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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(4-methylphenyl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C14H17N3OS2
    N-(4-methylphenyl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(3,4-dimethylphenyl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C15H19N3OS2
    N-(3,4-dimethylphenyl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C18H20N4O2S2
    2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— (2S)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C15H20N4OS2
    (2S)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— N-[2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]ethyl]acetamide —— C11H17N3O2S
    N-[2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]ethyl]acetamide
    —— N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C17H25N5O2S
    N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— (2S)-N,N-dimethyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H18N4OS2
    (2S)-N,N-dimethyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C15H20N4OS2
    (2R)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— N-(2-methylphenyl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C14H17N3OS2
    N-(2-methylphenyl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(4-methylphenyl)-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C20H19N5OS2
    N-(4-methylphenyl)-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— (2R)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C15H20N4OS2
    (2R)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— 2-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-propyl-1H-pyrimidin-6-one —— C16H18N4O3S
    2-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-propyl-1H-pyrimidin-6-one
    —— (2R)-N-ethyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H18N4OS2
    (2R)-N-ethyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-(2,3-dimethylphenyl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C15H19N3OS2
    N-(2,3-dimethylphenyl)-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2S)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C15H20N4OS2
    (2S)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— 5-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine —— C19H16FN5OS2
    5-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— (2R)-N,N-dimethyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H18N4OS2
    (2R)-N,N-dimethyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C15H20N4OS2
    (2S)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— (2S)-N-ethyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H18N4OS2
    (2S)-N-ethyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-(2-methylphenyl)-5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C20H19N5OS2
    N-(2-methylphenyl)-5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— (2R)-3-(4-methylphenyl)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanenitrile —— C17H19N3OS
    (2R)-3-(4-methylphenyl)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanenitrile
    —— 4-[[5-(3-Chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile —— C14H12ClN5OS2
    4-[[5-(3-Chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile
    —— (2S)-3-(4-methylphenyl)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanenitrile —— C17H19N3OS
    (2S)-3-(4-methylphenyl)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanenitrile
    —— N-methyl-N-(4-methylcyclohexyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C14H21N3O2S
    N-methyl-N-(4-methylcyclohexyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanamide —— C18H22FN3O2S
    (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanamide
    —— N-(cyclohexen-1-yl)-N-cyclopropyl-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C18H25N3O2S
    N-(cyclohexen-1-yl)-N-cyclopropyl-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 2,2-dimethyl-N-[[5-[2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]propanamide —— C19H25N3O3S2
    2,2-dimethyl-N-[[5-[2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]propanamide
    —— N-[(1R)-3-methyl-1-phenylbutyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C17H21N3O2S
    N-[(1R)-3-methyl-1-phenylbutyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 3-Amino-6-(2-nitrophenyl)sulfanylthieno[2,3-d]pyrimidin-4-one —— C12H8N4O3S2
    3-Amino-6-(2-nitrophenyl)sulfanylthieno[2,3-d]pyrimidin-4-one
    —— N,N-diethyl-6-(2-nitrophenyl)sulfanylthieno[2,3-d]pyrimidin-4-amine —— C16H16N4O2S2
    N,N-diethyl-6-(2-nitrophenyl)sulfanylthieno[2,3-d]pyrimidin-4-amine
    —— [(Z)-[5-(diethylamino)-4-(2-nitrophenyl)sulfanylfuran-2-yl]methylideneamino]thiourea —— C16H19N5O3S2
    [(Z)-[5-(diethylamino)-4-(2-nitrophenyl)sulfanylfuran-2-yl]methylideneamino]thiourea
    —— 2-pyridin-4-ylsulfanyl-1-[(2S)-2-(5-thiophen-2-yl-1,2-oxazol-3-yl)azepan-1-yl]ethanone —— C20H21N3O2S2
    2-pyridin-4-ylsulfanyl-1-[(2S)-2-(5-thiophen-2-yl-1,2-oxazol-3-yl)azepan-1-yl]ethanone
    —— 2-pyridin-4-ylsulfanyl-1-[(2R)-2-(5-thiophen-2-yl-1,2-oxazol-3-yl)azepan-1-yl]ethanone —— C20H21N3O2S2
    2-pyridin-4-ylsulfanyl-1-[(2R)-2-(5-thiophen-2-yl-1,2-oxazol-3-yl)azepan-1-yl]ethanone
    —— ethyl 5-[2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C15H20N4O3S
    ethyl 5-[2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone —— C20H25N3OS3
    2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone
    —— (2S)-2-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-phenylpropanenitrile —— C22H24N4S2
    (2S)-2-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-phenylpropanenitrile
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]ethanone —— C14H19N5O2S2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]ethanone
    —— (2R)-2-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-phenylpropanenitrile —— C22H24N4S2
    (2R)-2-[[4-cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-phenylpropanenitrile
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]ethanone —— C14H19N5O2S2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R,6S)-2,6-dimethylmorpholin-4-yl]ethanone
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-pyridin-3-ylethylideneamino]acetamide —— C15H14FN3OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-pyridin-3-ylethylideneamino]acetamide
    —— (2S)-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C14H16N4OS2
    (2S)-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide —— C18H17FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide
    —— (2R)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C14H16N4OS2
    (2R)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]ethanone —— C14H19N5O2S2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]ethanone
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-pyridin-4-ylethylideneamino]acetamide —— C15H14FN3OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-pyridin-4-ylethylideneamino]acetamide
    —— N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-3-(4-fluorophenyl)sulfanylpropanamide —— C17H16F2N2OS
    N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-3-(4-fluorophenyl)sulfanylpropanamide
    —— (2R)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C12H12N2O3S
    (2R)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— 3-(4-fluorophenyl)sulfanyl-N-[(Z)-1-pyridin-3-ylethylideneamino]propanamide —— C16H16FN3OS
    3-(4-fluorophenyl)sulfanyl-N-[(Z)-1-pyridin-3-ylethylideneamino]propanamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[(Z)-1-(furan-2-yl)ethylideneamino]propanamide —— C15H15FN2O2S
    3-(4-fluorophenyl)sulfanyl-N-[(Z)-1-(furan-2-yl)ethylideneamino]propanamide
    —— 2-[[4-(3,4-Dimethylphenyl)sulfanylphenyl]sulfonylamino]acetate —— C16H16NO4S2-
    2-[[4-(3,4-Dimethylphenyl)sulfanylphenyl]sulfonylamino]acetate