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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-(4-bromophenyl)sulfanyl-N-methoxy-N-methylpropanamide —— C11H14BrNO2S
    (2R)-2-(4-bromophenyl)sulfanyl-N-methoxy-N-methylpropanamide
    —— N-[4-(4-bromophenyl)sulfanylphenyl]cyclopentanecarboxamide —— C18H18BrNOS
    N-[4-(4-bromophenyl)sulfanylphenyl]cyclopentanecarboxamide
    —— N-[4-(4-bromophenyl)sulfanylphenyl]-2-thiophen-2-ylacetamide —— C18H14BrNOS2
    N-[4-(4-bromophenyl)sulfanylphenyl]-2-thiophen-2-ylacetamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(2-fluorophenyl)acetamide —— C22H20FNOS
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(2-fluorophenyl)acetamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenyl)acetamide —— C23H23NO2S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenyl)acetamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-3-phenylpropanamide —— C23H23NOS
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-3-phenylpropanamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-phenylacetamide —— C22H21NOS
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-phenylacetamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(6-methoxy-1-benzofuran-3-yl)acetamide —— C25H23NO3S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(6-methoxy-1-benzofuran-3-yl)acetamide
    —— 2-(2-chlorophenoxy)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide —— C22H20ClNO2S
    2-(2-chlorophenoxy)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]cyclopentanecarboxamide —— C20H23NOS
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]cyclopentanecarboxamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(2-methoxyphenoxy)acetamide —— C23H23NO3S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(2-methoxyphenoxy)acetamide
    —— 2-(4-chlorophenoxy)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide —— C22H20ClNO2S
    2-(4-chlorophenoxy)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide
    —— 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C17H28N4OS2
    2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— N-[(1R,2R)-2-methylcyclohexyl]-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C13H19F3N4OS
    N-[(1R,2R)-2-methylcyclohexyl]-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-[(3R)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(4-hydroxyphenyl)sulfanylethanone —— C22H20N2O3S
    1-[(3R)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(4-hydroxyphenyl)sulfanylethanone
    —— 1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(4-hydroxyphenyl)sulfanylethanone —— C22H20N2O3S
    1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(4-hydroxyphenyl)sulfanylethanone
    —— (2R)-N,N-dibenzyl-2-(4-hydroxyphenyl)sulfanylpropanamide —— C23H23NO2S
    (2R)-N,N-dibenzyl-2-(4-hydroxyphenyl)sulfanylpropanamide
    —— (2S)-N,N-dibenzyl-2-(4-hydroxyphenyl)sulfanylpropanamide —— C23H23NO2S
    (2S)-N,N-dibenzyl-2-(4-hydroxyphenyl)sulfanylpropanamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(2-fluorophenyl)methyl]acetamide —— C15H13BrFNOS
    2-(4-bromophenyl)sulfanyl-N-[(2-fluorophenyl)methyl]acetamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[(2-fluorophenyl)methyl]acetamide —— C17H18FNOS
    2-(2,4-dimethylphenyl)sulfanyl-N-[(2-fluorophenyl)methyl]acetamide
    —— (2R)-2-(2,4-dichlorophenoxy)-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]propanamide —— C17H13Cl2N3O2S2
    (2R)-2-(2,4-dichlorophenoxy)-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]propanamide
    —— (3R)-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]-3,4-dihydro-2H-chromene-3-carboxamide —— C18H15N3O2S2
    (3R)-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]-3,4-dihydro-2H-chromene-3-carboxamide
    —— (3R)-5-oxo-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]-1-(2,2,2-trifluoroethyl)pyrrolidine-3-carboxamide —— C15H13F3N4O2S2
    (3R)-5-oxo-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]-1-(2,2,2-trifluoroethyl)pyrrolidine-3-carboxamide
    —— (2R)-2-(2-bromo-4-chlorophenoxy)-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]propanamide —— C17H13BrClN3O2S2
    (2R)-2-(2-bromo-4-chlorophenoxy)-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]propanamide
    —— (3S)-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]-3,4-dihydro-2H-chromene-3-carboxamide —— C18H15N3O2S2
    (3S)-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]-3,4-dihydro-2H-chromene-3-carboxamide
    —— N-[(Z)-furan-2-ylmethylideneamino]-3-[(2,4,6-trimethylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C17H19N5OS
    N-[(Z)-furan-2-ylmethylideneamino]-3-[(2,4,6-trimethylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— N-[(Z)-benzylideneamino]-3-[(2,4,6-trimethylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C19H21N5S
    N-[(Z)-benzylideneamino]-3-[(2,4,6-trimethylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— 1-(2,3-Dimethylphenyl)-3-[(2-phenylsulfanylacetyl)amino]thiourea —— C17H19N3OS2
    1-(2,3-Dimethylphenyl)-3-[(2-phenylsulfanylacetyl)amino]thiourea
    —— 5-(Butylsulfanyl)-3-(2-methylphenyl)-6-phenyl-2-thioxo-2,3-dihydro[1,3]thiazolo[4,5-D]pyrimidin-7(6H)-one —— C22H21N3OS3
    5-(Butylsulfanyl)-3-(2-methylphenyl)-6-phenyl-2-thioxo-2,3-dihydro[1,3]thiazolo[4,5-D]pyrimidin-7(6H)-one
    —— N-[4-[(2S)-2-methylpiperidin-1-yl]butyl]-2-phenylsulfanylpyridine-3-carboxamide —— C22H29N3OS
    N-[4-[(2S)-2-methylpiperidin-1-yl]butyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— 2-(5-bromopyridin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylbenzamide —— C17H17BrN2O3S2
    2-(5-bromopyridin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylbenzamide
    —— 2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C19H20N6OS
    2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— N-[4-[(3R)-3-methylpiperidin-1-yl]butyl]-2-phenylsulfanylpyridine-3-carboxamide —— C22H29N3OS
    N-[4-[(3R)-3-methylpiperidin-1-yl]butyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[4-[(3S)-3-methylpiperidin-1-yl]butyl]-2-phenylsulfanylpyridine-3-carboxamide —— C22H29N3OS
    N-[4-[(3S)-3-methylpiperidin-1-yl]butyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— (3R)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-3,4-dihydro-2H-chromene-3-carboxamide —— C20H18N2O2S2
    (3R)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-3,4-dihydro-2H-chromene-3-carboxamide
    —— (3S)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-3,4-dihydro-2H-chromene-3-carboxamide —— C20H18N2O2S2
    (3S)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-3,4-dihydro-2H-chromene-3-carboxamide
    —— 1-(2,3-Dimethylphenyl)-3-[[2-(2-methylphenyl)sulfanylacetyl]amino]thiourea —— C18H21N3OS2
    1-(2,3-Dimethylphenyl)-3-[[2-(2-methylphenyl)sulfanylacetyl]amino]thiourea
    —— (3R)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-1-(thiophene-2-carbonyl)piperidine-3-carboxamide —— C21H21N3O2S3
    (3R)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-1-(thiophene-2-carbonyl)piperidine-3-carboxamide
    —— N-[4-[(2R)-2-methylpiperidin-1-yl]butyl]-2-phenylsulfanylpyridine-3-carboxamide —— C22H29N3OS
    N-[4-[(2R)-2-methylpiperidin-1-yl]butyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— (3S)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-1-(thiophene-2-carbonyl)piperidine-3-carboxamide —— C21H21N3O2S3
    (3S)-N-[4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]-1-(thiophene-2-carbonyl)piperidine-3-carboxamide
    —— 2-(5-bromopyridin-2-yl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylbenzamide —— C17H17BrN2O3S2
    2-(5-bromopyridin-2-yl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylbenzamide
    —— 2-[[5-[(2Z)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C17H18N6O2S
    2-[[5-[(2Z)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— 2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C19H20N6OS
    2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— N-[(S)-cyclopentyl(phenyl)methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C22H29N3OS
    N-[(S)-cyclopentyl(phenyl)methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(R)-cyclopentyl(phenyl)methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C22H29N3OS
    N-[(R)-cyclopentyl(phenyl)methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-(1-adamantylmethyl)-3-(4-chlorophenyl)sulfanylpropanamide —— C20H26ClNOS
    N-(1-adamantylmethyl)-3-(4-chlorophenyl)sulfanylpropanamide
    —— 2-[2-[(4aR,8aS)-2,3,4a,5,6,7,8,8a-octahydrobenzo[b][1,4]oxazine-4-carbonyl]phenyl]sulfanylbenzonitrile —— C22H22N2O2S
    2-[2-[(4aR,8aS)-2,3,4a,5,6,7,8,8a-octahydrobenzo[b][1,4]oxazine-4-carbonyl]phenyl]sulfanylbenzonitrile
    —— 2-[2-[(4aS,8aS)-2,3,4a,5,6,7,8,8a-octahydrobenzo[b][1,4]oxazine-4-carbonyl]phenyl]sulfanylbenzonitrile —— C22H22N2O2S
    2-[2-[(4aS,8aS)-2,3,4a,5,6,7,8,8a-octahydrobenzo[b][1,4]oxazine-4-carbonyl]phenyl]sulfanylbenzonitrile
    —— 2-[2-[(4aS,8aR)-2,3,4a,5,6,7,8,8a-octahydrobenzo[b][1,4]oxazine-4-carbonyl]phenyl]sulfanylbenzonitrile —— C22H22N2O2S
    2-[2-[(4aS,8aR)-2,3,4a,5,6,7,8,8a-octahydrobenzo[b][1,4]oxazine-4-carbonyl]phenyl]sulfanylbenzonitrile
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-phenoxyacetamide —— C20H16ClNO2S
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-phenoxyacetamide