)ethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate