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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R,3R)-2-amino-3-methylpentanethioamide —— C6H14N2S
    (2R,3R)-2-amino-3-methylpentanethioamide
    —— (2R)-N-[(1S)-1-phenylethyl]-2-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]butanamide —— C21H22N4OS
    (2R)-N-[(1S)-1-phenylethyl]-2-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]butanamide
    —— (2R)-2-amino-3-methylbutanethioamide —— C5H12N2S
    (2R)-2-amino-3-methylbutanethioamide
    —— (2R)-2-thiophen-2-ylsulfanylbutanedioate —— C8H6O4S2-2
    (2R)-2-thiophen-2-ylsulfanylbutanedioate
    —— (2R,3S)-2-amino-3-methylpentanethioamide —— C6H14N2S
    (2R,3S)-2-amino-3-methylpentanethioamide
    —— (2S,3R)-2-amino-3-methylpentanethioamide —— C6H14N2S
    (2S,3R)-2-amino-3-methylpentanethioamide
    —— (2S)-N-[(1S)-1-phenylethyl]-2-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]butanamide —— C21H22N4OS
    (2S)-N-[(1S)-1-phenylethyl]-2-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]butanamide
    —— (2S)-N-[(1R)-1-phenylethyl]-2-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]butanamide —— C21H22N4OS
    (2S)-N-[(1R)-1-phenylethyl]-2-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]butanamide
    —— (R)-2,3-Dihydrobenzo[b]thiophene-3-carboxylic acid —— C9H8O2S
    (R)-2,3-Dihydrobenzo[b]thiophene-3-carboxylic acid
    —— (S)-2,3-Dihydrobenzo[b]thiophene-3-carboxylic acid —— C9H8O2S
    (S)-2,3-Dihydrobenzo[b]thiophene-3-carboxylic acid
    —— 4,6-Dimethyl-2-(2-morpholin-4-ium-4-ylethylsulfanyl)pyridine-3-carbonitrile —— C14H20N3OS+
    4,6-Dimethyl-2-(2-morpholin-4-ium-4-ylethylsulfanyl)pyridine-3-carbonitrile
    —— (2S)-N-[(2R)-2-(4-bromophenyl)sulfanylpropyl]-1,4-dioxane-2-carboxamide —— C14H18BrNO3S
    (2S)-N-[(2R)-2-(4-bromophenyl)sulfanylpropyl]-1,4-dioxane-2-carboxamide
    —— N-[(2R)-2-(4-bromophenyl)sulfanylpropyl]acetamide —— C11H14BrNOS
    N-[(2R)-2-(4-bromophenyl)sulfanylpropyl]acetamide
    —— N-[(2S)-2-(4-bromophenyl)sulfanylpropyl]acetamide —— C11H14BrNOS
    N-[(2S)-2-(4-bromophenyl)sulfanylpropyl]acetamide
    —— (2R)-N-[(2S)-2-(4-bromophenyl)sulfanylpropyl]-1,4-dioxane-2-carboxamide —— C14H18BrNO3S
    (2R)-N-[(2S)-2-(4-bromophenyl)sulfanylpropyl]-1,4-dioxane-2-carboxamide
    —— (2R)-N-[(2R)-2-(4-bromophenyl)sulfanylpropyl]-1,4-dioxane-2-carboxamide —— C14H18BrNO3S
    (2R)-N-[(2R)-2-(4-bromophenyl)sulfanylpropyl]-1,4-dioxane-2-carboxamide
    —— (2S)-N-[(2S)-2-(4-bromophenyl)sulfanylpropyl]-1,4-dioxane-2-carboxamide —— C14H18BrNO3S
    (2S)-N-[(2S)-2-(4-bromophenyl)sulfanylpropyl]-1,4-dioxane-2-carboxamide
    —— 2-[[4-methyl-5-(2-methylpropyl)-6-oxo-1H-pyrimidin-2-yl]sulfanyl]acetate —— C11H15N2O3S-
    2-[[4-methyl-5-(2-methylpropyl)-6-oxo-1H-pyrimidin-2-yl]sulfanyl]acetate
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-1-[(6R)-2,2,6-trimethylmorpholin-4-yl]propan-1-one —— C17H27N3O2S
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-1-[(6R)-2,2,6-trimethylmorpholin-4-yl]propan-1-one
    —— 1-[(1S,2R,6S)-3-acetyl-4,6-dihydroxy-6-methyl-2-(4-methylsulfanylphenyl)cyclohex-3-en-1-yl]ethanone —— C18H22O4S
    1-[(1S,2R,6S)-3-acetyl-4,6-dihydroxy-6-methyl-2-(4-methylsulfanylphenyl)cyclohex-3-en-1-yl]ethanone
    —— 1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone —— C17H15ClN6O2S
    1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone
    —— [(1S)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl] (2S)-2,3-dihydro-1-benzothiophene-2-carboxylate —— C14H14N2O3S
    [(1S)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl] (2S)-2,3-dihydro-1-benzothiophene-2-carboxylate
    —— (6S,7R)-7-(4-bromofuran-2-yl)-2-ethyl-5-imino-6,7-dihydro-1H-thiopyrano[2,3-d]imidazole-6-carbonitrile —— C13H11BrN4OS
    (6S,7R)-7-(4-bromofuran-2-yl)-2-ethyl-5-imino-6,7-dihydro-1H-thiopyrano[2,3-d]imidazole-6-carbonitrile
    —— (6R,7S)-7-(4-bromofuran-2-yl)-2-ethyl-5-imino-6,7-dihydro-1H-thiopyrano[2,3-d]imidazole-6-carbonitrile —— C13H11BrN4OS
    (6R,7S)-7-(4-bromofuran-2-yl)-2-ethyl-5-imino-6,7-dihydro-1H-thiopyrano[2,3-d]imidazole-6-carbonitrile
    —— 2-pyrazol-1-ylethyl 2-(2-fluorophenyl)sulfanylacetate —— C13H13FN2O2S
    2-pyrazol-1-ylethyl 2-(2-fluorophenyl)sulfanylacetate
    —— [(1S)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl] (2R)-2,3-dihydro-1-benzothiophene-2-carboxylate —— C14H14N2O3S
    [(1S)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl] (2R)-2,3-dihydro-1-benzothiophene-2-carboxylate
    —— 3-(4-fluorophenyl)sulfanyl-N-[[(3S)-1-(2-methoxyethyl)pyrrolidin-3-yl]methyl]propanamide —— C17H25FN2O2S
    3-(4-fluorophenyl)sulfanyl-N-[[(3S)-1-(2-methoxyethyl)pyrrolidin-3-yl]methyl]propanamide
    —— [(1R)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl] (2S)-2,3-dihydro-1-benzothiophene-2-carboxylate —— C14H14N2O3S
    [(1R)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl] (2S)-2,3-dihydro-1-benzothiophene-2-carboxylate
    —— 2-(1-methyltetrazol-5-yl)sulfanyl-N-[(1S)-1-phenylethyl]acetamide —— C12H15N5OS
    2-(1-methyltetrazol-5-yl)sulfanyl-N-[(1S)-1-phenylethyl]acetamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C18H19N5OS2
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[[(3R)-1-(2-methoxyethyl)pyrrolidin-3-yl]methyl]propanamide —— C17H25FN2O2S
    3-(4-fluorophenyl)sulfanyl-N-[[(3R)-1-(2-methoxyethyl)pyrrolidin-3-yl]methyl]propanamide
    —— 1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone —— C18H18N6O2S
    1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone
    —— N-benzyl-2-(1-methyltetrazol-5-yl)sulfanyl-N-(2-phenylethyl)acetamide —— C19H21N5OS
    N-benzyl-2-(1-methyltetrazol-5-yl)sulfanyl-N-(2-phenylethyl)acetamide
    —— 1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone —— C17H15ClN6O2S
    1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone
    —— ethyl 2,4-dimethyl-5-[(2R)-2-(1-methyltetrazol-5-yl)sulfanylpropanoyl]-1H-pyrrole-3-carboxylate —— C14H19N5O3S
    ethyl 2,4-dimethyl-5-[(2R)-2-(1-methyltetrazol-5-yl)sulfanylpropanoyl]-1H-pyrrole-3-carboxylate
    —— 1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone —— C17H18FN5OS
    1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(1-methyltetrazol-5-yl)sulfanylethanone
    —— (2Z)-2-[1-(2,4-dimethylanilino)ethylidene]-1-benzothiophen-3-one —— C18H17NOS
    (2Z)-2-[1-(2,4-dimethylanilino)ethylidene]-1-benzothiophen-3-one
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C16H25N5OS
    N-[(1S)-1-(1-adamantyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C16H25N5OS
    N-[(1R)-1-(1-adamantyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 4-[(1-Methyltetrazol-5-yl)sulfanylmethyl]-2-thiophen-2-yl-1,3-oxazole —— C10H9N5OS2
    4-[(1-Methyltetrazol-5-yl)sulfanylmethyl]-2-thiophen-2-yl-1,3-oxazole
    —— (2R)-2-(cycloheptyliminomethyl)-1-benzothiophen-3-one —— C16H19NOS
    (2R)-2-(cycloheptyliminomethyl)-1-benzothiophen-3-one
    —— 6-Ethyl-3-methyl-2-(2-morpholin-4-yl-2-oxoethyl)sulfanylpyrimidin-4-one —— C13H19N3O3S
    6-Ethyl-3-methyl-2-(2-morpholin-4-yl-2-oxoethyl)sulfanylpyrimidin-4-one
    —— (2R)-N-(cyclohexylcarbamoyl)-2-(1-methylimidazol-2-yl)sulfanylpropanamide —— C14H22N4O2S
    (2R)-N-(cyclohexylcarbamoyl)-2-(1-methylimidazol-2-yl)sulfanylpropanamide
    —— N-(1-cyanocyclopentyl)-2-[(1-methyl-1H-imidazol-2-yl)sulfanyl]acetamide —— C12H16N4OS
    N-(1-cyanocyclopentyl)-2-[(1-methyl-1H-imidazol-2-yl)sulfanyl]acetamide
    —— N-(1-methylpiperidin-1-ium-4-yl)-2-phenylsulfanylacetamide —— C14H21N2OS+
    N-(1-methylpiperidin-1-ium-4-yl)-2-phenylsulfanylacetamide
    —— 1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone —— C19H17ClN4O2S
    1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C14H16ClN3OS
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— 4-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-2-phenylpyrimidine —— C16H16N6OS
    4-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-2-phenylpyrimidine
    —— N-(1-cyanocyclohexyl)-N-methyl-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C14H20N4OS
    N-(1-cyanocyclohexyl)-N-methyl-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— 2-[(1-Methylimidazol-2-yl)sulfanylmethyl]-5-phenyl-1,3,4-oxadiazole —— C13H12N4OS
    2-[(1-Methylimidazol-2-yl)sulfanylmethyl]-5-phenyl-1,3,4-oxadiazole