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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-pyrimidin-2-ylsulfanylethanone —— C17H14N4OS3
    1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-pyrimidin-2-ylsulfanylethanone
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H23N5O2S
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C15H20N4O2S
    2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— 1-[2,5-dimethyl-1-[(1R)-1-phenylethyl]pyrrol-3-yl]-2-pyrimidin-2-ylsulfanylethanone —— C20H21N3OS
    1-[2,5-dimethyl-1-[(1R)-1-phenylethyl]pyrrol-3-yl]-2-pyrimidin-2-ylsulfanylethanone
    —— N-[(1S)-1-(4-bromophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C14H14BrN3OS
    N-[(1S)-1-(4-bromophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N'-acetyl-2-pyrimidin-2-ylsulfanylacetohydrazide —— C8H10N4O2S
    N'-acetyl-2-pyrimidin-2-ylsulfanylacetohydrazide
    —— N-[(1R)-1-(4-ethylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C16H19N3OS
    N-[(1R)-1-(4-ethylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(1R)-1-(4-bromophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C14H14BrN3OS
    N-[(1R)-1-(4-bromophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— 1-[2,5-dimethyl-1-[(1S)-1-phenylethyl]pyrrol-3-yl]-2-pyrimidin-2-ylsulfanylethanone —— C20H21N3OS
    1-[2,5-dimethyl-1-[(1S)-1-phenylethyl]pyrrol-3-yl]-2-pyrimidin-2-ylsulfanylethanone
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C18H21N5O2S
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H19ClN4OS
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— methyl 2,4-dimethyl-5-[(2S)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C17H22N4O3S
    methyl 2,4-dimethyl-5-[(2S)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H19ClN4OS
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(4-fluorophenyl)methyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H17FN4OS
    N-[(4-fluorophenyl)methyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C18H24N4O3S2
    1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 6-Amino-3-methyl-5-[2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione —— C16H22N6O3S
    6-Amino-3-methyl-5-[2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione
    —— 1-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C17H19N5OS2
    1-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (2R)-N-(1-adamantyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C19H28N4OS
    (2R)-N-(1-adamantyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 1-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C21H24N4OS
    1-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 2-(4-Chlorophenyl)-4-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazole —— C16H15ClN4S2
    2-(4-Chlorophenyl)-4-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazole
    —— 2-[(5-Methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C8H12N4OS
    2-[(5-Methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-N-cyclopropyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C12H18N4OS
    (2R)-N-cyclopropyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C9H14N4OS
    N-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-(2-Bromophenyl)-5-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C15H14BrN5OS
    2-(2-Bromophenyl)-5-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C20H30N4OS
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— ethyl 2,4-dimethyl-5-[(2S)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C18H24N4O3S
    ethyl 2,4-dimethyl-5-[(2S)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— methyl 2,4-dimethyl-5-[(2R)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C17H22N4O3S
    methyl 2,4-dimethyl-5-[(2R)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— 7-[(5-Methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C13H13N5OS2
    7-[(5-Methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— N-[(4-chlorophenyl)methyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H17ClN4OS
    N-[(4-chlorophenyl)methyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-[(3R)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C22H23N5O2S
    1-[(3R)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (2S)-N-cyclopropyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C12H18N4OS
    (2S)-N-cyclopropyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— ethyl 2,4-dimethyl-5-[(2R)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C18H24N4O3S
    ethyl 2,4-dimethyl-5-[(2R)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— 1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C22H23N5O2S
    1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H18N4O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N'-acetyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetohydrazide —— C10H15N5O2S
    N'-acetyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetohydrazide
    —— (2S)-N-(1-cyanocyclohexyl)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanamide —— C17H24N4O2S
    (2S)-N-(1-cyanocyclohexyl)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanamide
    —— 2-(4-fluorophenyl)sulfanyl-N-(2-methyl-2-morpholin-4-ium-4-ylpropyl)acetamide —— C16H24FN2O2S+
    2-(4-fluorophenyl)sulfanyl-N-(2-methyl-2-morpholin-4-ium-4-ylpropyl)acetamide
    —— (2R)-N-(1-cyanocyclohexyl)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanamide —— C17H24N4O2S
    (2R)-N-(1-cyanocyclohexyl)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanamide
    —— 5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C8H13N3OS2
    5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 5-[[(2R)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C8H13N3OS2
    5-[[(2R)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-(1H-1,2,4-triazol-5-ylsulfanyl)-1-(1,2,5-trimethylpyrrol-3-yl)ethanone —— C11H14N4OS
    2-(1H-1,2,4-triazol-5-ylsulfanyl)-1-(1,2,5-trimethylpyrrol-3-yl)ethanone
    —— 3-[(3aS,7aS)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide —— C21H22ClN3O3S2
    3-[(3aS,7aS)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide
    —— 1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C17H14ClN5O2S
    1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— 1-[(2S)-2-(2-chlorophenyl)sulfanylpropanoyl]-N-ethylazetidine-3-carboxamide —— C15H19ClN2O2S
    1-[(2S)-2-(2-chlorophenyl)sulfanylpropanoyl]-N-ethylazetidine-3-carboxamide
    —— 1-[(2R)-2-(2-chlorophenyl)sulfanylpropanoyl]-N-ethylazetidine-3-carboxamide —— C15H19ClN2O2S
    1-[(2R)-2-(2-chlorophenyl)sulfanylpropanoyl]-N-ethylazetidine-3-carboxamide
    —— 3-[2-(4-Chlorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazol-2-one —— C14H11ClN2O2S2
    3-[2-(4-Chlorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazol-2-one
    —— (2R)-2-[4-[2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetyl]piperazin-1-yl]-2-phenylacetonitrile —— C21H29N7OS
    (2R)-2-[4-[2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetyl]piperazin-1-yl]-2-phenylacetonitrile
    —— (2S)-2-[4-[2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetyl]piperazin-1-yl]-2-phenylacetonitrile —— C21H29N7OS
    (2S)-2-[4-[2-[[5-(dimethylamino)-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetyl]piperazin-1-yl]-2-phenylacetonitrile
    —— N-[(3,4-dimethoxyphenyl)methyl]-2-phenylsulfanylpyridine-3-carboxamide —— C21H20N2O3S
    N-[(3,4-dimethoxyphenyl)methyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— 2-(2-Cyano-phenylsulfanyl)-N-cyclohexyl-benzamide —— C20H20N2OS
    2-(2-Cyano-phenylsulfanyl)-N-cyclohexyl-benzamide