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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C14H13N5OS2
    5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— 1-[1-(2-Methoxyethyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H22N4O2S2
    1-[1-(2-Methoxyethyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C9H11N5OS2
    5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— N-(2-cyanoethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C10H13N5OS2
    N-(2-cyanoethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(4-chlorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H17ClN4OS2
    N-[2-(4-chlorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H22N4OS2
    N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(4-fluorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H17FN4OS2
    N-[2-(4-fluorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(4-fluorophenyl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H15FN4OS2
    N-[(4-fluorophenyl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C20H21FN4OS2
    1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H16F2N4OS2
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C9H11F3N4OS2
    2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— 1-(1-Ethyl-2,5-dimethylpyrrol-3-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C15H20N4OS2
    1-(1-Ethyl-2,5-dimethylpyrrol-3-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H22N4OS2
    1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 5-[(4-methylphenyl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C13H15N3S2
    5-[(4-methylphenyl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H22N4OS2
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N,N-dimethyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C9H14N4OS2
    N,N-dimethyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 5-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C14H12ClN5OS2
    5-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— N-[[(3S)-3-(cyclopentanecarbonylcarbamothioylamino)pentyl]carbamothioyl]cyclopentanecarboxamide —— C19H32N4O2S2
    N-[[(3S)-3-(cyclopentanecarbonylcarbamothioylamino)pentyl]carbamothioyl]cyclopentanecarboxamide
    —— 5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C12H11BrFN3S2
    5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— 5-[(1R)-1-phenylethyl]sulfanyl-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C13H15N3S2
    5-[(1R)-1-phenylethyl]sulfanyl-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— 5-[(1S)-1-phenylethyl]sulfanyl-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C13H15N3S2
    5-[(1S)-1-phenylethyl]sulfanyl-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— 2-(1-Oxidopyridin-1-ium-2-yl)sulfanyl-1-(1,2,5-trimethylpyrrol-3-yl)ethanone —— C14H16N2O2S
    2-(1-Oxidopyridin-1-ium-2-yl)sulfanyl-1-(1,2,5-trimethylpyrrol-3-yl)ethanone
    —— N-[(2S)-butan-2-yl]-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C15H22N2O4S2
    N-[(2S)-butan-2-yl]-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone —— C17H17N3O3S
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C15H15ClN2O2S
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide —— C16H22N2O2S
    (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide
    —— N-cyclohexyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C17H24N2O4S2
    N-cyclohexyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C15H15ClN2O2S
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide —— C16H22N2O2S
    (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C21H20N2O2S2
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C13H15N3O2S
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 1-Oxido-2-[[3-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]phenyl]methylsulfanyl]pyridin-1-ium —— C18H16N2O2S2
    1-Oxido-2-[[3-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]phenyl]methylsulfanyl]pyridin-1-ium
    —— ethyl 2,4-dimethyl-5-[(2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanoyl]-1H-pyrrole-3-carboxylate —— C17H20N2O4S
    ethyl 2,4-dimethyl-5-[(2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanoyl]-1H-pyrrole-3-carboxylate
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C19H26N2O2S
    N-[(1S)-1-(1-adamantyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— (2R)-N-(cyclohexen-1-ylmethyl)-2-ethylsulfonylpropanamide —— C12H21NO3S
    (2R)-N-(cyclohexen-1-ylmethyl)-2-ethylsulfonylpropanamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C19H26N2O2S
    N-[(1R)-1-(1-adamantyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[(2R)-butan-2-yl]-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C15H22N2O4S2
    N-[(2R)-butan-2-yl]-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C12H13N3O4S2
    N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N,N-dibenzyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C21H20N2O2S
    N,N-dibenzyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— (2S)-N-cyclopentyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide —— C13H18N2O2S
    (2S)-N-cyclopentyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C15H15ClN2O2S
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone —— C21H19N3O3S
    1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone
    —— 1-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone —— C20H20N2O2S
    1-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone
    —— (2R)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C18H22N2O2S
    (2R)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— (2R)-N-benzyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide —— C15H16N2O2S
    (2R)-N-benzyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide
    —— N-cyclohexyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C17H24N2O4S2
    N-cyclohexyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— (2S)-N-benzyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide —— C15H16N2O2S
    (2S)-N-benzyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropanamide
    —— (5R)-3-methyl-N-[2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-4,5-dihydro-1,2-oxazole-5-carboxamide —— C10H15N5O2S
    (5R)-3-methyl-N-[2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-4,5-dihydro-1,2-oxazole-5-carboxamide
    —— (5S)-3-methyl-N-[2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-4,5-dihydro-1,2-oxazole-5-carboxamide —— C10H15N5O2S
    (5S)-3-methyl-N-[2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-4,5-dihydro-1,2-oxazole-5-carboxamide
    —— (2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C18H22N2O2S
    (2S)-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide