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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(S)-(4-chlorophenyl)-thiophen-2-ylmethyl]acetamide —— C21H15Cl2N3O2S2
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(S)-(4-chlorophenyl)-thiophen-2-ylmethyl]acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(R)-(4-chlorophenyl)-thiophen-2-ylmethyl]acetamide —— C21H15Cl2N3O2S2
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(R)-(4-chlorophenyl)-thiophen-2-ylmethyl]acetamide
    —— N-[[3-[[(2R)-2-methylbutanoyl]amino]phenyl]methyl]-2-phenylsulfanylpyridine-3-carboxamide —— C24H25N3O2S
    N-[[3-[[(2R)-2-methylbutanoyl]amino]phenyl]methyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[[3-[[(2R)-butan-2-yl]carbamoyl]phenyl]methyl]-2-phenylsulfanylpyridine-3-carboxamide —— C24H25N3O2S
    N-[[3-[[(2R)-butan-2-yl]carbamoyl]phenyl]methyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(2,3-dihydro-1H-inden-5-yloxy)acetamide —— C23H20ClNO2S
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(2,3-dihydro-1H-inden-5-yloxy)acetamide
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(3-ethylphenoxy)acetamide —— C22H20ClNO2S
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(3-ethylphenoxy)acetamide
    —— N-[[3-[[(2S)-2-methylbutanoyl]amino]phenyl]methyl]-2-phenylsulfanylpyridine-3-carboxamide —— C24H25N3O2S
    N-[[3-[[(2S)-2-methylbutanoyl]amino]phenyl]methyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(4-ethoxyphenoxy)acetamide —— C22H20ClNO3S
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(4-ethoxyphenoxy)acetamide
    —— [(2R)-oxan-2-yl]methyl (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C12H19N3O3S
    [(2R)-oxan-2-yl]methyl (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— 3-(6-methylpyridin-2-yl)propyl (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C15H20N4O2S
    3-(6-methylpyridin-2-yl)propyl (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— 3-(6-methylpyridin-2-yl)propyl (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C15H20N4O2S
    3-(6-methylpyridin-2-yl)propyl (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— [(2S)-oxan-2-yl]methyl (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C12H19N3O3S
    [(2S)-oxan-2-yl]methyl (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— [(2R)-oxan-2-yl]methyl (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C12H19N3O3S
    [(2R)-oxan-2-yl]methyl (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— [(2S)-oxan-2-yl]methyl (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C12H19N3O3S
    [(2S)-oxan-2-yl]methyl (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (E)-2-cyano-3-(furan-2-yl)prop-2-enoate —— C22H16N2O4S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (E)-2-cyano-3-(furan-2-yl)prop-2-enoate
    —— 3-(4-Fluorophenyl)-5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazole-2-thione —— C15H10F2N2S3
    3-(4-Fluorophenyl)-5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazole-2-thione
    —— 5-[(3,5-Dimethyl-1,2-oxazol-4-yl)methylsulfanyl]-3-(4-fluorophenyl)-1,3,4-thiadiazole-2-thione —— C14H12FN3OS3
    5-[(3,5-Dimethyl-1,2-oxazol-4-yl)methylsulfanyl]-3-(4-fluorophenyl)-1,3,4-thiadiazole-2-thione
    —— 5-[(2,5-Dimethylphenyl)methylsulfanyl]-3-(4-fluorophenyl)-1,3,4-thiadiazole-2-thione —— C17H15FN2S3
    5-[(2,5-Dimethylphenyl)methylsulfanyl]-3-(4-fluorophenyl)-1,3,4-thiadiazole-2-thione
    —— 3-(4-Fluorophenyl)-5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazole-2-thione —— C15H10F2N2S3
    3-(4-Fluorophenyl)-5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazole-2-thione
    —— N-[(E)-1-(4-bromophenyl)ethylideneamino]-3-(pyridin-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine —— C16H15BrN6S
    N-[(E)-1-(4-bromophenyl)ethylideneamino]-3-(pyridin-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— 3-benzylsulfanyl-N-[(E)-1-phenylethylideneamino]-1H-1,2,4-triazol-5-amine —— C17H17N5S
    3-benzylsulfanyl-N-[(E)-1-phenylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— (2S)-N-benzyl-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H16FN3OS3
    (2S)-N-benzyl-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 3-[(2-chlorophenyl)methylsulfanyl]-N-[(E)-1-(4-fluorophenyl)ethylideneamino]-1H-1,2,4-triazol-5-amine —— C17H15ClFN5S
    3-[(2-chlorophenyl)methylsulfanyl]-N-[(E)-1-(4-fluorophenyl)ethylideneamino]-1H-1,2,4-triazol-5-amine
