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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-N-(cyclododecylideneamino)-2-phenylsulfanylpropanamide —— C21H32N2OS
    (2S)-N-(cyclododecylideneamino)-2-phenylsulfanylpropanamide
    —— (4S)-3-propyl-4-(2-propylsulfanylpyrimidin-5-yl)-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridin-6-one —— C16H21N5OS
    (4S)-3-propyl-4-(2-propylsulfanylpyrimidin-5-yl)-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridin-6-one
    —— (4R)-3-propyl-4-(2-propylsulfanylpyrimidin-5-yl)-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridin-6-one —— C16H21N5OS
    (4R)-3-propyl-4-(2-propylsulfanylpyrimidin-5-yl)-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridin-6-one
    —— (2R)-N-(cyclododecylideneamino)-2-phenylsulfanylpropanamide —— C21H32N2OS
    (2R)-N-(cyclododecylideneamino)-2-phenylsulfanylpropanamide
    —— 2-propylsulfanyl-5-[[(3S)-3-(1H-pyrazol-5-yl)piperidin-1-yl]methyl]pyrimidine —— C16H23N5S
    2-propylsulfanyl-5-[[(3S)-3-(1H-pyrazol-5-yl)piperidin-1-yl]methyl]pyrimidine
    —— 2-propylsulfanyl-5-[[(3R)-3-(1H-pyrazol-5-yl)piperidin-1-yl]methyl]pyrimidine —— C16H23N5S
    2-propylsulfanyl-5-[[(3R)-3-(1H-pyrazol-5-yl)piperidin-1-yl]methyl]pyrimidine
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2R)-2-phenylcyclopropyl]acetamide —— C21H22N4OS
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2R)-2-phenylcyclopropyl]acetamide
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2S)-2-phenylcyclopropyl]acetamide —— C21H22N4OS
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2S)-2-phenylcyclopropyl]acetamide
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2R)-2-phenylcyclopropyl]acetamide —— C21H22N4OS
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2R)-2-phenylcyclopropyl]acetamide
    —— 5-Methyl-2-[(2-oxopropyl)sulfanyl]-6-(thiophen-2-yl)pyridine-3-carbonitrile —— C14H12N2OS2
    5-Methyl-2-[(2-oxopropyl)sulfanyl]-6-(thiophen-2-yl)pyridine-3-carbonitrile
    —— (2R)-1-[2-(2-methylpropyl)-5,7-dihydropyrrolo[3,4-d]pyrimidin-6-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C18H22N4OS
    (2R)-1-[2-(2-methylpropyl)-5,7-dihydropyrrolo[3,4-d]pyrimidin-6-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— (4S)-6-methyl-N-[2-(1-methyltetrazol-5-yl)sulfanylethyl]-2-oxo-4-pyridin-3-yl-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C15H18N8O2S
    (4S)-6-methyl-N-[2-(1-methyltetrazol-5-yl)sulfanylethyl]-2-oxo-4-pyridin-3-yl-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— Ethyl 4-[1,4-dimethyl-5-[(3-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylbutanoate —— C20H26N2O3S
    Ethyl 4-[1,4-dimethyl-5-[(3-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylbutanoate
    —— (4R)-6-methyl-N-[2-(1-methyltetrazol-5-yl)sulfanylethyl]-2-oxo-4-pyridin-3-yl-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C15H18N8O2S
    (4R)-6-methyl-N-[2-(1-methyltetrazol-5-yl)sulfanylethyl]-2-oxo-4-pyridin-3-yl-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— (2S)-1-[2-(2-methylpropyl)-5,7-dihydropyrrolo[3,4-d]pyrimidin-6-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C18H22N4OS
    (2S)-1-[2-(2-methylpropyl)-5,7-dihydropyrrolo[3,4-d]pyrimidin-6-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— (2R)-N-[(3,5-dimethyl-1,2-oxazol-4-yl)methyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-methylpropanamide —— C16H22N4O2S
    (2R)-N-[(3,5-dimethyl-1,2-oxazol-4-yl)methyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-methylpropanamide
    —— (2S)-N-[(3,5-dimethyl-1,2-oxazol-4-yl)methyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-methylpropanamide —— C16H22N4O2S
    (2S)-N-[(3,5-dimethyl-1,2-oxazol-4-yl)methyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-methylpropanamide
    —— 2-[[5-cyclohexyl-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C18H23N3O2S
    2-[[5-cyclohexyl-4-[(1S)-1-phenylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]butanoic acid —— C7H11N3O2S
    (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]butanoic acid
    —— (5E)-5-{[5-(1H-benzimidazol-2-ylthio)-2-furyl]methylene}-3-isopropyl-1,3-thiazolidine-2,4-dione —— C18H15N3O3S2
    (5E)-5-{[5-(1H-benzimidazol-2-ylthio)-2-furyl]methylene}-3-isopropyl-1,3-thiazolidine-2,4-dione
    —— (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]butanoate —— C7H10N3O2S-
    (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]butanoate
    —— (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]butanoic acid —— C7H11N3O2S
    (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]butanoic acid
    —— 4-(4-Methyl-4H-[1,2,4]triazol-3-ylsulfanyl)-but-2-yn-1-ol —— C7H9N3OS
    4-(4-Methyl-4H-[1,2,4]triazol-3-ylsulfanyl)-but-2-yn-1-ol
    —— (1R,2R,3S,5R,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane —— C16H28OS
    (1R,2R,3S,5R,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane
    —— (1R,2S,3S,5R,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane —— C16H28OS
    (1R,2S,3S,5R,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane
    —— 4-{[5-(3-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}but-2-yn-1-ol —— C12H9BrN2O2S
    4-{[5-(3-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}but-2-yn-1-ol
    —— (2E,5Z)-3-(2-ethoxyethyl)-5-[4-(methylsulfanyl)benzylidene]-2-(phenylimino)-1,3-thiazolidin-4-one —— C21H22N2O2S2
    (2E,5Z)-3-(2-ethoxyethyl)-5-[4-(methylsulfanyl)benzylidene]-2-(phenylimino)-1,3-thiazolidin-4-one
    —— (3S)-3-amino-1-[[5-(1H-1,2,4-triazol-5-ylsulfanyl)furan-2-yl]methyl]pyrrolidine-3-carboxylic acid —— C12H15N5O3S
    (3S)-3-amino-1-[[5-(1H-1,2,4-triazol-5-ylsulfanyl)furan-2-yl]methyl]pyrrolidine-3-carboxylic acid
    —— (3R)-3-amino-1-[[5-(1H-1,2,4-triazol-5-ylsulfanyl)furan-2-yl]methyl]pyrrolidine-3-carboxylic acid —— C12H15N5O3S
    (3R)-3-amino-1-[[5-(1H-1,2,4-triazol-5-ylsulfanyl)furan-2-yl]methyl]pyrrolidine-3-carboxylic acid
    —— 1-[(1R)-1-isothiocyanatoethyl]adamantane —— C13H19NS
    1-[(1R)-1-isothiocyanatoethyl]adamantane
    —— 1-[(3S)-3-phenyl-3,4-dihydropyrazol-2-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C19H16N4OS3
    1-[(3S)-3-phenyl-3,4-dihydropyrazol-2-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— 1-[(1S)-1-isothiocyanatoethyl]adamantane —— C13H19NS
    1-[(1S)-1-isothiocyanatoethyl]adamantane
    —— (3S)-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]piperidin-3-amine —— C9H17N5S
    (3S)-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]piperidin-3-amine
    —— (2S)-N-[(4-tert-butylcyclohexylidene)amino]-2-(4-methylphenyl)sulfanylpropanamide —— C20H30N2OS
    (2S)-N-[(4-tert-butylcyclohexylidene)amino]-2-(4-methylphenyl)sulfanylpropanamide
    —— (3R)-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]piperidin-3-amine —— C9H17N5S
    (3R)-N-[2-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]piperidin-3-amine
    —— (4S)-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine —— C13H14N6OS
    (4S)-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine
    —— (4R)-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine —— C13H14N6OS
    (4R)-4-[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]-4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine
    —— (5R)-2-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-2,9-diazaspiro[4.5]decane —— C16H23N5OS
    (5R)-2-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-2,9-diazaspiro[4.5]decane
    —— (5S)-2-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-2,9-diazaspiro[4.5]decane —— C16H23N5OS
    (5S)-2-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-2,9-diazaspiro[4.5]decane
    —— 2-[[4-methyl-5-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C18H24N4O2S
    2-[[4-methyl-5-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[3-Cyano-6-(2-methylpropyl)pyridin-2-yl]sulfanyl-2-methylpropanoate —— C14H17N2O2S-
    2-[3-Cyano-6-(2-methylpropyl)pyridin-2-yl]sulfanyl-2-methylpropanoate
    —— (2R)-N-[2-[(2-chloro-6-fluorophenyl)methylsulfanyl]ethyl]-2-(4-methylphenyl)sulfanylpropanamide —— C19H21ClFNOS2
    (2R)-N-[2-[(2-chloro-6-fluorophenyl)methylsulfanyl]ethyl]-2-(4-methylphenyl)sulfanylpropanamide
    —— 2-[(5E)-5-[[4-(4-chlorophenyl)sulfanylphenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetate —— C18H11ClNO4S2-
    2-[(5E)-5-[[4-(4-chlorophenyl)sulfanylphenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetate
    —— (2S)-N-[2-[(2-chloro-6-fluorophenyl)methylsulfanyl]ethyl]-2-(4-methylphenyl)sulfanylpropanamide —— C19H21ClFNOS2
    (2S)-N-[2-[(2-chloro-6-fluorophenyl)methylsulfanyl]ethyl]-2-(4-methylphenyl)sulfanylpropanamide
    —— [(5E)-5-{4-[(4-chlorophenyl)sulfanyl]benzylidene}-2,4-dioxo-1,3-thiazolidin-3-yl]acetic acid —— C18H12ClNO4S2
    [(5E)-5-{4-[(4-chlorophenyl)sulfanyl]benzylidene}-2,4-dioxo-1,3-thiazolidin-3-yl]acetic acid
    —— (2R)-N-(2-tert-butylsulfanylethyl)-2-(4-methylphenyl)sulfanylpropanamide —— C16H25NOS2
    (2R)-N-(2-tert-butylsulfanylethyl)-2-(4-methylphenyl)sulfanylpropanamide
    —— ethyl (2S)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-phenylacetate —— C16H18N2O2S
    ethyl (2S)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-phenylacetate
    —— (2S)-N-(2-tert-butylsulfanylethyl)-2-(4-methylphenyl)sulfanylpropanamide —— C16H25NOS2
    (2S)-N-(2-tert-butylsulfanylethyl)-2-(4-methylphenyl)sulfanylpropanamide
    —— ethyl (2R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-phenylacetate —— C16H18N2O2S
    ethyl (2R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-phenylacetate
    —— (2R)-2-tert-butyl-2,3-dihydropyrido[1,2-b][1,4,2]oxathiazin-5-ium —— C11H16NOS+
    (2R)-2-tert-butyl-2,3-dihydropyrido[1,2-b][1,4,2]oxathiazin-5-ium