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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-Chlorophenyl)-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole —— C13H10ClN3O2S
    2-(4-Chlorophenyl)-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 3-[(5-Methyl-1,2-oxazol-3-yl)methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-amine —— C8H8F3N5OS
    3-[(5-Methyl-1,2-oxazol-3-yl)methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-amine
    —— 4,6-Diamino-3-prop-2-enylsulfanyl-1,2,4-triazin-5-one —— C6H9N5OS
    4,6-Diamino-3-prop-2-enylsulfanyl-1,2,4-triazin-5-one
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C13H14F3N5OS2
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C13H17N5OS2
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C11H15N5OS2
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-chlorophenyl)sulfanylethyl]acetamide —— C13H13ClF3N5OS2
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-chlorophenyl)sulfanylethyl]acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2,4-dimethylphenyl)methyl]-N-methylacetamide —— C15H21N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2,4-dimethylphenyl)methyl]-N-methylacetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C16H14ClN3O2S2
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— 2-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone —— C17H17N3OS3
    2-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone
    —— N-(2-thiophen-2-ylethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C10H12N4OS2
    N-(2-thiophen-2-ylethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-[(1S)-1-(1-oxidopyridin-1-ium-2-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C15H13N3O2S
    2-[(1S)-1-(1-oxidopyridin-1-ium-2-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— [2-(2,5-Dimethylthiophen-3-yl)-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C17H17BrO3S2
    [2-(2,5-Dimethylthiophen-3-yl)-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— N-[2-(4-methylphenyl)sulfanylethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C16H18N2O2S2
    N-[2-(4-methylphenyl)sulfanylethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-(2-phenylsulfanylethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H14N4OS2
    N-(2-phenylsulfanylethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-(4,5-dichloro-6-oxopyridazin-1-yl)-N-(2-phenylsulfanylethyl)acetamide —— C14H13Cl2N3O2S
    2-(4,5-dichloro-6-oxopyridazin-1-yl)-N-(2-phenylsulfanylethyl)acetamide
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13ClN4OS2
    N-[2-(4-chlorophenyl)sulfanylethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C15H15ClN2O2S2
    N-[2-(4-chlorophenyl)sulfanylethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 2-[(1R)-1-(1-methyltetrazol-5-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C12H12N6OS
    2-[(1R)-1-(1-methyltetrazol-5-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[(1R)-1-(4-bromophenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C16H13BrN2OS
    2-[(1R)-1-(4-bromophenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— [2-(2,5-Dimethylthiophen-3-yl)-2-oxoethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C22H17NO3S2
    [2-(2,5-Dimethylthiophen-3-yl)-2-oxoethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— 2-(4-bromophenyl)sulfanyl-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C17H18BrNOS2
    2-(4-bromophenyl)sulfanyl-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 2-[(1S)-1-(1-methyltetrazol-5-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C12H12N6OS
    2-[(1S)-1-(1-methyltetrazol-5-yl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 2-(2-chloro-6-fluorophenyl)acetate —— C19H19ClFNO3S
    [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 2-(2-chloro-6-fluorophenyl)acetate
    —— 2-[(1S)-1-(2-chlorophenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole —— C16H13ClN2OS
    2-[(1S)-1-(2-chlorophenyl)sulfanylethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2,4-dimethylphenyl)methyl]-N-methylacetamide —— C14H18N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2,4-dimethylphenyl)methyl]-N-methylacetamide
    —— 5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C12H11N5OS2
    5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 2-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone —— C10H11N3OS3
    2-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone
    —— 2-(2-chlorophenyl)sulfanyl-N-[2-(4-chlorophenyl)sulfanylethyl]acetamide —— C16H15Cl2NOS2
    2-(2-chlorophenyl)sulfanyl-N-[2-(4-chlorophenyl)sulfanylethyl]acetamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone —— C10H12N4OS2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone
    —— [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] 2-phenylacetate —— C18H18ClNO3S
    [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] 2-phenylacetate
    —— 3-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-amine —— C12H12N6OS
    3-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-amine
    —— [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 2-(1-adamantyl)acetate —— C22H29NO3S
    [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 2-(1-adamantyl)acetate
    —— [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] 3-phenylpropanoate —— C19H20ClNO3S
    [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] 3-phenylpropanoate
    —— [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 3-phenylpropanoate —— C20H23NO3S
    [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 3-phenylpropanoate
    —— [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 3-phenylpropanoate —— C19H21NO3S
    [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 3-phenylpropanoate
    —— [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 2-phenylacetate —— C19H21NO3S
    [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 2-phenylacetate
    —— [2-oxo-2-(2-phenylsulfanylethylamino)ethyl] (E)-3-(5-bromofuran-2-yl)prop-2-enoate —— C17H16BrNO4S
    [2-oxo-2-(2-phenylsulfanylethylamino)ethyl] (E)-3-(5-bromofuran-2-yl)prop-2-enoate
    —— 3-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C7H9N5OS
    3-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— 2-(4-chlorophenyl)sulfanyl-N-(2-thiophen-2-ylethyl)acetamide —— C14H14ClNOS2
    2-(4-chlorophenyl)sulfanyl-N-(2-thiophen-2-ylethyl)acetamide
    —— 4-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine —— C15H16N4S4
    4-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine
    —— (1'S,5'R)-N-[(1R)-1-(1-adamantyl)ethyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide —— C24H37NOS2
    (1'S,5'R)-N-[(1R)-1-(1-adamantyl)ethyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide
    —— N-(4-methylphenyl)-4-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazol-2-amine —— C16H19N5S2
    N-(4-methylphenyl)-4-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazol-2-amine
    —— (1'S,5'R)-N-[(1S)-1-(1-adamantyl)ethyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide —— C24H37NOS2
    (1'S,5'R)-N-[(1S)-1-(1-adamantyl)ethyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide
    —— 4-[(3,4-difluorophenyl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine —— C17H14F2N2S2
    4-[(3,4-difluorophenyl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine
    —— 5-[(1-butyltetrazol-5-yl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine —— C16H21N7S2
    5-[(1-butyltetrazol-5-yl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine
    —— N-(4-methylphenyl)-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C17H15N5OS3
    N-(4-methylphenyl)-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-(3,4-dimethylphenyl)-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C18H17N5OS3
    N-(3,4-dimethylphenyl)-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 5-[(1-butyltetrazol-5-yl)methylsulfanyl]-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine —— C15H19N7S2
    5-[(1-butyltetrazol-5-yl)methylsulfanyl]-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— N-(3,4-dimethylphenyl)-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C18H17N5OS3
    N-(3,4-dimethylphenyl)-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine