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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(2-bromophenyl)methanimine —— C17H15BrN4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(2-bromophenyl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(2,3,6-trichlorophenyl)methanimine —— C17H13Cl3N4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(2,3,6-trichlorophenyl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(4-fluorophenyl)methanimine —— C17H15FN4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(4-fluorophenyl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(3-methylphenyl)methanimine —— C18H18N4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(3-methylphenyl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(5-methylfuran-2-yl)methanimine —— C16H16N4OS
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(5-methylfuran-2-yl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(4-bromophenyl)methanimine —— C17H15BrN4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(4-bromophenyl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-pyridin-4-ylmethanimine —— C16H15N5S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-pyridin-4-ylmethanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-[(1S)-cyclohex-3-en-1-yl]methanimine —— C17H20N4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-[(1S)-cyclohex-3-en-1-yl]methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(3-chlorophenyl)methanimine —— C17H15ClN4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(3-chlorophenyl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(4-methylphenyl)methanimine —— C18H18N4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(4-methylphenyl)methanimine
    —— 3-[(Z)-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)iminomethyl]phenol —— C17H16N4OS
    3-[(Z)-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)iminomethyl]phenol
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-[(1R)-cyclohex-3-en-1-yl]methanimine —— C17H20N4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-[(1R)-cyclohex-3-en-1-yl]methanimine
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(4-chlorophenyl)methanimine —— C17H15ClN4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(4-chlorophenyl)methanimine
    —— 3-Cyclohexyl-5-[(3,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C17H24N4S
    3-Cyclohexyl-5-[(3,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 13-Cyclohexyl-17-thia-2,9,11,12,14,15-hexazatetracyclo[8.7.0.03,8.012,16]heptadeca-1,3,5,7,9,13,15-heptaene —— C16H16N6S
    13-Cyclohexyl-17-thia-2,9,11,12,14,15-hexazatetracyclo[8.7.0.03,8.012,16]heptadeca-1,3,5,7,9,13,15-heptaene
    —— (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(2-chloro-6-fluorophenyl)methanimine —— C17H14ClFN4S
    (Z)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(2-chloro-6-fluorophenyl)methanimine
    —— 3-Cyclohexyl-5-[(2,3,6-trichlorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C15H17Cl3N4S
    3-Cyclohexyl-5-[(2,3,6-trichlorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 2-[[4-(4-fluoro-3-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetic acid —— C12H10FNO2S2
    2-[[4-(4-fluoro-3-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetic acid
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carboxylic acid —— C12H9ClN6O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carboxylic acid
    —— 3-methyl-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C11H12N4S2
    3-methyl-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-propyl-1H-1,2,4-triazole-5-thione —— C13H16N4S2
    4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-propyl-1H-1,2,4-triazole-5-thione
    —— 1-(1,4-diazepan-1-yl)-2-(4-fluoro-3-methylphenyl)sulfanylethanone —— C14H19FN2OS
    1-(1,4-diazepan-1-yl)-2-(4-fluoro-3-methylphenyl)sulfanylethanone
    —— 4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C10H10N4S2
    4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-ethyl-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C12H14N4S2
    3-ethyl-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-[3-[(4-Amino-5-butyl-1,2,4-triazol-3-yl)sulfanyl]propylsulfanyl]-5-butyl-1,2,4-triazol-4-amine —— C15H28N8S2
    3-[3-[(4-Amino-5-butyl-1,2,4-triazol-3-yl)sulfanyl]propylsulfanyl]-5-butyl-1,2,4-triazol-4-amine
    —— 1-(1,4-Diazepan-1-yl)-3-(4-fluorophenyl)sulfanylpropan-1-one —— C14H19FN2OS
    1-(1,4-Diazepan-1-yl)-3-(4-fluorophenyl)sulfanylpropan-1-one
    —— 1-(1,4-diazepan-1-yl)-2-(4-fluoro-2-methylphenyl)sulfanylethanone —— C14H19FN2OS
    1-(1,4-diazepan-1-yl)-2-(4-fluoro-2-methylphenyl)sulfanylethanone
    —— 1-ethyl-3-[(E)-(4-methylsulfanylphenyl)methylideneamino]thiourea —— C11H15N3S2
    1-ethyl-3-[(E)-(4-methylsulfanylphenyl)methylideneamino]thiourea
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-methylsulfanylphenyl)methanimine —— C17H16N4S2
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-methylsulfanylphenyl)methanimine
    —— tert-butyl N-[(1S)-1-[5-[(2,5-dimethylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate —— C20H29N3O3S2
    tert-butyl N-[(1S)-1-[5-[(2,5-dimethylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate
    —— tert-butyl N-[(1S)-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate —— C19H27N3O3S2
    tert-butyl N-[(1S)-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate
    —— tert-butyl N-[(1S)-1-[5-[(3-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate —— C19H27N3O3S2
    tert-butyl N-[(1S)-1-[5-[(3-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate
    —— N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H22N4O4S2
    N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-(1,4-Diazepan-1-yl)-3-(3-methylphenyl)sulfanylpropan-1-one —— C15H22N2OS
    1-(1,4-Diazepan-1-yl)-3-(3-methylphenyl)sulfanylpropan-1-one
    —— 1-(1,4-Diazepan-1-yl)-3-(4-methylphenyl)sulfanylpropan-1-one —— C15H22N2OS
    1-(1,4-Diazepan-1-yl)-3-(4-methylphenyl)sulfanylpropan-1-one
    —— N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H22N4O4S2
    N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-(1,4-Diazepan-1-yl)-2-(4-ethylphenyl)sulfanylethanone —— C15H22N2OS
    1-(1,4-Diazepan-1-yl)-2-(4-ethylphenyl)sulfanylethanone
    —— 2-(4-methylphenyl)-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C17H14N4O2S2
    2-(4-methylphenyl)-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H21N3O4S2
    N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— ethyl 2-[2-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C15H15N3O3S3
    ethyl 2-[2-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— (2S)-2-[(5-bromothiophen-2-yl)sulfanylmethyl]pyrrolidine —— C9H12BrNS2
    (2S)-2-[(5-bromothiophen-2-yl)sulfanylmethyl]pyrrolidine
    —— (2R)-2-[(5-bromothiophen-2-yl)sulfanylmethyl]pyrrolidine —— C9H12BrNS2
    (2R)-2-[(5-bromothiophen-2-yl)sulfanylmethyl]pyrrolidine
    —— ethyl 2-[2-[2-[cyclopropyl-[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C16H22N2O5S3
    ethyl 2-[2-[2-[cyclopropyl-[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— 2-pyridin-3-yl-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C15H11N5O2S2
    2-pyridin-3-yl-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H18FN3O4S2
    N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 6-Amino-5-[2-[(4-benzyl-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-methylpyrimidine-2,4-dione —— C19H20N6O3S
    6-Amino-5-[2-[(4-benzyl-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-methylpyrimidine-2,4-dione
    —— 2-pyridin-3-yl-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C15H11N5O2S2
    2-pyridin-3-yl-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C16H18N4O4S2
    N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 3-[[3-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C12H14N8S2
    3-[[3-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H18FN3O4S2
    N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide