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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(1-cyanocyclohexyl)-4-phenylsulfanylbutanamide —— C17H22N2OS
    N-(1-cyanocyclohexyl)-4-phenylsulfanylbutanamide
    —— N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide —— C17H25NO3S2
    N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide
    —— [(2R)-1-[(4-methylphenyl)methylamino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C19H23N3O3S
    [(2R)-1-[(4-methylphenyl)methylamino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— 2-(2,5-dimethylphenyl)sulfanyl-N-[(S)-phenyl(pyridin-2-yl)methyl]acetamide —— C22H22N2OS
    2-(2,5-dimethylphenyl)sulfanyl-N-[(S)-phenyl(pyridin-2-yl)methyl]acetamide
    —— (2S)-N-cyclohexyl-N-ethyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H23N3OS3
    (2S)-N-cyclohexyl-N-ethyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-2-[(4-amino-5-tert-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-methylpropanamide —— C16H29N5OS
    (2R)-2-[(4-amino-5-tert-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-methylpropanamide
    —— (2S)-2-[(4-amino-5-tert-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-methylpropanamide —— C16H29N5OS
    (2S)-2-[(4-amino-5-tert-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-methylpropanamide
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C10H13F3N4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— (2R)-N-cyclohexyl-N-ethyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C20H27N3O2S
    (2R)-N-cyclohexyl-N-ethyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-benzyl-N-methyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H17N3OS3
    (2R)-N-benzyl-N-methyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H21N3OS3
    (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-cyclohexyl-N-ethyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H23N3OS3
    (2R)-N-cyclohexyl-N-ethyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C14H18ClNO3S2
    2-(4-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— (2R)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H16FN3OS2
    (2R)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-benzyl-N-methyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H17N3OS3
    (2S)-N-benzyl-N-methyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-cyclohexyl-N-ethyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C20H27N3O2S
    (2S)-N-cyclohexyl-N-ethyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H21N3OS3
    (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-phenylsulfanyl-N-propylacetamide —— C15H21NO3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-phenylsulfanyl-N-propylacetamide
    —— 2-(2,5-difluorophenyl)sulfanyl-N-[2-(3-fluorophenyl)ethyl]acetamide —— C16H14F3NOS
    2-(2,5-difluorophenyl)sulfanyl-N-[2-(3-fluorophenyl)ethyl]acetamide
    —— [(2S)-1-[[(3S)-1,1-dioxothiolan-3-yl]amino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C15H21N3O5S2
    [(2S)-1-[[(3S)-1,1-dioxothiolan-3-yl]amino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— (2S)-2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile —— C16H20N4O2S
    (2S)-2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— [(2R)-1-[(2-chlorophenyl)methylamino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C18H20ClN3O3S
    [(2R)-1-[(2-chlorophenyl)methylamino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C14H19N3O3S
    [(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[2-(3-fluorophenyl)ethyl]propanamide —— C18H22FN3OS
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[2-(3-fluorophenyl)ethyl]propanamide
    —— [(2R)-1-[[(3S)-1,1-dioxothiolan-3-yl]amino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C15H21N3O5S2
    [(2R)-1-[[(3S)-1,1-dioxothiolan-3-yl]amino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [(2S)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C18H27N3O3S
