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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]hexanamide —— C8H14N4OS2
    (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]hexanamide
    —— 4-[(2R)-2-(aminomethyl)-2,3-dihydro-1-benzofuran-7-yl]-6-(4-methylphenyl)sulfanylpyrimidin-2-amine —— C20H20N4OS
    4-[(2R)-2-(aminomethyl)-2,3-dihydro-1-benzofuran-7-yl]-6-(4-methylphenyl)sulfanylpyrimidin-2-amine
    —— 4-[(2S)-2-(aminomethyl)-2,3-dihydro-1-benzofuran-7-yl]-6-(4-methylphenyl)sulfanylpyrimidin-2-amine —— C20H20N4OS
    4-[(2S)-2-(aminomethyl)-2,3-dihydro-1-benzofuran-7-yl]-6-(4-methylphenyl)sulfanylpyrimidin-2-amine
    —— 3-[(5Z)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]propanoate —— C14H12NO3S3-
    3-[(5Z)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]propanoate
    —— 2-(2-methylphenyl)sulfanyl-N-[[(3R)-1-methylpyrrolidin-3-yl]methyl]acetamide —— C15H22N2OS
    2-(2-methylphenyl)sulfanyl-N-[[(3R)-1-methylpyrrolidin-3-yl]methyl]acetamide
    —— 2-[[4-[(1R)-1-phenylethyl]-5-(pyrazol-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H17N5O2S
    2-[[4-[(1R)-1-phenylethyl]-5-(pyrazol-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-(2-methylphenyl)sulfanyl-N-[[(3S)-1-methylpyrrolidin-3-yl]methyl]acetamide —— C15H22N2OS
    2-(2-methylphenyl)sulfanyl-N-[[(3S)-1-methylpyrrolidin-3-yl]methyl]acetamide
    —— 2-[[4-[(1S)-1-phenylethyl]-5-(pyrazol-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H17N5O2S
    2-[[4-[(1S)-1-phenylethyl]-5-(pyrazol-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— N-methyl-N'-(4-methylene-1,5-cyclohexadien-1-yl)thiourea —— C9H12N2S
    N-methyl-N'-(4-methylene-1,5-cyclohexadien-1-yl)thiourea
    —— 1,3-Bis(4-methylidenecyclohexa-1,5-dien-1-yl)thiourea —— C15H16N2S
    1,3-Bis(4-methylidenecyclohexa-1,5-dien-1-yl)thiourea
    —— 2-(2-Chlorophenyl)-6-(4-morpholinyl)-4-pyrimidinyl propyl sulfide —— C17H20ClN3OS
    2-(2-Chlorophenyl)-6-(4-morpholinyl)-4-pyrimidinyl propyl sulfide
    —— (4S)-2-phenyl-4-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]-5-propyl-4H-pyrazol-3-one —— C21H19N3OS2
    (4S)-2-phenyl-4-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]-5-propyl-4H-pyrazol-3-one
    —— (4R)-4-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-2-phenyl-5-propyl-4H-pyrazol-3-one —— C22H21N3OS2
    (4R)-4-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-2-phenyl-5-propyl-4H-pyrazol-3-one
    —— 3-[(4-Chlorophenyl)methyl]-6-[(2,5-dimethylphenyl)sulfanylmethyl]-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole —— C19H17ClN4S2
    3-[(4-Chlorophenyl)methyl]-6-[(2,5-dimethylphenyl)sulfanylmethyl]-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
    —— 5-[(6-Methyl-2-pyrrolidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-3-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazole-2-thione —— C17H25N6OS2+
    5-[(6-Methyl-2-pyrrolidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-3-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazole-2-thione
    —— [4-(4-Hydroxyphenyl)sulfanylphenyl] cyclopentanecarboxylate —— C18H18O3S
    [4-(4-Hydroxyphenyl)sulfanylphenyl] cyclopentanecarboxylate
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(3S)-3-propylmorpholin-4-yl]ethanone —— C11H19N5O2S
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(3S)-3-propylmorpholin-4-yl]ethanone
    —— [4-(4-Methylsulfonyloxyphenyl)sulfanylphenyl] methanesulfonate 791840-52-3 C14H14O6S3
    [4-(4-Methylsulfonyloxyphenyl)sulfanylphenyl] methanesulfonate
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(3R)-3-propylmorpholin-4-yl]ethanone —— C11H19N5O2S
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(3R)-3-propylmorpholin-4-yl]ethanone
    —— 4-[(4-Hydroxyphenyl)sulfanyl]phenyl methanesulfonate —— C13H12O4S2
    4-[(4-Hydroxyphenyl)sulfanyl]phenyl methanesulfonate
    —— 2-[[5-(1,5-dimethylpyrazol-3-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H19N5O2S
    2-[[5-(1,5-dimethylpyrazol-3-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-(1,5-dimethylpyrazol-3-yl)-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H19N5O2S
    2-[[5-(1,5-dimethylpyrazol-3-yl)-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 4-[4-(3-Cyano-4,6-dimethylpyridin-2-yl)sulfanylanilino]-4-oxobutanoate —— C18H16N3O3S-
    4-[4-(3-Cyano-4,6-dimethylpyridin-2-yl)sulfanylanilino]-4-oxobutanoate
    —— Ethyl 5-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyltriazolo[1,5-a]quinazoline-3-carboxylate —— C20H16N6O2S
    Ethyl 5-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyltriazolo[1,5-a]quinazoline-3-carboxylate
    —— (4S)-N,6-dimethyl-N-[(5-methyl-1H-imidazol-2-yl)methyl]-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C19H23N5O2S
    (4S)-N,6-dimethyl-N-[(5-methyl-1H-imidazol-2-yl)methyl]-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— (4R)-N,6-dimethyl-N-[(5-methyl-1H-imidazol-2-yl)methyl]-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C19H23N5O2S
    (4R)-N,6-dimethyl-N-[(5-methyl-1H-imidazol-2-yl)methyl]-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— N-[(2R)-butan-2-yl]-3-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylpropanamide —— C16H18F3N3O2S
    N-[(2R)-butan-2-yl]-3-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylpropanamide
    —— 3-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[(2R)-1-methoxypropan-2-yl]propanamide —— C16H18F3N3O3S
    3-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[(2R)-1-methoxypropan-2-yl]propanamide
    —— 3-[(4-Chloroanilino)methyl]-5-[4-(methylsulfanyl)benzylidene]-1,3-thiazolidine-2,4-dione —— C18H15ClN2O2S2
    3-[(4-Chloroanilino)methyl]-5-[4-(methylsulfanyl)benzylidene]-1,3-thiazolidine-2,4-dione
    —— N-[(1S)-1-(5-methyl-1H-1,2,4-triazol-3-yl)ethyl]-2-pyridin-4-ylsulfanylacetamide —— C12H15N5OS
    N-[(1S)-1-(5-methyl-1H-1,2,4-triazol-3-yl)ethyl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(1R)-1-(5-methyl-1H-1,2,4-triazol-3-yl)ethyl]-2-pyridin-4-ylsulfanylacetamide —— C12H15N5OS
    N-[(1R)-1-(5-methyl-1H-1,2,4-triazol-3-yl)ethyl]-2-pyridin-4-ylsulfanylacetamide
    —— 2-[[5-(1,5-dimethylpyrazol-4-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H19N5O2S
    2-[[5-(1,5-dimethylpyrazol-4-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (E)-(diaminomethylideneamino)-[2-(4-methylphenyl)sulfanylethylidene]azanium —— C10H15N4S+
    (E)-(diaminomethylideneamino)-[2-(4-methylphenyl)sulfanylethylidene]azanium
    —— (E)-(diaminomethylideneamino)-(2-phenylsulfanylethylidene)azanium —— C9H13N4S+
    (E)-(diaminomethylideneamino)-(2-phenylsulfanylethylidene)azanium
    —— 6-Oxo-2-{[2-oxo-2-(2-thienyl)ethyl]sulfanyl}-4-(2-phenylethyl)-1,6-dihydro-5-pyrimidinecarbonitrile —— C19H15N3O2S2
    6-Oxo-2-{[2-oxo-2-(2-thienyl)ethyl]sulfanyl}-4-(2-phenylethyl)-1,6-dihydro-5-pyrimidinecarbonitrile
    —— (9aR)-8-methyl-2-[[5-(1H-1,2,4-triazol-5-ylsulfanyl)furan-2-yl]methyl]-1,3,4,6,7,9a-hexahydropyrazino[1,2-a]pyrazin-9-one —— C15H20N6O2S
    (9aR)-8-methyl-2-[[5-(1H-1,2,4-triazol-5-ylsulfanyl)furan-2-yl]methyl]-1,3,4,6,7,9a-hexahydropyrazino[1,2-a]pyrazin-9-one
    —— 2-Methylsulfanyl-9-oxo-4-thiophen-2-ylindeno[2,1-b]pyridine-3-carbonitrile 717843-65-7 C18H10N2OS2
    2-Methylsulfanyl-9-oxo-4-thiophen-2-ylindeno[2,1-b]pyridine-3-carbonitrile
    —— 9-Oxo-2-(2-oxopropylsulfanyl)-4-thiophen-2-ylindeno[2,1-b]pyridine-3-carbonitrile —— C20H12N2O2S2
    9-Oxo-2-(2-oxopropylsulfanyl)-4-thiophen-2-ylindeno[2,1-b]pyridine-3-carbonitrile
    —— (2S)-N-methyl-2-pyridin-2-ylsulfanyl-N-(thiophen-3-ylmethyl)propanamide —— C14H16N2OS2
    (2S)-N-methyl-2-pyridin-2-ylsulfanyl-N-(thiophen-3-ylmethyl)propanamide
    —— 2-[[5-[(4-hydroxyphenyl)methyl]-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C19H19N3O3S
    2-[[5-[(4-hydroxyphenyl)methyl]-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2R)-N-methyl-2-pyridin-2-ylsulfanyl-N-(thiophen-3-ylmethyl)propanamide —— C14H16N2OS2
    (2R)-N-methyl-2-pyridin-2-ylsulfanyl-N-(thiophen-3-ylmethyl)propanamide
    —— 2-[[5-[(4-hydroxyphenyl)methyl]-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C19H19N3O3S
    2-[[5-[(4-hydroxyphenyl)methyl]-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 4-[(2R,5S)-5-[(4,6-dimethylpyrimidin-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline —— C18H25N4OS+
    4-[(2R,5S)-5-[(4,6-dimethylpyrimidin-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline
    —— 4-[(2S,5R)-5-[(4,6-dimethylpyrimidin-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline —— C18H25N4OS+
    4-[(2S,5R)-5-[(4,6-dimethylpyrimidin-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline
    —— 2-(Methyliminomethyl)-1-benzothiophen-3-one —— C10H9NOS
    2-(Methyliminomethyl)-1-benzothiophen-3-one
    —— (2S)-2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]butanamide —— C17H21N3O3S
    (2S)-2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]butanamide
    —— 2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C15H17N3O3S
    2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— 2-[[5-(3-methylthiophen-2-yl)-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H17N3O2S2
    2-[[5-(3-methylthiophen-2-yl)-4-[(1R)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-(3-methylthiophen-2-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H17N3O2S2
    2-[[5-(3-methylthiophen-2-yl)-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— N-[[(3S)-1-cyclohexylpiperidin-3-yl]methyl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(pyridin-3-ylmethyl)acetamide —— C23H33N5O2S
    N-[[(3S)-1-cyclohexylpiperidin-3-yl]methyl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(pyridin-3-ylmethyl)acetamide