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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)propanamide —— C19H20N4OS2
    (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)propanamide
    —— (2S)-N-(1-cyanocyclohexyl)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C15H23N5OS
    (2S)-N-(1-cyanocyclohexyl)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C15H20N4OS
    (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C14H17FN4OS
    (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— (2S)-N-[(2-chlorophenyl)methyl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H17ClN4OS
    (2S)-N-[(2-chlorophenyl)methyl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-tert-butyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C11H20N4OS
    (2R)-N-tert-butyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-N-tert-butyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C11H20N4OS
    (2S)-N-tert-butyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-N-cycloheptyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H24N4OS
    (2S)-N-cycloheptyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-N-benzyl-N-tert-butyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H26N4OS
    (2S)-N-benzyl-N-tert-butyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)propanamide —— C15H20N4OS
    (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)propanamide
    —— (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)propanamide —— C15H20N4OS
    (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)propanamide
    —— (2R)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C21H24N4O2S
    (2R)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C13H20N4O3S2
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C13H20N4O3S2
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[(1R)-2-methyl-1-pyridin-2-ylpropyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H19N5OS
    N-[(1R)-2-methyl-1-pyridin-2-ylpropyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H22N4O4S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylpropanamide —— C16H20N4O2S
    (2S)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— (2S)-N-[(4-fluorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C20H21FN4O2S
    (2S)-N-[(4-fluorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-N-cycloheptyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H26N4OS
    (2R)-N-cycloheptyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-N-cycloheptyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C20H28N4O2S
    (2S)-N-cycloheptyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H22N4O4S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C13H20N4O3S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— methyl N-[(2S)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanoyl]carbamate —— C15H18N4O4S
    methyl N-[(2S)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanoyl]carbamate
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H22N4O4S2
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-N-[(2-chlorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C20H21ClN4O2S
    (2R)-N-[(2-chlorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C21H24N4O2S
    (2S)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2R)-N-cycloheptyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C20H28N4O2S
    (2R)-N-cycloheptyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 7-Methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C13H14N6OS2
    7-Methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— (2R)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)propanamide —— C21H22N4OS2
    (2R)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)propanamide
    —— (2R)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylpropanamide —— C16H20N4O2S
    (2R)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— (2S)-N-[(4-methylphenyl)methyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H22N4OS
    (2S)-N-[(4-methylphenyl)methyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-[[5-(4-Methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C20H18N4O2S2
    2-[[5-(4-Methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— N-[(1S)-2-methyl-1-pyridin-2-ylpropyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H19N5OS
    N-[(1S)-2-methyl-1-pyridin-2-ylpropyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-3-methyl-1-morpholin-4-yl-2-[[5-(thiophen-2-ylmethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]butan-1-one —— C16H22N4O2S2
    (2R)-3-methyl-1-morpholin-4-yl-2-[[5-(thiophen-2-ylmethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]butan-1-one
    —— 2-(4-Fluorophenyl)sulfanyl-4-morpholin-4-ylpyridine-3-carbonitrile —— C16H14FN3OS
    2-(4-Fluorophenyl)sulfanyl-4-morpholin-4-ylpyridine-3-carbonitrile
    —— 2-(2,5-Dimethylfuran-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C12H13N5O2S
    2-(2,5-Dimethylfuran-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— 5-[(4-Methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C10H9N5OS2
    5-[(4-Methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 2-(4-Methoxyphenyl)sulfanyl-4-morpholin-4-ylpyridine-3-carbonitrile —— C17H17N3O2S
    2-(4-Methoxyphenyl)sulfanyl-4-morpholin-4-ylpyridine-3-carbonitrile
    —— (2S)-N-cyclohexyl-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanamide —— C15H26N4OS
    (2S)-N-cyclohexyl-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanamide
    —— (5S)-5-methyl-3-(4-oxidopyrazin-4-ium-2-yl)-5,6-dihydro-[1,3]thiazolo[2,3-c][1,2,4]triazole —— C9H9N5OS
    (5S)-5-methyl-3-(4-oxidopyrazin-4-ium-2-yl)-5,6-dihydro-[1,3]thiazolo[2,3-c][1,2,4]triazole
    —— 2-Phenylsulfanyl-5-pyrimidin-2-yl-1,3,4-thiadiazole —— C12H8N4S2
    2-Phenylsulfanyl-5-pyrimidin-2-yl-1,3,4-thiadiazole
    —— (2S)-3-methyl-1-morpholin-4-yl-2-[[5-(thiophen-2-ylmethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]butan-1-one —— C16H22N4O2S2
    (2S)-3-methyl-1-morpholin-4-yl-2-[[5-(thiophen-2-ylmethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]butan-1-one
    —— 2-Methylsulfanyl-5-pyrimidin-2-yl-1,3,4-thiadiazole —— C7H6N4S2
    2-Methylsulfanyl-5-pyrimidin-2-yl-1,3,4-thiadiazole
    —— 4-Morpholin-4-yl-2-(2-morpholin-4-ylethylsulfanyl)pyridine-3-carbonitrile —— C16H22N4O2S
    4-Morpholin-4-yl-2-(2-morpholin-4-ylethylsulfanyl)pyridine-3-carbonitrile
    —— 2-[(4-Methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C14H15N5OS2
    2-[(4-Methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— (5R)-5-methyl-3-(4-oxidopyrazin-4-ium-2-yl)-5,6-dihydro-[1,3]thiazolo[2,3-c][1,2,4]triazole —— C9H9N5OS
    (5R)-5-methyl-3-(4-oxidopyrazin-4-ium-2-yl)-5,6-dihydro-[1,3]thiazolo[2,3-c][1,2,4]triazole
    —— (2R)-N-cyclohexyl-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanamide —— C15H26N4OS
    (2R)-N-cyclohexyl-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanamide
    —— 2-Methylsulfanyl-5-(4-oxidopyrazin-4-ium-2-yl)-1,3,4-thiadiazole —— C7H6N4OS2
    2-Methylsulfanyl-5-(4-oxidopyrazin-4-ium-2-yl)-1,3,4-thiadiazole
    —— (2R)-N-cyclohexyl-3-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide —— C17H24N4OS2
    (2R)-N-cyclohexyl-3-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide
    —— (2R)-N-cyclopentyl-3-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide —— C16H22N4OS2
    (2R)-N-cyclopentyl-3-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide