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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]ethanone —— C20H20N2O3S2
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]ethanone
    —— N-(1-cyanocyclopentyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C17H20N2O3S
    N-(1-cyanocyclopentyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— [(1S,2S)-2-methyl-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium —— C15H22N3OS+
    [(1S,2S)-2-methyl-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium
    —— N-[2-(4-chlorophenyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C19H20ClNO3S
    N-[2-(4-chlorophenyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C16H22BrNOS
    2-(4-bromo-2-methylphenyl)sulfanyl-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C11H13NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C19H20ClNO3S
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C19H20ClNO3S
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C18H25NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C18H25NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— (2R)-N-(1-adamantyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanamide —— C22H29NO3S
    (2R)-N-(1-adamantyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanamide
    —— 7-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanylmethyl)-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C16H14N2O3S2
    7-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanylmethyl)-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 1-(5-bromothiophen-2-yl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethanone —— C15H13BrO3S2
    1-(5-bromothiophen-2-yl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethanone
    —— 6-amino-5-[2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetyl]-3-methyl-1-propylpyrimidine-2,4-dione —— C19H23N3O5S
    6-amino-5-[2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetyl]-3-methyl-1-propylpyrimidine-2,4-dione
    —— ethyl N-[2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetyl]carbamate —— C14H17NO5S
    ethyl N-[2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetyl]carbamate
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanylmethyl)-5-phenyl-1,3,4-oxadiazole —— C18H16N2O3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanylmethyl)-5-phenyl-1,3,4-oxadiazole
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-methylacetamide —— C12H15NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-methylacetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-pentan-3-ylacetamide —— C16H23NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-pentan-3-ylacetamide
    —— N-(1-cyanocyclohexyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C18H22N2O3S
    N-(1-cyanocyclohexyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)ethanone —— C20H25NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)ethanone
    —— (2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanamide —— C12H15NO3S
    (2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanamide
    —— N-cyclopentyl-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C16H21NO3S
    N-cyclopentyl-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— (1S,2S)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine —— C14H18FN3OS
    (1S,2S)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(1R)-1-phenylethyl]acetamide —— C19H21NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(1R)-1-phenylethyl]acetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C23H31NO3S
    N-[(1S)-1-(1-adamantyl)ethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— methyl 5-[(2S)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C20H23NO5S
    methyl 5-[(2S)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C17H22N2O3S
    N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-(1-ethyl-2,5-dimethylpyrrol-3-yl)ethanone —— C19H23NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-(1-ethyl-2,5-dimethylpyrrol-3-yl)ethanone
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C17H22N2O3S
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(4-fluorophenyl)methyl]acetamide —— C18H18FNO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(4-fluorophenyl)methyl]acetamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]ethanone —— C22H23NO4S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— ethyl 5-[(2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C21H25NO5S
    ethyl 5-[(2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— (2S)-N-(1-adamantyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanamide —— C22H29NO3S
    (2S)-N-(1-adamantyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-propan-2-ylacetamide —— C14H19NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-propan-2-ylacetamide
    —— 1-(1-adamantyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethanone —— C21H26O3S
    1-(1-adamantyl)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethanone
    —— methyl 5-[(2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C20H23NO5S
    methyl 5-[(2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-(2-methylpropyl)acetamide —— C15H21NO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-(2-methylpropyl)acetamide
    —— ethyl 5-[(2S)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C21H25NO5S
    ethyl 5-[(2S)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[2-(4-fluorophenyl)ethyl]acetamide —— C19H20FNO3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[2-(4-fluorophenyl)ethyl]acetamide
    —— (2S)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanamide —— C12H15NO3S
    (2S)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanamide
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C15H19NO5S2
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— ethyl (2S)-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C16H20N2O3S
    ethyl (2S)-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— (2S)-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-phenoxypropanamide —— C19H18ClN3O2S
    (2S)-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-phenoxypropanamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C16H22BrNOS
    2-(4-bromo-2-methylphenyl)sulfanyl-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— ethyl 4-[2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetyl]-2,5-dimethyl-1H-pyrrole-3-carboxylate —— C20H23NO5S
    ethyl 4-[2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetyl]-2,5-dimethyl-1H-pyrrole-3-carboxylate
    —— N-[(1R)-1-(4-fluorophenyl)ethyl]-N-methyl-2-[[5-morpholin-4-yl-4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H23F4N5O2S
    N-[(1R)-1-(4-fluorophenyl)ethyl]-N-methyl-2-[[5-morpholin-4-yl-4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-phenoxypropanamide —— C19H18ClN3O2S
    (2R)-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-phenoxypropanamide
    —— (2R)-2-[[5-morpholin-4-yl-4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide —— C20H26F3N5O2S
    (2R)-2-[[5-morpholin-4-yl-4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide
    —— N-[(1R)-3-methyl-1-phenylbutyl]-2-[[5-morpholin-4-yl-4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C21H28F3N5O2S
    N-[(1R)-3-methyl-1-phenylbutyl]-2-[[5-morpholin-4-yl-4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2S)-2-[[5-morpholin-4-yl-4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide —— C20H26F3N5O2S
    (2S)-2-[[5-morpholin-4-yl-4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide