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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Propyl 3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C15H19N3O2S2
    Propyl 3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— (2R)-N-pentyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H20N4OS2
    (2R)-N-pentyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]pentanedinitrile —— C15H15N5S2
    (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]pentanedinitrile
    —— 3-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C12H14N4OS2
    3-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— Butyl 3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C16H21N3O2S2
    Butyl 3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— (2S)-N-pentyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H20N4OS2
    (2S)-N-pentyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-[(2-ethyl-1,3-thiazol-4-yl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C17H19N3OS2
    2-[(2-ethyl-1,3-thiazol-4-yl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)propanamide —— C17H20ClN3O2S
    (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)propanamide
    —— (2R)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)propanamide —— C19H26N4OS
    (2R)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)propanamide
    —— (2S)-N-(2-methylbutan-2-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H20N4OS2
    (2S)-N-(2-methylbutan-2-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)propanamide —— C19H26N4OS
    (2S)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)propanamide
    —— (2R)-N'-(4-methoxypyrimidin-2-yl)-2,3-dihydro-1-benzothiophene-2-carbohydrazide —— C14H14N4O2S
    (2R)-N'-(4-methoxypyrimidin-2-yl)-2,3-dihydro-1-benzothiophene-2-carbohydrazide
    —— (3R,4S)-1,1-dioxo-4-pyrimidin-2-ylsulfanylthiolan-3-ol —— C8H10N2O3S2
    (3R,4S)-1,1-dioxo-4-pyrimidin-2-ylsulfanylthiolan-3-ol
    —— 3-[(2R)-oxolan-2-yl]-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C15H16N6O2S
    3-[(2R)-oxolan-2-yl]-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)acetamide —— C21H24N4OS2
    2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)acetamide
    —— 3-[(2S)-oxolan-2-yl]-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C15H16N6O2S
    3-[(2S)-oxolan-2-yl]-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— (3R,4R)-1,1-dioxo-4-pyrimidin-2-ylsulfanylthiolan-3-ol —— C8H10N2O3S2
    (3R,4R)-1,1-dioxo-4-pyrimidin-2-ylsulfanylthiolan-3-ol
    —— 4-phenylsulfanyl-N-[(3-pyridin-4-yl-1,2,4-oxadiazol-5-yl)methyl]butanamide —— C18H18N4O2S
    4-phenylsulfanyl-N-[(3-pyridin-4-yl-1,2,4-oxadiazol-5-yl)methyl]butanamide
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H23ClN4OS
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H23ClN4OS
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C19H25N5O2S
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— N-(1-cyanocyclopentyl)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H23N5OS
    N-(1-cyanocyclopentyl)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (3S,4S)-1,1-dioxo-4-pyrimidin-2-ylsulfanylthiolan-3-ol —— C8H10N2O3S2
    (3S,4S)-1,1-dioxo-4-pyrimidin-2-ylsulfanylthiolan-3-ol
    —— N-[(2-chlorophenyl)methyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H21ClN4OS
    N-[(2-chlorophenyl)methyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(4-chlorophenyl)methyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H21ClN4OS
    N-[(4-chlorophenyl)methyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C17H14N4O3S2
    2-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H25FN4OS
    (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H19N5O3S
    N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H25FN4OS
    (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— ethyl 2,4-dimethyl-5-[(2S)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C19H28N4O3S
    ethyl 2,4-dimethyl-5-[(2S)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H25FN4OS
    (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-(1-cyanocyclohexyl)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H25N5OS
    N-(1-cyanocyclohexyl)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H25N5OS
    N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C21H34N4OS
    N-[(1R)-1-(1-adamantyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-methylbutyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H21N3O3S
    3-methylbutyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]propan-1-one —— C14H18N4OS2
    3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]propan-1-one
    —— 3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-thiophen-2-ylpyrrolidin-1-yl]propan-1-one —— C14H18N4OS2
    3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-thiophen-2-ylpyrrolidin-1-yl]propan-1-one
    —— 2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(S)-phenyl(pyridin-3-yl)methyl]acetamide —— C17H17N5OS
    2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(S)-phenyl(pyridin-3-yl)methyl]acetamide
    —— 3-[(2R)-1-methoxypropan-2-yl]-1-methyl-1-[(4-methylsulfanylphenyl)methyl]urea —— C14H22N2O2S
    3-[(2R)-1-methoxypropan-2-yl]-1-methyl-1-[(4-methylsulfanylphenyl)methyl]urea
    —— 3-[(2S)-1-methoxypropan-2-yl]-1-methyl-1-[(4-methylsulfanylphenyl)methyl]urea —— C14H22N2O2S
    3-[(2S)-1-methoxypropan-2-yl]-1-methyl-1-[(4-methylsulfanylphenyl)methyl]urea
    —— 2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-2-methyl-4-oxopentan-3-yl]acetamide —— C12H20N4O2S
    2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-2-methyl-4-oxopentan-3-yl]acetamide
    —— 1-[(5S)-6-chloro-8,8,9,9-tetrafluoro-1-oxa-4-thiaspiro[4.4]non-6-en-7-yl]-4-methylpiperazine —— C12H15ClF4N2OS
    1-[(5S)-6-chloro-8,8,9,9-tetrafluoro-1-oxa-4-thiaspiro[4.4]non-6-en-7-yl]-4-methylpiperazine
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C21H34N4OS
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 7-[(4-Pentyl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C14H17N5OS2
    7-[(4-Pentyl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 2-(2,5-Dimethylfuran-3-yl)-5-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C14H13N3O3S
    2-(2,5-Dimethylfuran-3-yl)-5-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C17H24N4O2S
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— N-(1-adamantylmethyl)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C20H32N4OS
    N-(1-adamantylmethyl)-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H25N5OS
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— ethyl 2,4-dimethyl-5-[2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate —— C18H26N4O3S
    ethyl 2,4-dimethyl-5-[2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate
    —— N-[(1R)-1-(4-bromophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H23BrN4OS
    N-[(1R)-1-(4-bromophenyl)ethyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide