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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-3-methyl-1-morpholin-4-yl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-1-one —— C14H20N2O3S
    (2R)-3-methyl-1-morpholin-4-yl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-1-one
    —— (2S)-N-cyclohexyl-3-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide —— C17H24N4OS2
    (2S)-N-cyclohexyl-3-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide
    —— (2R)-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclopentyl-3-methylbutanamide —— C16H27N3OS3
    (2R)-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclopentyl-3-methylbutanamide
    —— (2S)-N-cyclopentyl-3-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide —— C16H22N4OS2
    (2S)-N-cyclopentyl-3-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide —— C18H22ClN3O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(cyclohexen-1-yl)-N-cyclopropylacetamide —— C19H20ClN3O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(cyclohexen-1-yl)-N-cyclopropylacetamide
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C19H17ClFN3O2S
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile —— C18H14ClN3OS
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— 2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide —— C19H26FN5OS
    2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-enyl-N-(thiophen-2-ylmethyl)acetamide —— C18H16ClN3O2S2
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-enyl-N-(thiophen-2-ylmethyl)acetamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(cyclohexen-1-yl)-N-ethylacetamide —— C18H20ClN3O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(cyclohexen-1-yl)-N-ethylacetamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide —— C21H22ClN3O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide —— C21H22ClN3O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide
    —— (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C19H17ClFN3O2S
    (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[[2-(dimethylamino)pyridin-4-yl]methyl]propanamide —— C17H20ClN3OS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[[2-(dimethylamino)pyridin-4-yl]methyl]propanamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[[2-(dimethylamino)pyridin-4-yl]methyl]propanamide —— C17H20ClN3OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[[2-(dimethylamino)pyridin-4-yl]methyl]propanamide
    —— (2S)-3-methyl-1-morpholin-4-yl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-1-one —— C14H20N2O3S
    (2S)-3-methyl-1-morpholin-4-yl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-1-one
    —— 4-chloro-2-methyl-5-[[5-(thiophen-2-ylmethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]pyridazin-3-one —— C12H10ClN5OS2
    4-chloro-2-methyl-5-[[5-(thiophen-2-ylmethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]pyridazin-3-one
    —— 3-ethyl-5-[(1R)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole —— C12H13N5OS2
    3-ethyl-5-[(1R)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole
    —— N-(furan-2-ylmethyl)-4-phenylsulfanyl-N-(pyridin-3-ylmethyl)butanamide —— C21H22N2O2S
    N-(furan-2-ylmethyl)-4-phenylsulfanyl-N-(pyridin-3-ylmethyl)butanamide
    —— 2-(3,4-dimethylphenyl)-5-[(2-propyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole —— C17H19N3OS2
    2-(3,4-dimethylphenyl)-5-[(2-propyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 5-[[(2R)-oxolan-2-yl]methyl]-3-propan-2-ylsulfanyl-1H-1,2,4-triazole —— C10H17N3OS
    5-[[(2R)-oxolan-2-yl]methyl]-3-propan-2-ylsulfanyl-1H-1,2,4-triazole
    —— 3-methylsulfanyl-5-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazole —— C8H13N3OS
    3-methylsulfanyl-5-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazole
    —— 3-methylsulfanyl-5-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazole —— C8H13N3OS
    3-methylsulfanyl-5-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazole
    —— N,N-dimethyl-2-[[5-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanamine —— C11H20N4OS
    N,N-dimethyl-2-[[5-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanamine
    —— 4-[2-[[5-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]morpholine —— C13H22N4O2S
    4-[2-[[5-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]morpholine
    —— 5-[[(2S)-oxolan-2-yl]methyl]-3-propan-2-ylsulfanyl-1H-1,2,4-triazole —— C10H17N3OS
    5-[[(2S)-oxolan-2-yl]methyl]-3-propan-2-ylsulfanyl-1H-1,2,4-triazole
    —— 4-[2-[[5-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]morpholine —— C13H22N4O2S
    4-[2-[[5-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethyl]morpholine
    —— 2-(2-Methylfuran-3-yl)-5-[(3-thiophen-3-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole —— C14H10N4O3S2
    2-(2-Methylfuran-3-yl)-5-[(3-thiophen-3-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C16H21N3O5S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-(5-cyano-2,6-dimethylpyrimidin-4-yl)sulfanyl-N-[(2-fluorophenyl)methyl]propanamide —— C17H17FN4OS
    (2S)-2-(5-cyano-2,6-dimethylpyrimidin-4-yl)sulfanyl-N-[(2-fluorophenyl)methyl]propanamide
    —— 7-Methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C14H11N5O3S2
    7-Methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— (2R)-2-(5-cyano-2,6-dimethylpyrimidin-4-yl)sulfanyl-N-[(2-fluorophenyl)methyl]propanamide —— C17H17FN4OS
    (2R)-2-(5-cyano-2,6-dimethylpyrimidin-4-yl)sulfanyl-N-[(2-fluorophenyl)methyl]propanamide
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C15H19N3O5S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C15H19N3O5S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C15H15N3O3S2
    (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— (2S)-N-benzyl-N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C21H25N3O3S
    (2S)-N-benzyl-N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C15H19N3O5S2
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cycloheptylacetamide —— C23H35N5OS
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cycloheptylacetamide
    —— (2R)-1-(azepan-1-yl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C16H21N3O3S
    (2R)-1-(azepan-1-yl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C18H19N3O3S
    (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— [(1R)-1-[4-benzyl-5-[2-(cycloheptylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H36N5OS+
    [(1R)-1-[4-benzyl-5-[2-(cycloheptylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (2R)-N-cycloheptyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C17H23N3O3S
    (2R)-N-cycloheptyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— [(1S)-1-[4-benzyl-5-[2-(cycloheptylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H36N5OS+
    [(1S)-1-[4-benzyl-5-[2-(cycloheptylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide —— C14H19N3O3S
    (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide
    —— (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]propanamide —— C13H20N4OS2
    (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]propanamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H17N3O5S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide —— C13H15N3O3S
    (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— (2R)-N-[(2-chlorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C17H16ClN3O3S
    (2R)-N-[(2-chlorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-[(2-chlorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C17H16ClN3O3S
    (2S)-N-[(2-chlorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide