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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide —— C14H19N3O3S
    (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide
    —— (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide —— C13H15N3O3S
    (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— (2R)-N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H19N3O3S
    (2R)-N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)propanamide —— C18H19N3O3S
    (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)propanamide
    —— (2S)-N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H19N3O3S
    (2S)-N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H17N3O5S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— methyl N-[(2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C12H13N3O5S
    methyl N-[(2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— 1-[(2S)-2-(5-methylthiophen-2-yl)pyrrolidin-1-yl]-3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C15H20N4OS2
    1-[(2S)-2-(5-methylthiophen-2-yl)pyrrolidin-1-yl]-3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— [(3S)-1,1-dioxothiolan-3-yl] 2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C13H14N2O6S2
    [(3S)-1,1-dioxothiolan-3-yl] 2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)propanamide —— C18H19N3O3S
    (2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)propanamide
    —— (2R)-N-(2-methoxyethyl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C13H17N3O4S
    (2R)-N-(2-methoxyethyl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2-ethyl-1,3-thiazol-4-yl)methyl 2-(2-fluorophenyl)sulfanylacetate —— C14H14FNO2S2
    (2-ethyl-1,3-thiazol-4-yl)methyl 2-(2-fluorophenyl)sulfanylacetate
    —— methyl N-[(2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C12H13N3O5S
    methyl N-[(2S)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— (2S)-N-(1-cyanocyclohexyl)-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H22N4O3S
    (2S)-N-(1-cyanocyclohexyl)-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— ethyl (2Z)-2-[3-[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate —— C16H17N3O5S2
    ethyl (2Z)-2-[3-[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate
    —— (2E)-2-(2,5,6,7,8,9-hexahydro-[1,2,4]triazolo[4,3-a]azepin-3-ylidene)-4-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C18H18N6O3S
    (2E)-2-(2,5,6,7,8,9-hexahydro-[1,2,4]triazolo[4,3-a]azepin-3-ylidene)-4-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— 3-benzyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C16H12N6O2S2
    3-benzyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 3-cyclopropyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C12H10N6O2S2
    3-cyclopropyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 1-imidazol-1-yl-2-(1-propyltetrazol-5-yl)sulfanylethanone —— C9H12N6OS
    1-imidazol-1-yl-2-(1-propyltetrazol-5-yl)sulfanylethanone
    —— 3-ethyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C11H10N6O2S2
    3-ethyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 3-cyclopentyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C14H14N6O2S2
    3-cyclopentyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C9H6N6O2S2
    7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 3-tert-butyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C13H14N6O2S2
    3-tert-butyl-7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-3-(4-methylphenyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C16H12N6O2S2
    7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-3-(4-methylphenyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C15H10N6O2S2
    7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-3-methyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C10H8N6O2S2
    7-(2-imidazol-1-yl-2-oxoethyl)sulfanyl-3-methyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— (4-Oxo-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-2-yl)methyl 2-(2,5-dimethylphenyl)sulfanylacetate —— C21H22N2O3S2
    (4-Oxo-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-2-yl)methyl 2-(2,5-dimethylphenyl)sulfanylacetate
    —— 2-[6-tert-butyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid —— C18H23N3O3S
    2-[6-tert-butyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid
    —— 2-[5-(2-hydroxyethyl)-6-methyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid —— C17H21N3O4S
    2-[5-(2-hydroxyethyl)-6-methyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid
    —— 2-[5,6-dimethyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid —— C16H19N3O3S
    2-[5,6-dimethyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid
    —— 2-[2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid —— C14H15N3O3S
    2-[2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid
    —— 2-[5-ethyl-6-methyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid —— C17H21N3O3S
    2-[5-ethyl-6-methyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid
    —— 2-[[2-[(4-methylsulfanylphenyl)methylamino]-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]oxy]acetic acid —— C17H19N3O3S
    2-[[2-[(4-methylsulfanylphenyl)methylamino]-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]oxy]acetic acid
    —— 2-[6-ethyl-5-methyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid —— C17H21N3O3S
    2-[6-ethyl-5-methyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid
    —— 2-[6-ethyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid —— C16H19N3O3S
    2-[6-ethyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid
    —— 2-[2-[(4-methylsulfanylphenyl)methylamino]-6-(trifluoromethyl)pyrimidin-4-yl]oxyacetic acid —— C15H14F3N3O3S
    2-[2-[(4-methylsulfanylphenyl)methylamino]-6-(trifluoromethyl)pyrimidin-4-yl]oxyacetic acid
    —— 2-[2-[(4-methylsulfanylphenyl)methylamino]-6-pyridin-4-ylpyrimidin-4-yl]oxyacetic acid —— C19H18N4O3S
    2-[2-[(4-methylsulfanylphenyl)methylamino]-6-pyridin-4-ylpyrimidin-4-yl]oxyacetic acid
    —— 2-[2-[(4-methylsulfanylphenyl)methylamino]-6-propan-2-ylpyrimidin-4-yl]oxyacetic acid —— C17H21N3O3S
    2-[2-[(4-methylsulfanylphenyl)methylamino]-6-propan-2-ylpyrimidin-4-yl]oxyacetic acid
    —— 2-[6-methyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid —— C15H17N3O3S
    2-[6-methyl-2-[(4-methylsulfanylphenyl)methylamino]pyrimidin-4-yl]oxyacetic acid
    —— 2-[5,6-dimethyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid —— C15H17N3O3S
    2-[5,6-dimethyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid
    —— 2-[6-tert-butyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid —— C17H21N3O3S
    2-[6-tert-butyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid
    —— 2-[[2-(3-methylsulfanylanilino)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]oxy]acetic acid —— C16H17N3O3S
    2-[[2-(3-methylsulfanylanilino)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]oxy]acetic acid
    —— 2-[2-(3-methylsulfanylanilino)-6-(trifluoromethyl)pyrimidin-4-yl]oxyacetic acid —— C14H12F3N3O3S
    2-[2-(3-methylsulfanylanilino)-6-(trifluoromethyl)pyrimidin-4-yl]oxyacetic acid
    —— 2-[5-(2-hydroxyethyl)-6-methyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid —— C16H19N3O4S
    2-[5-(2-hydroxyethyl)-6-methyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid
    —— 2-[2-(3-methylsulfanylanilino)-6-propylpyrimidin-4-yl]oxyacetic acid —— C16H19N3O3S
    2-[2-(3-methylsulfanylanilino)-6-propylpyrimidin-4-yl]oxyacetic acid
    —— 2-[2-(3-methylsulfanylanilino)-6-pyridin-4-ylpyrimidin-4-yl]oxyacetic acid —— C18H16N4O3S
    2-[2-(3-methylsulfanylanilino)-6-pyridin-4-ylpyrimidin-4-yl]oxyacetic acid
    —— 2-[6-ethyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid —— C15H17N3O3S
    2-[6-ethyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid
    —— 2-[6-ethyl-5-methyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid —— C16H19N3O3S
    2-[6-ethyl-5-methyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid
    —— 2-[6-(methoxymethyl)-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid —— C15H17N3O4S
    2-[6-(methoxymethyl)-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid
    —— 2-[5-ethyl-6-methyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid —— C16H19N3O3S
    2-[5-ethyl-6-methyl-2-(3-methylsulfanylanilino)pyrimidin-4-yl]oxyacetic acid