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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(4-bromophenyl)sulfanyl-N-[(2R)-1-(dimethylamino)-4-methylpentan-2-yl]propanamide —— C17H27BrN2OS
    3-(4-bromophenyl)sulfanyl-N-[(2R)-1-(dimethylamino)-4-methylpentan-2-yl]propanamide
    —— (2R)-2-(1,3-thiazol-2-ylsulfanyl)-N-(2,2,2-trifluoroethyl)propanamide —— C8H9F3N2OS2
    (2R)-2-(1,3-thiazol-2-ylsulfanyl)-N-(2,2,2-trifluoroethyl)propanamide
    —— 3-(4-bromophenyl)sulfanyl-N-[3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propyl]propanamide —— C18H27BrN2O2S
    3-(4-bromophenyl)sulfanyl-N-[3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propyl]propanamide
    —— (2S)-1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1,3-thiazol-2-ylsulfanyl)propan-1-one —— C19H16ClN3O2S2
    (2S)-1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1,3-thiazol-2-ylsulfanyl)propan-1-one
    —— 3-propan-2-yl-5-[(1R)-1-(1,3-thiazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole —— C10H13N3OS2
    3-propan-2-yl-5-[(1R)-1-(1,3-thiazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole
    —— (2R)-N-benzyl-N-methyl-2-(1,3-thiazol-2-ylsulfanyl)propanamide —— C14H16N2OS2
    (2R)-N-benzyl-N-methyl-2-(1,3-thiazol-2-ylsulfanyl)propanamide
    —— 3-(4-bromophenyl)sulfanyl-N-[(2S)-1-(dimethylamino)-4-methylpentan-2-yl]propanamide —— C17H27BrN2OS
    3-(4-bromophenyl)sulfanyl-N-[(2S)-1-(dimethylamino)-4-methylpentan-2-yl]propanamide
    —— (2R)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1,3-thiazol-2-ylsulfanyl)propan-1-one —— C19H16ClN3O2S2
    (2R)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1,3-thiazol-2-ylsulfanyl)propan-1-one
    —— 1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C14H22N4O2S2
    1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— (2R)-1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one —— C20H19ClN6O2S
    (2R)-1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one
    —— N-[(2S)-heptan-2-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H26N4OS2
    N-[(2S)-heptan-2-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— butyl (2S)-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanoate —— C9H14N2O2S2
    butyl (2S)-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanoate
    —— (2S)-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)propanamide —— C11H15F3N4OS2
    (2S)-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)propanamide
    —— N-[(2R)-heptan-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylacetamide —— C13H23N5OS
    N-[(2R)-heptan-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylacetamide
    —— (2R)-2-(1-prop-2-enyltetrazol-5-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C9H12F3N5OS
    (2R)-2-(1-prop-2-enyltetrazol-5-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— (2R)-N-benzyl-N-methyl-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropanamide —— C15H19N5OS
    (2R)-N-benzyl-N-methyl-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropanamide
    —— (2S)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one —— C20H19ClN6O2S
    (2S)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one
    —— 3-(4-bromophenyl)sulfanyl-N-[3-[(2R,6S)-2,6-dimethylmorpholin-4-yl]propyl]propanamide —— C18H27BrN2O2S
    3-(4-bromophenyl)sulfanyl-N-[3-[(2R,6S)-2,6-dimethylmorpholin-4-yl]propyl]propanamide
    —— (2S)-1-(4-ethylpiperazin-1-yl)-2-(1,3-thiazol-2-ylsulfanyl)propan-1-one —— C12H19N3OS2
    (2S)-1-(4-ethylpiperazin-1-yl)-2-(1,3-thiazol-2-ylsulfanyl)propan-1-one
    —— 1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C19H19N5OS4
    1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— 2-[[(2S)-oxolan-2-yl]methylsulfanyl]-5-pyrrolidin-1-yl-1,3,4-thiadiazole —— C11H17N3OS2
    2-[[(2S)-oxolan-2-yl]methylsulfanyl]-5-pyrrolidin-1-yl-1,3,4-thiadiazole
    —— 1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C14H22N4O2S2
    1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— 3-(4-bromophenyl)sulfanyl-1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-1-yl]propan-1-one —— C17H23BrN2O3S2
    3-(4-bromophenyl)sulfanyl-1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-1-yl]propan-1-one
    —— N-[(2S)-6-methylheptan-2-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C16H28N4OS2
    N-[(2S)-6-methylheptan-2-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanone —— C12H19N5O2S
    1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanone
    —— 5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1-prop-2-enyltetrazole —— C9H14N4OS
    5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1-prop-2-enyltetrazole
    —— 1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanone —— C12H19N5O2S
    1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanone
    —— (2R)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one —— C20H19ClN6O2S
    (2R)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one
    —— (2R)-1-(4-ethylpiperazin-1-yl)-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one —— C13H22N6OS
    (2R)-1-(4-ethylpiperazin-1-yl)-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one
    —— 3-propan-2-yl-5-[(1R)-1-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-1,2,4-oxadiazole —— C13H19N5OS2
    3-propan-2-yl-5-[(1R)-1-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C14H22N4O2S2
    1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— (2S)-1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one —— C20H19ClN6O2S
    (2S)-1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylpropan-1-one
    —— N-[(2S)-6-methylheptan-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylacetamide —— C14H25N5OS
    N-[(2S)-6-methylheptan-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylacetamide
    —— 1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C19H19N5OS4
    1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— 1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanone —— C12H19N5O2S
    1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanone
    —— (2R)-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)propanamide —— C11H15F3N4OS2
    (2R)-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)propanamide
    —— (2S)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1,3-thiazol-2-ylsulfanyl)propan-1-one —— C19H16ClN3O2S2
    (2S)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1,3-thiazol-2-ylsulfanyl)propan-1-one
    —— (2S)-2-(1-prop-2-enyltetrazol-5-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C9H12F3N5OS
    (2S)-2-(1-prop-2-enyltetrazol-5-yl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— N-[(2R)-6-methylheptan-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylacetamide —— C14H25N5OS
    N-[(2R)-6-methylheptan-2-yl]-2-(1-prop-2-enyltetrazol-5-yl)sulfanylacetamide
    —— butyl (2R)-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanoate —— C9H14N2O2S2
    butyl (2R)-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanoate
    —— 3-(4-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-prop-2-enylpropanamide —— C16H20ClNO3S2
    3-(4-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-prop-2-enylpropanamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-prop-2-enylacetamide —— C17H22BrNO3S2
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-prop-2-enylacetamide
    —— 1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C20H19ClN4O3S2
    1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— (2S)-N-cyclopropyl-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C11H17N3O2S2
    (2S)-N-cyclopropyl-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C20H19ClN4O3S2
    1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— N-[(2S)-heptan-2-yl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C14H25N3O2S2
    N-[(2S)-heptan-2-yl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(2R)-heptan-2-yl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C14H25N3O2S2
    N-[(2R)-heptan-2-yl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (3R,5S)-1-[5-(2-bromoprop-2-enylsulfanyl)-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine —— C17H23BrN4OS
    (3R,5S)-1-[5-(2-bromoprop-2-enylsulfanyl)-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine
    —— 3-tert-butyl-5-[(1S)-1-(3-chloro-4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-4-amine —— C14H18ClFN4S
    3-tert-butyl-5-[(1S)-1-(3-chloro-4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— (3R,5R)-1-[5-(2-bromoprop-2-enylsulfanyl)-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine —— C17H23BrN4OS
    (3R,5R)-1-[5-(2-bromoprop-2-enylsulfanyl)-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine