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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(3-Bromophenyl)methylsulfanyl]-5-(3-chlorophenyl)-1,3,4-oxadiazole —— C15H10BrClN2OS
    2-[(3-Bromophenyl)methylsulfanyl]-5-(3-chlorophenyl)-1,3,4-oxadiazole
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]propanamide —— C19H22ClN3O2S
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]propanamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide —— C19H18ClN3O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide
    —— 1-[2-[[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrolidin-2-one —— C14H12ClN3O3S
    1-[2-[[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrolidin-2-one
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide —— C14H16ClN3O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide
    —— 7-({[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-YL]sulfanyl}methyl)-5H-[1,3]thiazolo[3,2-A]pyrimidin-5-one —— C15H9ClN4O2S2
    7-({[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-YL]sulfanyl}methyl)-5H-[1,3]thiazolo[3,2-A]pyrimidin-5-one
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide —— C16H15ClN4O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]acetamide —— C15H13ClN4O4S2
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]acetamide
    —— 4-[[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one —— C16H13ClN2O2S2
    4-[[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide —— C14H16ClN3O3S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C14H13ClN2O2S
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— N-[(2-chlorophenyl)methyl]-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H13Cl2N3O2S
    N-[(2-chlorophenyl)methyl]-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide —— C18H15ClFN3O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide
    —— (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C14H13ClN2O2S
    (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (2R)-2-phenylsulfanylpropanehydrazide —— C9H12N2OS
    (2R)-2-phenylsulfanylpropanehydrazide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C14H16ClN3O3S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— N-[2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide —— C16H13ClN4O3S
    N-[2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide
    —— (2R)-2-(4-methylphenyl)sulfanylpropanehydrazide —— C10H14N2OS
    (2R)-2-(4-methylphenyl)sulfanylpropanehydrazide
    —— (2S)-2-(4-methylphenyl)sulfanylpropanehydrazide —— C10H14N2OS
    (2S)-2-(4-methylphenyl)sulfanylpropanehydrazide
    —— (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetic acid —— C12H13N3O2S
    (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetic acid
    —— (1R,2S)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-methylcyclohexan-1-amine —— C15H22ClNS
    (1R,2S)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-methylcyclohexan-1-amine
    —— (2S)-N-[2-(4-methylphenyl)sulfanylethyl]heptan-2-amine —— C16H27NS
    (2S)-N-[2-(4-methylphenyl)sulfanylethyl]heptan-2-amine
    —— (1S,3R)-N-[2-(4-bromophenyl)sulfanylethyl]-3-methylcyclohexan-1-amine —— C15H22BrNS
    (1S,3R)-N-[2-(4-bromophenyl)sulfanylethyl]-3-methylcyclohexan-1-amine
    —— (1S,3S)-N-[2-(4-bromophenyl)sulfanylethyl]-3-methylcyclohexan-1-amine —— C15H22BrNS
    (1S,3S)-N-[2-(4-bromophenyl)sulfanylethyl]-3-methylcyclohexan-1-amine
    —— (1S,2R)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-methylcyclohexan-1-amine —— C15H22ClNS
    (1S,2R)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-methylcyclohexan-1-amine
    —— (1S,2S)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-methylcyclohexan-1-amine —— C15H22ClNS
    (1S,2S)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-methylcyclohexan-1-amine
    —— (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetic acid —— C12H13N3O2S
    (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetic acid
    —— (2S)-N-[2-(2-fluorophenyl)sulfanylethyl]-5-methylhexan-2-amine —— C15H24FNS
    (2S)-N-[2-(2-fluorophenyl)sulfanylethyl]-5-methylhexan-2-amine
    —— (2R)-N-[2-(2-fluorophenyl)sulfanylethyl]-5-methylhexan-2-amine —— C15H24FNS
    (2R)-N-[2-(2-fluorophenyl)sulfanylethyl]-5-methylhexan-2-amine
    —— (3R,5S)-1-[2-(4-fluorophenyl)sulfanylethyl]-3,5-dimethylpiperazine —— C14H21FN2S
    (3R,5S)-1-[2-(4-fluorophenyl)sulfanylethyl]-3,5-dimethylpiperazine
    —— (1R,3R)-N-[2-(4-bromophenyl)sulfanylethyl]-3-methylcyclohexan-1-amine —— C15H22BrNS
    (1R,3R)-N-[2-(4-bromophenyl)sulfanylethyl]-3-methylcyclohexan-1-amine
    —— (3S,5S)-1-[2-(4-fluorophenyl)sulfanylethyl]-3,5-dimethylpiperazine —— C14H21FN2S
    (3S,5S)-1-[2-(4-fluorophenyl)sulfanylethyl]-3,5-dimethylpiperazine
    —— (3R,5R)-1-[2-(4-fluorophenyl)sulfanylethyl]-3,5-dimethylpiperazine —— C14H21FN2S
    (3R,5R)-1-[2-(4-fluorophenyl)sulfanylethyl]-3,5-dimethylpiperazine
    —— N-cyclohexyl-N-[(4-fluorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C17H21FN4OS
    N-cyclohexyl-N-[(4-fluorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 1-[(3S,5R)-3,5-dimethylpiperazin-1-yl]-2-phenylsulfanylethanone —— C14H20N2OS
    1-[(3S,5R)-3,5-dimethylpiperazin-1-yl]-2-phenylsulfanylethanone
    —— 1-[(3S,5S)-3,5-dimethylpiperazin-1-yl]-2-phenylsulfanylethanone —— C14H20N2OS
    1-[(3S,5S)-3,5-dimethylpiperazin-1-yl]-2-phenylsulfanylethanone
    —— 4-[[4-Cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile —— C16H17N5OS2
    4-[[4-Cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile
    —— 2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C15H20N4OS
    2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C17H18N4O2S
    2-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— (2R)-1-chloro-2-methyl-3-methylsulfonylpropane —— C5H11ClO2S
    (2R)-1-chloro-2-methyl-3-methylsulfonylpropane
    —— (2S)-2-phenylsulfanyl-N-[3-[[(2R)-2-phenylsulfanylpropanoyl]sulfamoyl]propyl]propanamide —— C21H26N2O4S3
    (2S)-2-phenylsulfanyl-N-[3-[[(2R)-2-phenylsulfanylpropanoyl]sulfamoyl]propyl]propanamide
    —— (2R)-2-phenylsulfanyl-N-[3-[[(2R)-2-phenylsulfanylpropanoyl]sulfamoyl]propyl]propanamide —— C21H26N2O4S3
    (2R)-2-phenylsulfanyl-N-[3-[[(2R)-2-phenylsulfanylpropanoyl]sulfamoyl]propyl]propanamide
    —— (2S)-2-phenylsulfanyl-N-[3-[[(2S)-2-phenylsulfanylpropanoyl]sulfamoyl]propyl]propanamide —— C21H26N2O4S3
    (2S)-2-phenylsulfanyl-N-[3-[[(2S)-2-phenylsulfanylpropanoyl]sulfamoyl]propyl]propanamide
    —— (2R)-2-phenylsulfanyl-N-[3-[[(2S)-2-phenylsulfanylpropanoyl]sulfamoyl]propyl]propanamide —— C21H26N2O4S3
    (2R)-2-phenylsulfanyl-N-[3-[[(2S)-2-phenylsulfanylpropanoyl]sulfamoyl]propyl]propanamide
    —— dimethyl-[2-[(2-phenyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl)sulfanyl]ethyl]azanium —— C17H22N3S+
    dimethyl-[2-[(2-phenyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl)sulfanyl]ethyl]azanium
    —— N-[[4-(dimethylamino)phenyl]methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[[(2S)-oxolan-2-yl]methyl]propanamide —— C24H34N4O2S
    N-[[4-(dimethylamino)phenyl]methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[[(2S)-oxolan-2-yl]methyl]propanamide
    —— (2Z,5S)-2-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylidenehydrazinylidene]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazolidin-4-one —— C18H19F2N3OS2
    (2Z,5S)-2-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylidenehydrazinylidene]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazolidin-4-one
    —— (3S)-1-methyl-3-(3-methylphenyl)sulfanylpyrrolidin-2-one —— C12H15NOS
    (3S)-1-methyl-3-(3-methylphenyl)sulfanylpyrrolidin-2-one
    —— (2R)-N-cyclopropyl-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H14FN3OS3
    (2R)-N-cyclopropyl-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 3-[(5-chloro-1,3-dimethylpyrazol-4-yl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C13H18ClN5O2S
    3-[(5-chloro-1,3-dimethylpyrazol-4-yl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one