    —— N-[(E)-1-pyridin-2-ylethylideneamino]-3-(pyridin-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine —— C15H15N7S
    N-[(E)-1-pyridin-2-ylethylideneamino]-3-(pyridin-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— N-[(E)-1-pyridin-2-ylethylideneamino]-3-(pyridin-4-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine —— C15H15N7S
    N-[(E)-1-pyridin-2-ylethylideneamino]-3-(pyridin-4-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— N-[(E)-1-(4-fluorophenyl)ethylideneamino]-3-[(4-fluorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C17H15F2N5S
    N-[(E)-1-(4-fluorophenyl)ethylideneamino]-3-[(4-fluorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— N-[(E)-1-(4-fluorophenyl)ethylideneamino]-3-(pyridin-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine —— C16H15FN6S
    N-[(E)-1-(4-fluorophenyl)ethylideneamino]-3-(pyridin-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— 5-[(3-Chlorophenyl)methylsulfanyl]-3-(4-fluorophenyl)-1,3,4-thiadiazole-2-thione —— C15H10ClFN2S3
    5-[(3-Chlorophenyl)methylsulfanyl]-3-(4-fluorophenyl)-1,3,4-thiadiazole-2-thione
    —— 3-[(4-chlorophenyl)methylsulfanyl]-N-[(E)-1-(4-fluorophenyl)ethylideneamino]-1H-1,2,4-triazol-5-amine —— C17H15ClFN5S
    3-[(4-chlorophenyl)methylsulfanyl]-N-[(E)-1-(4-fluorophenyl)ethylideneamino]-1H-1,2,4-triazol-5-amine
    —— 3-benzylsulfanyl-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine —— C16H16N6S
    3-benzylsulfanyl-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— 3-[(4-fluorophenyl)methylsulfanyl]-N-[(E)-1-phenylethylideneamino]-1H-1,2,4-triazol-5-amine —— C17H16FN5S
    3-[(4-fluorophenyl)methylsulfanyl]-N-[(E)-1-phenylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— 3-[(2-chlorophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine —— C16H15ClN6S
    3-[(2-chlorophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— N-(2-phenylethyl)-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H21N7OS
    N-(2-phenylethyl)-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-[(4-chlorophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine —— C16H15ClN6S
    3-[(4-chlorophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— N-[(E)-1-phenylethylideneamino]-3-prop-2-enylsulfanyl-1H-1,2,4-triazol-5-amine —— C13H15N5S
    N-[(E)-1-phenylethylideneamino]-3-prop-2-enylsulfanyl-1H-1,2,4-triazol-5-amine
    —— methyl 2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C12H14N6O2S
    methyl 2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— methyl 2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H15N5O2S
    methyl 2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C11H11N7S
    2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— N-(furan-2-ylmethyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H18N6O2S
    N-(furan-2-ylmethyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(3-chlorophenyl)methyl]-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H18ClN7OS
    N-[(3-chlorophenyl)methyl]-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— methyl 2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H14FN5O2S
    methyl 2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— N-(furan-2-ylmethyl)-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H17N7O2S
    N-(furan-2-ylmethyl)-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(4-chlorophenyl)methyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H19ClN6OS
    N-[(4-chlorophenyl)methyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— methyl 2-[[5-[(2E)-2-[1-(4-bromophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H14BrN5O2S
    methyl 2-[[5-[(2E)-2-[1-(4-bromophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— N-[(4-chlorophenyl)methyl]-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H18ClN7OS
    N-[(4-chlorophenyl)methyl]-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-cyclopentyl-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H22N6OS
    N-cyclopentyl-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C12H13FN6OS
    2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide —— C19H18F2N6OS
    2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide
    —— N-tert-butyl-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H22N6OS
    N-tert-butyl-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylethyl)acetamide —— C20H21FN6OS
    2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylethyl)acetamide