    [(2S)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [(2S)-1-[[(3R)-1,1-dioxothiolan-3-yl]amino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C15H21N3O5S2
    [(2S)-1-[[(3R)-1,1-dioxothiolan-3-yl]amino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [(2R)-1-[(4-fluorophenyl)methylamino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C18H20FN3O3S
    [(2R)-1-[(4-fluorophenyl)methylamino]-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— 2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanol —— C16H22N2O2S2
    2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanol
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C10H13F3N4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— N-[(S)-phenyl(pyridin-4-yl)methyl]-2-pyridin-4-ylsulfanylacetamide —— C19H17N3OS
    N-[(S)-phenyl(pyridin-4-yl)methyl]-2-pyridin-4-ylsulfanylacetamide
    —— 4-amino-3-[(3,4-difluorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-one —— C11H10F2N4OS
    4-amino-3-[(3,4-difluorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-one
    —— 3-[(3,4-Difluorophenyl)methylsulfanyl]-5-(furan-2-yl)-4-methyl-1,2,4-triazole —— C14H11F2N3OS
    3-[(3,4-Difluorophenyl)methylsulfanyl]-5-(furan-2-yl)-4-methyl-1,2,4-triazole
    —— 2-(3,4-dimethylphenyl)sulfanyl-N-[2-(3-fluorophenyl)ethyl]acetamide —— C18H20FNOS
    2-(3,4-dimethylphenyl)sulfanyl-N-[2-(3-fluorophenyl)ethyl]acetamide
    —— N-[2-(3-fluorophenyl)ethyl]-2-(4-methylphenyl)sulfanylacetamide —— C17H18FNOS
    N-[2-(3-fluorophenyl)ethyl]-2-(4-methylphenyl)sulfanylacetamide
    —— (2R)-N-cyclopropyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide —— C12H13F3N2OS
    (2R)-N-cyclopropyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide
    —— N-[2-(3-fluorophenyl)ethyl]-2-(2-methylphenyl)sulfanylacetamide —— C17H18FNOS
    N-[2-(3-fluorophenyl)ethyl]-2-(2-methylphenyl)sulfanylacetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[2-(3-fluorophenyl)ethyl]acetamide —— C16H15BrFNOS
    2-(4-bromophenyl)sulfanyl-N-[2-(3-fluorophenyl)ethyl]acetamide
    —— 4-amino-3-(3-hydroxypropylsulfanyl)-6-methyl-1,2,4-triazin-5-one —— C7H12N4O2S
    4-amino-3-(3-hydroxypropylsulfanyl)-6-methyl-1,2,4-triazin-5-one
    —— 4-amino-6-methyl-3-(3-phenylpropylsulfanyl)-1,2,4-triazin-5-one —— C13H16N4OS
    4-amino-6-methyl-3-(3-phenylpropylsulfanyl)-1,2,4-triazin-5-one
    —— 4-amino-6-methyl-3-(2-phenylethylsulfanyl)-1,2,4-triazin-5-one —— C12H14N4OS
    4-amino-6-methyl-3-(2-phenylethylsulfanyl)-1,2,4-triazin-5-one
    —— [(3S)-3-cyano-4-imino-2-oxopentyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C16H20N4O3S
    [(3S)-3-cyano-4-imino-2-oxopentyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— 2-methylsulfanylethyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H17N3O3S2
    2-methylsulfanylethyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 5-(Pyrimidin-2-ylsulfanylmethyl)-3-thiophen-2-yl-1,2,4-oxadiazole —— C11H8N4OS2
    5-(Pyrimidin-2-ylsulfanylmethyl)-3-thiophen-2-yl-1,2,4-oxadiazole
    —— N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-pyrimidin-2-ylsulfanylacetamide —— C14H19N5OS
    N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— 2-(2,5-Dimethylfuran-3-yl)-5-(pyrimidin-2-ylsulfanylmethyl)-1,3,4-oxadiazole —— C13H12N4O2S
    2-(2,5-Dimethylfuran-3-yl)-5-(pyrimidin-2-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— 3-(furan-2-yl)-4-methyl-5-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazole —— C15H15N3OS
    3-(furan-2-yl)-4-methyl-5-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazole
    —— 3-(furan-2-yl)-4-methyl-5-[(1R)-1-phenylethyl]sulfanyl-1,2,4-triazole —— C15H15N3OS
    3-(furan-2-yl)-4-methyl-5-[(1R)-1-phenylethyl]sulfanyl-1,2,4-triazole
    —— methyl (2R)-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C9H15N3O3S
    methyl (2R)-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— pyridin-2-ylmethyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H16N4O3S
    pyridin-2-ylmethyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate