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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(1R)-1-(2,6-difluorophenyl)ethyl]sulfanyl-6-methylpyrimidin-4-amine —— C13H13F2N3S
    2-[(1R)-1-(2,6-difluorophenyl)ethyl]sulfanyl-6-methylpyrimidin-4-amine
    —— 2-[(1S)-1-(2,6-difluorophenyl)ethyl]sulfanyl-6-methylpyrimidin-4-amine —— C13H13F2N3S
    2-[(1S)-1-(2,6-difluorophenyl)ethyl]sulfanyl-6-methylpyrimidin-4-amine
    —— (3S)-3-[[5-(furan-2-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanylmethyl]-1-methylpiperidine —— C16H22N4OS
    (3S)-3-[[5-(furan-2-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanylmethyl]-1-methylpiperidine
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(2R)-2-hydroxybutyl]piperazin-1-yl]methanone —— C17H24N2O3S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(2R)-2-hydroxybutyl]piperazin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(2S)-2-hydroxybutyl]piperazin-1-yl]methanone —— C17H24N2O3S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(2S)-2-hydroxybutyl]piperazin-1-yl]methanone
    —— (2S)-N-[(E)-3-chloroprop-2-enyl]-N-methyl-1-methylsulfonylpropan-2-amine —— C8H16ClNO2S
    (2S)-N-[(E)-3-chloroprop-2-enyl]-N-methyl-1-methylsulfonylpropan-2-amine
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(2S)-2-hydroxybutyl]piperazin-1-yl]methanone —— C17H24N2O3S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(2S)-2-hydroxybutyl]piperazin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(2R)-2-hydroxybutyl]piperazin-1-yl]methanone —— C17H24N2O3S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(2R)-2-hydroxybutyl]piperazin-1-yl]methanone
    —— (2R)-N-[(E)-3-chloroprop-2-enyl]-N-methyl-1-methylsulfonylpropan-2-amine —— C8H16ClNO2S
    (2R)-N-[(E)-3-chloroprop-2-enyl]-N-methyl-1-methylsulfonylpropan-2-amine
    —— 2-[4,5-dimethyl-1-(2-methylpropyl)imidazol-2-yl]sulfanyl-N-(2-phenylsulfanylphenyl)acetamide —— C23H27N3OS2
    2-[4,5-dimethyl-1-(2-methylpropyl)imidazol-2-yl]sulfanyl-N-(2-phenylsulfanylphenyl)acetamide
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C18H21N3OS
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— 2-[(1S)-2,2,2-trifluoro-1-phenylethyl]sulfanyl-1,3,4-thiadiazole —— C10H7F3N2S2
    2-[(1S)-2,2,2-trifluoro-1-phenylethyl]sulfanyl-1,3,4-thiadiazole
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C18H21N3OS
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C18H21N3OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— 2-[(1R)-2,2,2-trifluoro-1-phenylethyl]sulfanyl-1,3,4-thiadiazole —— C10H7F3N2S2
    2-[(1R)-2,2,2-trifluoro-1-phenylethyl]sulfanyl-1,3,4-thiadiazole
    —— N-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-(1-methylpyrazol-4-yl)propanamide —— C17H23N3OS
    N-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-(1-methylpyrazol-4-yl)propanamide
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone —— C18H21N3OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-[(4-methylpyrazol-1-yl)methyl]pyrrolidin-1-yl]methanone
    —— N-[(S)-phenyl(1,3-thiazol-2-yl)methyl]-2-pyridin-2-ylsulfanylacetamide —— C17H15N3OS2
    N-[(S)-phenyl(1,3-thiazol-2-yl)methyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(R)-phenyl(1,3-thiazol-2-yl)methyl]-2-pyridin-2-ylsulfanylacetamide —— C17H15N3OS2
    N-[(R)-phenyl(1,3-thiazol-2-yl)methyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-3-(1-methylpyrazol-4-yl)propanamide —— C17H23N3OS
    N-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-3-(1-methylpyrazol-4-yl)propanamide
    —— 2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(R)-cyclopropyl-(4-methylphenyl)methyl]acetamide —— C18H22N4OS
    2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(R)-cyclopropyl-(4-methylphenyl)methyl]acetamide
    —— 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C22H26N4O2S
    2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C22H26N4O2S
    2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— N-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3,4-dimethyl-6-oxo-1H-pyridazine-5-carboxamide —— C17H21N3O2S
    N-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3,4-dimethyl-6-oxo-1H-pyridazine-5-carboxamide
    —— N-methyl-N-[4-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazol-2-yl]acetamide —— C14H19N5O3S2
    N-methyl-N-[4-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazol-2-yl]acetamide
    —— [2-oxo-2-[[(1R)-1-phenylbutyl]amino]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C22H27NO3S
    [2-oxo-2-[[(1R)-1-phenylbutyl]amino]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-oxo-2-[[(1R)-1-phenylbutyl]amino]ethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C22H27NO3S
    [2-oxo-2-[[(1R)-1-phenylbutyl]amino]ethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— 2-(3-bromophenyl)-5-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H12BrFN2OS
    2-(3-bromophenyl)-5-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide —— C16H15BrN4O2S
    2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C21H23N3O2S
    2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 2-(3-Bromophenyl)-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,3,4-oxadiazole —— C16H13BrN2OS2
    2-(3-Bromophenyl)-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-(3-bromophenyl)-5-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H12BrClN2OS
    2-(3-bromophenyl)-5-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide —— C16H15BrN4O2S
    2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-(2-chlorophenyl)sulfanyl-1-[4-[[(2R)-oxolan-2-yl]methyl]piperazin-1-yl]ethanone —— C17H23ClN2O2S
    2-(2-chlorophenyl)sulfanyl-1-[4-[[(2R)-oxolan-2-yl]methyl]piperazin-1-yl]ethanone
    —— 2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide —— C14H16BrN3O3S
    2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide
    —— [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C22H27NO3S
    [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— 3-[[(3S)-1-methylpiperidin-3-yl]methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C14H24N4O2S
    3-[[(3S)-1-methylpiperidin-3-yl]methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C22H25N3O2S
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cycloheptylacetamide —— C17H20BrN3O2S
    2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cycloheptylacetamide
    —— 2-(3-Bromophenyl)-5-[(3-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazole —— C15H10BrClN2OS
    2-(3-Bromophenyl)-5-[(3-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2R)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylpropanamide —— C16H18BrN3O2S
    (2R)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylpropanamide
    —— 4-[[5-(3-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile —— C14H11BrN4O2S
    4-[[5-(3-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile
    —— 3-[[(3R)-1-methylpiperidin-3-yl]methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C14H24N4O2S
    3-[[(3R)-1-methylpiperidin-3-yl]methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— 2-(3-Bromophenyl)-5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazole —— C16H13BrN2OS
    2-(3-Bromophenyl)-5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-(2-chlorophenyl)sulfanyl-1-[4-[[(2S)-oxolan-2-yl]methyl]piperazin-1-yl]ethanone —— C17H23ClN2O2S
    2-(2-chlorophenyl)sulfanyl-1-[4-[[(2S)-oxolan-2-yl]methyl]piperazin-1-yl]ethanone
    —— (2S)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylpropanamide —— C16H18BrN3O2S
    (2S)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylpropanamide
    —— 2-(3-bromophenyl)-5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H12BrClN2OS
    2-(3-bromophenyl)-5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C15H19N3OS2
    2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 4-[[5-(3-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one —— C16H13BrN2O2S2
    4-[[5-(3-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one
    —— 2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylacetamide —— C15H16BrN3O2S
    2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylacetamide