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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[[3-[(4-Amino-5-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-5-ethyl-1,2,4-triazol-4-amine —— C16H22N8S2
    3-[[3-[(4-Amino-5-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-5-ethyl-1,2,4-triazol-4-amine
    —— 3-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-5-ethyl-1,2,4-triazol-4-amine —— C11H12ClFN4S
    3-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-5-ethyl-1,2,4-triazol-4-amine
    —— 3-[(2-Bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-amine —— C10H11BrN4S
    3-[(2-Bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-amine
    —— N-[(Z)-benzylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C16H16N2OS
    N-[(Z)-benzylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[4-hydroxy-3-(1H-1,2,4-triazol-3-ylsulfanyl)phenyl]-2,4-dimethylbenzenesulfonamide —— C16H16N4O3S2
    N-[4-hydroxy-3-(1H-1,2,4-triazol-3-ylsulfanyl)phenyl]-2,4-dimethylbenzenesulfonamide
    —— 5-[(2-chlorophenyl)methyl]-4-methyl-2-methylsulfanyl-1H-pyrimidin-6-one —— C13H13ClN2OS
    5-[(2-chlorophenyl)methyl]-4-methyl-2-methylsulfanyl-1H-pyrimidin-6-one
    —— 5-[(2-chlorophenyl)methyl]-2-ethylsulfanyl-4-methyl-1H-pyrimidin-6-one —— C14H15ClN2OS
    5-[(2-chlorophenyl)methyl]-2-ethylsulfanyl-4-methyl-1H-pyrimidin-6-one
    —— 3-[[4-(2,5-difluorophenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid —— C12H9F2NO2S2
    3-[[4-(2,5-difluorophenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 2,6-difluorobenzoate —— C21H15F2NO3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 2,6-difluorobenzoate
    —— 3-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid —— C12H10ClNO2S2
    3-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid
    —— 3-(3-chlorophenyl)sulfanyl-1-(1,4-diazepan-1-yl)propan-1-one —— C14H19ClN2OS
    3-(3-chlorophenyl)sulfanyl-1-(1,4-diazepan-1-yl)propan-1-one
    —— 2-(4-chloro-3-methylphenyl)sulfanyl-1-(1,4-diazepan-1-yl)ethanone —— C14H19ClN2OS
    2-(4-chloro-3-methylphenyl)sulfanyl-1-(1,4-diazepan-1-yl)ethanone
    —— 3-[[4-(4-fluoro-3-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid —— C13H12FNO2S2
    3-[[4-(4-fluoro-3-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid
    —— 2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(3-chlorophenyl)ethyl]acetamide —— C20H21ClN4OS
    2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(3-chlorophenyl)ethyl]acetamide
    —— 2-[(5-Benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C21H21N5OS
    2-[(5-Benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— 2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-chlorophenyl)methyl]acetamide —— C19H19ClN4OS
    2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-chlorophenyl)methyl]acetamide
    —— 1-(1,4-diazepan-1-yl)-3-(4-fluoro-2-methylphenyl)sulfanylpropan-1-one —— C15H21FN2OS
    1-(1,4-diazepan-1-yl)-3-(4-fluoro-2-methylphenyl)sulfanylpropan-1-one
    —— 1-(1,4-diazepan-1-yl)-3-(4-fluoro-3-methylphenyl)sulfanylpropan-1-one —— C15H21FN2OS
    1-(1,4-diazepan-1-yl)-3-(4-fluoro-3-methylphenyl)sulfanylpropan-1-one
    —— (2E,5S)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-2-methylpropylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C15H17F2N3OS2
    (2E,5S)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-2-methylpropylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (7Z)-2-methylsulfanyl-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile —— C19H14N2S3
    (7Z)-2-methylsulfanyl-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile
    —— 3-[[4-Benzyl-5-[(4-chloroanilino)methyl]-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C19H18ClN4O2S-
    3-[[4-Benzyl-5-[(4-chloroanilino)methyl]-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— 3-[[4-(2,5-dimethylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid —— C14H15NO2S2
    3-[[4-(2,5-dimethylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid
    —— 3-[[4-(4-ethylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid —— C14H15NO2S2
    3-[[4-(4-ethylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid
    —— 3-[[4-(3,4-dimethylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid —— C14H15NO2S2
    3-[[4-(3,4-dimethylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid
    —— 3-[[4-(2,4-dimethylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid —— C14H15NO2S2
    3-[[4-(2,4-dimethylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanoic acid
    —— 1-(1,4-Diazepan-1-yl)-3-(3,4-dimethylphenyl)sulfanylpropan-1-one —— C16H24N2OS
    1-(1,4-Diazepan-1-yl)-3-(3,4-dimethylphenyl)sulfanylpropan-1-one
    —— 1-(1,4-diazepan-1-yl)-3-(2,4-dimethylphenyl)sulfanylpropan-1-one —— C16H24N2OS
    1-(1,4-diazepan-1-yl)-3-(2,4-dimethylphenyl)sulfanylpropan-1-one
    —— 1-(1,4-diazepan-1-yl)-2-(2,4,6-trimethylphenyl)sulfanylethanone —— C16H24N2OS
    1-(1,4-diazepan-1-yl)-2-(2,4,6-trimethylphenyl)sulfanylethanone
    —— 1-(1,4-diazepan-1-yl)-3-(2,5-dimethylphenyl)sulfanylpropan-1-one —— C16H24N2OS
    1-(1,4-diazepan-1-yl)-3-(2,5-dimethylphenyl)sulfanylpropan-1-one
    —— 1-(1,4-diazepan-1-yl)-3-(4-ethylphenyl)sulfanylpropan-1-one —— C16H24N2OS
    1-(1,4-diazepan-1-yl)-3-(4-ethylphenyl)sulfanylpropan-1-one
    —— (3R)-3-[(5-bromothiophen-2-yl)sulfanylmethyl]piperidine —— C10H14BrNS2
    (3R)-3-[(5-bromothiophen-2-yl)sulfanylmethyl]piperidine
    —— 4-(Diethylamino)-2-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-6-thiophen-2-ylpyridin-1-ium-3-carbonitrile —— C20H20N3OS3+
    4-(Diethylamino)-2-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-6-thiophen-2-ylpyridin-1-ium-3-carbonitrile
    —— (3S)-3-[(5-bromothiophen-2-yl)sulfanylmethyl]piperidine —— C10H14BrNS2
    (3S)-3-[(5-bromothiophen-2-yl)sulfanylmethyl]piperidine
    —— 2-(5-chlorothiophen-2-yl)sulfanyl-1-(1,4-diazepan-1-yl)ethanone —— C11H15ClN2OS2
    2-(5-chlorothiophen-2-yl)sulfanyl-1-(1,4-diazepan-1-yl)ethanone
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 2-methylbenzoate —— C24H23NO3S
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 2-methylbenzoate
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] cyclobutanecarboxylate —— C21H23NO3S
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] cyclobutanecarboxylate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 4-cyanobenzoate —— C22H16N2O3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 4-cyanobenzoate
    —— 6-Amino-1-methyl-5-[2-(2,3,5,6-tetramethylphenyl)sulfanylacetyl]pyrimidine-2,4-dione —— C17H21N3O3S
    6-Amino-1-methyl-5-[2-(2,3,5,6-tetramethylphenyl)sulfanylacetyl]pyrimidine-2,4-dione
    —— 4-(2-phenylethyl)-3-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C18H17N5O2S2
    4-(2-phenylethyl)-3-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 6-Amino-1-methyl-5-[2-(2,3,4,5,6-pentafluorophenyl)sulfanylacetyl]pyrimidine-2,4-dione —— C13H8F5N3O3S
    6-Amino-1-methyl-5-[2-(2,3,4,5,6-pentafluorophenyl)sulfanylacetyl]pyrimidine-2,4-dione
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C11H17N5O3S2
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C11H17N5O3S2
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C16H16FN3O5S
    [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C17H15FN2O3S2
    [(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— [(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C16H13FN2O3S2
    [(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C18H18N2O3S2
    [(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C16H13FN2O3S2
    [(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— 6-Amino-5-[2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-methylpyrimidine-2,4-dione —— C17H18N6O3S
    6-Amino-5-[2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-methylpyrimidine-2,4-dione
    —— N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H21N3O4S2
    N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— [(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 2-phenylsulfanylacetate —— C16H14N2O3S2
    [(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 2-phenylsulfanylacetate