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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C17H16FN3O3S
    (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N-(1-adamantylmethyl)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H23N3O3S
    N-(1-adamantylmethyl)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(4-chlorophenyl)ethyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H14ClN3O3S
    N-[2-(4-chlorophenyl)ethyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 1-(1-Adamantyl)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C18H20N2O3S
    1-(1-Adamantyl)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— 2-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]ethanone —— C17H19N3O4S
    2-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— 2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(propan-2-ylcarbamoyl)acetamide —— C12H14N4O4S
    2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(propan-2-ylcarbamoyl)acetamide
    —— ethyl 5-[2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C17H17N3O5S
    ethyl 5-[2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[[(2S)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide —— C21H27N3OS
    2-(2,4-dimethylphenyl)sulfanyl-N-[[(2S)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide
    —— N-[(3-chlorophenyl)methyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C15H12ClN3O3S
    N-[(3-chlorophenyl)methyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[[(2S)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide —— C19H22BrN3OS
    2-(4-bromophenyl)sulfanyl-N-[[(2S)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide
    —— 2-(3,4-dimethylphenyl)sulfanyl-N-[[(2S)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide —— C21H27N3OS
    2-(3,4-dimethylphenyl)sulfanyl-N-[[(2S)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide
    —— 5-Benzyl-2-[(4-fluorophenyl)methylsulfanyl]-3,6-dimethylpyrimidin-4-one —— C20H19FN2OS
    5-Benzyl-2-[(4-fluorophenyl)methylsulfanyl]-3,6-dimethylpyrimidin-4-one
    —— methyl (2S)-2-[1,4-dimethyl-5-[(4-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylpropanoate —— C18H22N2O3S
    methyl (2S)-2-[1,4-dimethyl-5-[(4-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylpropanoate
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[[(2R)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide —— C21H27N3OS
    2-(2,4-dimethylphenyl)sulfanyl-N-[[(2R)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide
    —— 2-(3,4-dimethylphenyl)sulfanyl-N-[[(2R)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide —— C21H27N3OS
    2-(3,4-dimethylphenyl)sulfanyl-N-[[(2R)-1-ethylpyrrolidin-2-yl]methyl]pyridine-3-carboxamide
    —— 1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone —— C20H16ClN3O3S
    1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone
    —— 1-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone —— C18H22N2O3S
    1-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone
    —— 2-Ethanimidoyl-4-(1-oxidopyridin-1-ium-2-yl)sulfanyl-3-oxobutanenitrile —— C11H11N3O2S
    2-Ethanimidoyl-4-(1-oxidopyridin-1-ium-2-yl)sulfanyl-3-oxobutanenitrile
    —— 2-(4-bromophenyl)sulfanyl-N-[(2R)-3-methylbutan-2-yl]pyridine-3-carboxamide —— C17H19BrN2OS
    2-(4-bromophenyl)sulfanyl-N-[(2R)-3-methylbutan-2-yl]pyridine-3-carboxamide
    —— N-[(2S)-3-methylbutan-2-yl]-2-phenylsulfanylpyridine-3-carboxamide —— C17H20N2OS
    N-[(2S)-3-methylbutan-2-yl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[(2R)-3-methylbutan-2-yl]-2-phenylsulfanylpyridine-3-carboxamide —— C17H20N2OS
    N-[(2R)-3-methylbutan-2-yl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H18F2N4OS2
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]pyridine-3-carboxamide —— C17H19BrN2OS
    2-(4-bromophenyl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]pyridine-3-carboxamide
    —— (2S)-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C9H11N2O3S-
    (2S)-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— (2S)-2-(4-methylphenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)propanamide —— C17H27N2O2S+
    (2S)-2-(4-methylphenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)propanamide
    —— N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H18F2N4OS2
    N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C9H11N2O3S-
    (2R)-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— N-[(1R)-1-[3-(2-oxo-1,3-oxazolidin-3-yl)phenyl]ethyl]-3-phenylsulfanylpropanamide —— C20H22N2O3S
    N-[(1R)-1-[3-(2-oxo-1,3-oxazolidin-3-yl)phenyl]ethyl]-3-phenylsulfanylpropanamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(1R)-1-[3-(2-oxo-1,3-oxazolidin-3-yl)phenyl]ethyl]acetamide —— C19H19ClN2O3S
    2-(4-chlorophenyl)sulfanyl-N-[(1R)-1-[3-(2-oxo-1,3-oxazolidin-3-yl)phenyl]ethyl]acetamide
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-(3-morpholin-4-ylpropyl)propanamide —— C17H26N2O2S
    (2R)-2-(4-methylphenyl)sulfanyl-N-(3-morpholin-4-ylpropyl)propanamide
    —— (2R)-N-(3-morpholin-4-ylpropyl)-2-phenylsulfanylpropanamide —— C16H24N2O2S
    (2R)-N-(3-morpholin-4-ylpropyl)-2-phenylsulfanylpropanamide
    —— (2R)-N-(3-morpholin-4-ium-4-ylpropyl)-2-phenylsulfanylpropanamide —— C16H25N2O2S+
    (2R)-N-(3-morpholin-4-ium-4-ylpropyl)-2-phenylsulfanylpropanamide
    —— [(E)-1-(3-methylsulfanyl-1,2,4-triazin-5-yl)ethylideneamino]thiourea —— C7H10N6S2
    [(E)-1-(3-methylsulfanyl-1,2,4-triazin-5-yl)ethylideneamino]thiourea
    —— (2S)-N-(3-morpholin-4-ium-4-ylpropyl)-2-phenylsulfanylpropanamide —— C16H25N2O2S+
    (2S)-N-(3-morpholin-4-ium-4-ylpropyl)-2-phenylsulfanylpropanamide
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)propanamide —— C17H27N2O2S+
    (2R)-2-(4-methylphenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)propanamide
    —— (2Z)-2-[(4-methylanilino)methylidene]-1-benzothiophen-3-one —— C16H13NOS
    (2Z)-2-[(4-methylanilino)methylidene]-1-benzothiophen-3-one
    —— N-[(E)-1-(3-methylsulfanyl-1,2,4-triazin-5-yl)ethylideneamino]acetamide —— C8H11N5OS
    N-[(E)-1-(3-methylsulfanyl-1,2,4-triazin-5-yl)ethylideneamino]acetamide
    —— (2S)-2-(4-methylphenyl)sulfanyl-N-(3-morpholin-4-ylpropyl)propanamide —— C17H26N2O2S
    (2S)-2-(4-methylphenyl)sulfanyl-N-(3-morpholin-4-ylpropyl)propanamide
    —— 2-(N-benzyl-C-methylcarbonimidoyl)-1-benzothiophen-3-one —— C17H15NOS
    2-(N-benzyl-C-methylcarbonimidoyl)-1-benzothiophen-3-one
    —— N-ethyl-3-{[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}propanamide —— C12H15N3O3S
    N-ethyl-3-{[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}propanamide
    —— (2R)-2-(3-chlorophenyl)-2-thiophen-2-ylsulfanylacetic acid —— C12H9ClO2S2
    (2R)-2-(3-chlorophenyl)-2-thiophen-2-ylsulfanylacetic acid
    —— (2S)-5-(trifluoromethyl)-2,3-dihydro-1-benzothiophene-2-carboxylic acid —— C10H7F3O2S
    (2S)-5-(trifluoromethyl)-2,3-dihydro-1-benzothiophene-2-carboxylic acid
    —— (2R)-5-(trifluoromethyl)-2,3-dihydro-1-benzothiophene-2-carboxylic acid —— C10H7F3O2S
    (2R)-5-(trifluoromethyl)-2,3-dihydro-1-benzothiophene-2-carboxylic acid
    —— (2S)-2-(3-chlorophenyl)-2-thiophen-2-ylsulfanylacetic acid —— C12H9ClO2S2
    (2S)-2-(3-chlorophenyl)-2-thiophen-2-ylsulfanylacetic acid
    —— 1-(4-Methylpiperazin-1-yl)-3-(phenylsulfanyl)propan-1-one —— C14H20N2OS
    1-(4-Methylpiperazin-1-yl)-3-(phenylsulfanyl)propan-1-one
    —— N-[(2R)-1-methylsulfonylpropan-2-yl]cyclopropanamine —— C7H15NO2S
    N-[(2R)-1-methylsulfonylpropan-2-yl]cyclopropanamine
    —— (2S)-1-ethylsulfonyl-N-methylpropan-2-amine —— C6H15NO2S
    (2S)-1-ethylsulfonyl-N-methylpropan-2-amine
    —— 1-(4-Methylpiperazin-4-ium-1-yl)-3-phenylsulfanylpropan-1-one —— C14H21N2OS+
    1-(4-Methylpiperazin-4-ium-1-yl)-3-phenylsulfanylpropan-1-one
    —— N-[(2S)-1-methylsulfonylpropan-2-yl]cyclopropanamine —— C7H15NO2S
    N-[(2S)-1-methylsulfonylpropan-2-yl]cyclopropanamine
    —— (2S)-2-amino-2-methylpentanethioamide —— C6H14N2S
    (2S)-2-amino-2-methylpentanethioamide