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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-pyrimidin-2-ylsulfanyl-N-[2-(4,5,6,7-tetrahydro-1,3-benzothiazol-2-yl)ethyl]propanamide —— C16H20N4OS2
    (2R)-2-pyrimidin-2-ylsulfanyl-N-[2-(4,5,6,7-tetrahydro-1,3-benzothiazol-2-yl)ethyl]propanamide
    —— 1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C20H17N5O2S4
    1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1S)-1-phenylethyl]propanamide —— C17H18ClNOS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1S)-1-phenylethyl]propanamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2S)-2-phenylpropyl]propanamide —— C18H20ClNOS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2S)-2-phenylpropyl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(2R)-2-phenylpropyl]propanamide —— C18H20ClNOS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(2R)-2-phenylpropyl]propanamide
    —— 4-[[2-(4-chlorophenyl)sulfanylethylamino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one —— C16H17ClN2O2S
    4-[[2-(4-chlorophenyl)sulfanylethylamino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one
    —— 1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C20H17N5O2S4
    1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(2S)-2-phenylpropyl]propanamide —— C18H20ClNOS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(2S)-2-phenylpropyl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(1S)-1-phenylethyl]propanamide —— C17H18ClNOS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(1S)-1-phenylethyl]propanamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1R)-1-phenylethyl]propanamide —— C17H18ClNOS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1R)-1-phenylethyl]propanamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2R)-2-phenylpropyl]propanamide —— C18H20ClNOS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2R)-2-phenylpropyl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(1R)-1-phenylethyl]propanamide —— C17H18ClNOS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(1R)-1-phenylethyl]propanamide
    —— 4-[[3-(4-cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propylamino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one —— C19H27N5O2S
    4-[[3-(4-cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propylamino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one
    —— 5-(hydroxymethyl)-2-methyl-4-[[2-(1-methylimidazol-2-yl)sulfanylethylamino]methylidene]pyridin-3-one —— C14H18N4O2S
    5-(hydroxymethyl)-2-methyl-4-[[2-(1-methylimidazol-2-yl)sulfanylethylamino]methylidene]pyridin-3-one
    —— 4-[[4-(1H-benzimidazol-2-ylsulfanyl)anilino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one —— C21H18N4O2S
    4-[[4-(1H-benzimidazol-2-ylsulfanyl)anilino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one
    —— 4-[[4-(3,4-dimethylphenyl)sulfanylanilino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one —— C22H22N2O2S
    4-[[4-(3,4-dimethylphenyl)sulfanylanilino]methylidene]-5-(hydroxymethyl)-2-methylpyridin-3-one
    —— N-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C15H20N4OS2
    N-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 5-(hydroxymethyl)-2-methyl-4-[(3-phenylsulfanylpropylamino)methylidene]pyridin-3-one —— C17H20N2O2S
    5-(hydroxymethyl)-2-methyl-4-[(3-phenylsulfanylpropylamino)methylidene]pyridin-3-one
    —— 5-(hydroxymethyl)-2-methyl-4-[[2-(4-methylphenyl)sulfanylethylamino]methylidene]pyridin-3-one —— C17H20N2O2S
    5-(hydroxymethyl)-2-methyl-4-[[2-(4-methylphenyl)sulfanylethylamino]methylidene]pyridin-3-one
    —— 5-(hydroxymethyl)-2-methyl-4-[(2-methylsulfanylanilino)methylidene]pyridin-3-one —— C15H16N2O2S
    5-(hydroxymethyl)-2-methyl-4-[(2-methylsulfanylanilino)methylidene]pyridin-3-one
    —— (2R)-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide —— C18H18F2N4OS4
    (2R)-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide
    —— ethyl (2Z)-2-[3-[2-(1-methyltetrazol-5-yl)sulfanylethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate —— C11H15N5O3S2
    ethyl (2Z)-2-[3-[2-(1-methyltetrazol-5-yl)sulfanylethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate
    —— 5-(hydroxymethyl)-2-methyl-4-[(3-methylsulfanylanilino)methylidene]pyridin-3-one —— C15H16N2O2S
    5-(hydroxymethyl)-2-methyl-4-[(3-methylsulfanylanilino)methylidene]pyridin-3-one
    —— N-[2-[(1S,2S)-2-methylcyclohexyl]oxyethyl]-1-methylsulfonylcyclopentane-1-carboxamide —— C16H29NO4S
    N-[2-[(1S,2S)-2-methylcyclohexyl]oxyethyl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[2-[(1S,2R)-2-methylcyclohexyl]oxyethyl]-1-methylsulfonylcyclopentane-1-carboxamide —— C16H29NO4S
    N-[2-[(1S,2R)-2-methylcyclohexyl]oxyethyl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[2-[(1R,2R)-2-methylcyclohexyl]oxyethyl]-1-methylsulfonylcyclopentane-1-carboxamide —— C16H29NO4S
    N-[2-[(1R,2R)-2-methylcyclohexyl]oxyethyl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[2-[(1R,2S)-2-methylcyclohexyl]oxyethyl]-1-methylsulfonylcyclopentane-1-carboxamide —— C16H29NO4S
    N-[2-[(1R,2S)-2-methylcyclohexyl]oxyethyl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(1S)-1-(4-tert-butyl-1,3-thiazol-2-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H19N5OS2
    N-[(1S)-1-(4-tert-butyl-1,3-thiazol-2-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1R)-1-(4-tert-butyl-1,3-thiazol-2-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H19N5OS2
    N-[(1R)-1-(4-tert-butyl-1,3-thiazol-2-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— ethyl (2Z)-2-[3-[2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate —— C11H14N4O3S3
    ethyl (2Z)-2-[3-[2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate
    —— ethyl (2Z)-2-[3-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate —— C13H16N2O3S3
    ethyl (2Z)-2-[3-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate
    —— 4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]butan-2-one —— C19H17N3OS
    4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]butan-2-one
    —— 4-[[5-(4-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butan-2-one —— C13H15N3OS2
    4-[[5-(4-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butan-2-one
    —— ethyl (2Z)-2-[3-[2-(4-bromophenyl)sulfanylethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate —— C15H16BrNO3S2
    ethyl (2Z)-2-[3-[2-(4-bromophenyl)sulfanylethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate
    —— 4-[[5-(2-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butan-2-one —— C13H15N3OS2
    4-[[5-(2-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butan-2-one
    —— 2-(2-oxopyrimidin-1-yl)-N-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]acetamide —— C17H21N3O2S
    2-(2-oxopyrimidin-1-yl)-N-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]acetamide
    —— 2-[(1R)-1-(3-chlorophenyl)sulfanylethyl]-5-methyl-1,3,4-oxadiazole —— C11H11ClN2OS
    2-[(1R)-1-(3-chlorophenyl)sulfanylethyl]-5-methyl-1,3,4-oxadiazole
    —— 2-[6-(Furan-2-yl)pyridazin-3-yl]sulfanyl-1-thiophen-2-ylethanone —— C14H10N2O2S2
    2-[6-(Furan-2-yl)pyridazin-3-yl]sulfanyl-1-thiophen-2-ylethanone
    —— 2-[(1S)-1-(3-chlorophenyl)sulfanylethyl]-5-methyl-1,3,4-oxadiazole —— C11H11ClN2OS
    2-[(1S)-1-(3-chlorophenyl)sulfanylethyl]-5-methyl-1,3,4-oxadiazole
    —— 2-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole —— C17H22N2O3S
    2-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole
    —— 2-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole —— C17H22N2O3S
    2-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole
    —— 2-(4-Chlorophenyl)sulfanyl-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C17H15ClN2OS
    2-(4-Chlorophenyl)sulfanyl-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— 2-(4-chlorophenyl)sulfanyl-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide —— C14H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide —— C14H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-(1-cyanocyclohexyl)acetamide —— C15H17ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-(1-cyanocyclohexyl)acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C14H14ClNOS2
    2-(4-chlorophenyl)sulfanyl-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-(1-cyanocyclohexyl)-N-methylacetamide —— C16H19ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-(1-cyanocyclohexyl)-N-methylacetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(1R)-1-thiophen-2-ylethyl]acetamide —— C14H14ClNOS2
    2-(4-chlorophenyl)sulfanyl-N-[(1R)-1-thiophen-2-ylethyl]acetamide
    —— 4-[[5-(2-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]butanenitrile —— C12H10BrN3OS
    4-[[5-(2-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]butanenitrile
    —— (2R)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylpropanamide —— C16H18BrN3O2S
    (2R)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylpropanamide