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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-2-methylsulfonylpropanamide —— C22H28FNO3S2
    (2R)-N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-2-methylsulfonylpropanamide
    —— (2R)-N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-2-methylsulfonylpropanamide —— C22H28FNO3S2
    (2R)-N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-2-methylsulfonylpropanamide
    —— N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1-oxidopyridin-1-ium-3-carboxamide —— C24H25FN2O2S
    N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1-oxidopyridin-1-ium-3-carboxamide
    —— N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1-oxidopyridin-1-ium-3-carboxamide —— C24H25FN2O2S
    N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1-oxidopyridin-1-ium-3-carboxamide
    —— N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N,1-dimethyl-6-oxopyridazine-3-carboxamide —— C24H26FN3O2S
    N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N,1-dimethyl-6-oxopyridazine-3-carboxamide
    —— N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N,1-dimethyl-6-oxopyridazine-3-carboxamide —— C24H26FN3O2S
    N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N,1-dimethyl-6-oxopyridazine-3-carboxamide
    —— (2S)-N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-2-methylsulfonylpropanamide —— C22H28FNO3S2
    (2S)-N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-2-methylsulfonylpropanamide
    —— (2S)-N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-2-methylsulfonylpropanamide —— C22H28FNO3S2
    (2S)-N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-2-methylsulfonylpropanamide
    —— (2R)-2-[(E)-(1-amino-3-ethylsulfonylpropylidene)amino]oxy-N-cyclohexyl-N-methylpropanamide —— C15H29N3O4S
    (2R)-2-[(E)-(1-amino-3-ethylsulfonylpropylidene)amino]oxy-N-cyclohexyl-N-methylpropanamide
    —— (2S)-2-[(E)-(1-amino-3-ethylsulfonylpropylidene)amino]oxy-N-cyclohexyl-N-methylpropanamide —— C15H29N3O4S
    (2S)-2-[(E)-(1-amino-3-ethylsulfonylpropylidene)amino]oxy-N-cyclohexyl-N-methylpropanamide
    —— 2-(4-methylphenyl)sulfanyl-N-[(2S)-4-morpholin-4-ylbutan-2-yl]acetamide —— C17H26N2O2S
    2-(4-methylphenyl)sulfanyl-N-[(2S)-4-morpholin-4-ylbutan-2-yl]acetamide
    —— 2-(4-methylphenyl)sulfanyl-N-[(2R)-4-morpholin-4-ylbutan-2-yl]acetamide —— C17H26N2O2S
    2-(4-methylphenyl)sulfanyl-N-[(2R)-4-morpholin-4-ylbutan-2-yl]acetamide
    —— 1-ethyl-1-[(2R)-1-ethylsulfonylpropan-2-yl]-3-propan-2-ylurea —— C11H24N2O3S
    1-ethyl-1-[(2R)-1-ethylsulfonylpropan-2-yl]-3-propan-2-ylurea
    —— 1-ethyl-1-[(2S)-1-ethylsulfonylpropan-2-yl]-3-propan-2-ylurea —— C11H24N2O3S
    1-ethyl-1-[(2S)-1-ethylsulfonylpropan-2-yl]-3-propan-2-ylurea
    —— 3-cyclopropyl-1-ethyl-1-[(2R)-1-methylsulfonylpropan-2-yl]urea —— C10H20N2O3S
    3-cyclopropyl-1-ethyl-1-[(2R)-1-methylsulfonylpropan-2-yl]urea
    —— 3-cyclopropyl-1-ethyl-1-[(2S)-1-methylsulfonylpropan-2-yl]urea —— C10H20N2O3S
    3-cyclopropyl-1-ethyl-1-[(2S)-1-methylsulfonylpropan-2-yl]urea
    —— (2R)-N-(3-chloro-4-phenylsulfanylphenyl)-2-(2-ethoxyethoxy)propanamide —— C19H22ClNO3S
    (2R)-N-(3-chloro-4-phenylsulfanylphenyl)-2-(2-ethoxyethoxy)propanamide
    —— (2S)-N-(3-chloro-4-phenylsulfanylphenyl)-2-(2-ethoxyethoxy)propanamide —— C19H22ClNO3S
    (2S)-N-(3-chloro-4-phenylsulfanylphenyl)-2-(2-ethoxyethoxy)propanamide
    —— (2R)-2-(3,4-dimethylphenyl)sulfanyl-N,N-dimethylpropanamide —— C13H19NOS
    (2R)-2-(3,4-dimethylphenyl)sulfanyl-N,N-dimethylpropanamide
    —— 2-(4,5-Dimethyl-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanylacetic acid —— C12H17N3O2S
    2-(4,5-Dimethyl-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanylacetic acid
    —— [(2R)-1-pyridin-2-ylhexan-2-yl] (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C17H24N4O2S
    [(2R)-1-pyridin-2-ylhexan-2-yl] (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— [(2S)-1-pyridin-2-ylhexan-2-yl] (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C17H24N4O2S
    [(2S)-1-pyridin-2-ylhexan-2-yl] (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— 2-(4,5-Dimethyl-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanylacetate —— C12H16N3O2S-
    2-(4,5-Dimethyl-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanylacetate
    —— [(2S)-1-pyridin-2-ylhexan-2-yl] (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C17H24N4O2S
    [(2S)-1-pyridin-2-ylhexan-2-yl] (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— [(2R)-1-pyridin-2-ylhexan-2-yl] (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C17H24N4O2S
    [(2R)-1-pyridin-2-ylhexan-2-yl] (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— 1-Morpholin-4-yl-3-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C20H30N4OS+2
    1-Morpholin-4-yl-3-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 3-{[2-(Dimethylamino)ethyl]sulfanyl}-1-(morpholin-4-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C18H26N4OS
    3-{[2-(Dimethylamino)ethyl]sulfanyl}-1-(morpholin-4-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— 6-ethylsulfanyl-N-[(3S)-1-pyrimidin-2-ylpiperidin-3-yl]pyrazin-2-amine —— C15H20N6S
    6-ethylsulfanyl-N-[(3S)-1-pyrimidin-2-ylpiperidin-3-yl]pyrazin-2-amine
    —— 6-ethylsulfanyl-N-[(S)-(1-methylimidazol-2-yl)-phenylmethyl]pyrazin-2-amine —— C17H19N5S
    6-ethylsulfanyl-N-[(S)-(1-methylimidazol-2-yl)-phenylmethyl]pyrazin-2-amine
    —— 6-(4-chlorophenyl)-3-(2-methylfuran-3-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C15H11ClN4OS
    6-(4-chlorophenyl)-3-(2-methylfuran-3-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— Methyl [(5-cyano-6-methyl-2-phenylpyrimidin-4-yl)sulfanyl]acetate —— C15H13N3O2S
    Methyl [(5-cyano-6-methyl-2-phenylpyrimidin-4-yl)sulfanyl]acetate
    —— 3-{[2-(Morpholin-4-yl)ethyl]sulfanyl}-1-(piperidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C21H30N4OS
    3-{[2-(Morpholin-4-yl)ethyl]sulfanyl}-1-(piperidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— 3-(2-Morpholin-4-ium-4-ylethylsulfanyl)-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C21H32N4OS+2
    3-(2-Morpholin-4-ium-4-ylethylsulfanyl)-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— methyl (2R)-2-[(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)sulfanyl]butanoate —— C19H25N3O3S
    methyl (2R)-2-[(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)sulfanyl]butanoate
    —— methyl (2R)-2-[(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]butanoate —— C19H26N3O3S+
    methyl (2R)-2-[(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]butanoate
    —— 6-ethylsulfanyl-N-[(R)-(1-methylimidazol-2-yl)-phenylmethyl]pyrazin-2-amine —— C17H19N5S
    6-ethylsulfanyl-N-[(R)-(1-methylimidazol-2-yl)-phenylmethyl]pyrazin-2-amine
    —— 6-ethylsulfanyl-N-[(3R)-1-pyrimidin-2-ylpiperidin-3-yl]pyrazin-2-amine —— C15H20N6S
    6-ethylsulfanyl-N-[(3R)-1-pyrimidin-2-ylpiperidin-3-yl]pyrazin-2-amine
    —— 2-[(4-Cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]ethyl-dimethylazanium —— C19H30N4S+2
    2-[(4-Cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]ethyl-dimethylazanium
    —— 4-Methyl-6-{[2-(morpholin-4-yl)ethyl]sulfanyl}-2-phenylpyrimidine-5-carbonitrile —— C18H20N4OS
    4-Methyl-6-{[2-(morpholin-4-yl)ethyl]sulfanyl}-2-phenylpyrimidine-5-carbonitrile
    —— 1-[[(3R,8aR)-3,4,6,7,8,8a-hexahydro-1H-pyrrolo[2,1-c][1,4]oxazin-3-yl]methyl]-3-[(4-methylsulfanylphenyl)methyl]urea —— C17H25N3O2S
    1-[[(3R,8aR)-3,4,6,7,8,8a-hexahydro-1H-pyrrolo[2,1-c][1,4]oxazin-3-yl]methyl]-3-[(4-methylsulfanylphenyl)methyl]urea
    —— 1-[[(3S,8aR)-3,4,6,7,8,8a-hexahydro-1H-pyrrolo[2,1-c][1,4]oxazin-3-yl]methyl]-3-[(4-methylsulfanylphenyl)methyl]urea —— C17H25N3O2S
    1-[[(3S,8aR)-3,4,6,7,8,8a-hexahydro-1H-pyrrolo[2,1-c][1,4]oxazin-3-yl]methyl]-3-[(4-methylsulfanylphenyl)methyl]urea
    —— 1-Piperidin-1-yl-3-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C21H32N4S+2
    1-Piperidin-1-yl-3-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 1-(4-Methylpiperidin-1-yl)-3-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C22H34N4S+2
    1-(4-Methylpiperidin-1-yl)-3-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 3-{[2-(Dimethylamino)ethyl]sulfanyl}-1-(4-methylpiperidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C20H30N4S
    3-{[2-(Dimethylamino)ethyl]sulfanyl}-1-(4-methylpiperidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— 2-[[4-Cyano-1-(4-methylpiperidin-1-yl)-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl]sulfanyl]ethyl-dimethylazanium —— C20H32N4S+2
    2-[[4-Cyano-1-(4-methylpiperidin-1-yl)-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl]sulfanyl]ethyl-dimethylazanium
    —— 3-{[3-(Dimethylamino)propyl]sulfanyl}-1-(4-methylpiperidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C21H32N4S
    3-{[3-(Dimethylamino)propyl]sulfanyl}-1-(4-methylpiperidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— 3-[[4-Cyano-1-(4-methylpiperidin-1-yl)-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl]sulfanyl]propyl-dimethylazanium —— C21H34N4S+2
    3-[[4-Cyano-1-(4-methylpiperidin-1-yl)-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl]sulfanyl]propyl-dimethylazanium
    —— 6-tert-butyl-4-[(Z)-2-ethylbutylideneamino]-3-methylsulfanyl-1,2,4-triazin-5-one —— C14H24N4OS
    6-tert-butyl-4-[(Z)-2-ethylbutylideneamino]-3-methylsulfanyl-1,2,4-triazin-5-one
    —— 2-[(2S)-3-oxothiomorpholin-2-yl]-N-(2-phenylsulfanylphenyl)acetamide —— C18H18N2O2S2
    2-[(2S)-3-oxothiomorpholin-2-yl]-N-(2-phenylsulfanylphenyl)acetamide
    —— (2S)-N-[[1-(dimethylamino)cycloheptyl]methyl]-2-propan-2-ylsulfonylpropanamide —— C16H32N2O3S
    (2S)-N-[[1-(dimethylamino)cycloheptyl]methyl]-2-propan-2-ylsulfonylpropanamide