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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(1S)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C13H18N4O2S
    2-[(1S)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— 2-[2-[3-[[(2S)-oxan-2-yl]methylsulfanyl]-1,2,4-triazol-4-yl]ethyl]pyridine —— C15H20N4OS
    2-[2-[3-[[(2S)-oxan-2-yl]methylsulfanyl]-1,2,4-triazol-4-yl]ethyl]pyridine
    —— 2-[(1S)-1-(1-cyclopentyltetrazol-5-yl)sulfanylethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole —— C14H22N6OS
    2-[(1S)-1-(1-cyclopentyltetrazol-5-yl)sulfanylethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole
    —— 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-[(4-methylphenyl)methyl]acetamide —— C21H24N4OS2
    2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-[(4-methylphenyl)methyl]acetamide
    —— 2-[(1S)-1-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole —— C15H19N5O2S
    2-[(1S)-1-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole
    —— 2-(2-cyclohexylethyl)-5-[(1S)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H24N4O2S
    2-(2-cyclohexylethyl)-5-[(1S)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-(2-methylpropyl)-5-[(1S)-1-[(4-methyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole —— C15H19N5OS2
    2-(2-methylpropyl)-5-[(1S)-1-[(4-methyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole
    —— 5-[(2,5-dimethylphenyl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine —— C19H21N3S2
    5-[(2,5-dimethylphenyl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine
    —— 5-[(3-bromophenyl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine —— C17H16BrN3S2
    5-[(3-bromophenyl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine
    —— 2-(2-cyclohexylethyl)-5-[(1R)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H24N4O2S
    2-(2-cyclohexylethyl)-5-[(1R)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— 3-(2-methylfuran-3-yl)-5-[(1R)-1-[5-(2-methylpropyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine —— C15H20N6O2S
    3-(2-methylfuran-3-yl)-5-[(1R)-1-[5-(2-methylpropyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— 2-[(1R)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C13H18N4O2S
    2-[(1R)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— N-(1-cyanocyclohexyl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H23N5OS2
    N-(1-cyanocyclohexyl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(1R)-1-(1-benzyltetrazol-5-yl)sulfanylethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole —— C16H20N6OS
    2-[(1R)-1-(1-benzyltetrazol-5-yl)sulfanylethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole
    —— (2S)-N-[[(3R)-1,1-dioxothiolan-3-yl]methyl]-2-phenylsulfanylbutanamide —— C15H21NO3S2
    (2S)-N-[[(3R)-1,1-dioxothiolan-3-yl]methyl]-2-phenylsulfanylbutanamide
    —— 2-[(1S)-1-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole —— C15H19N5O2S
    2-[(1S)-1-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-(2-methylpropyl)-1,3,4-oxadiazole
    —— 5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine —— C17H15ClFN3S2
    5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine
    —— 2-(2-methylpropyl)-5-[(1R)-1-[(4-methyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole —— C15H19N5OS2
    2-(2-methylpropyl)-5-[(1R)-1-[(4-methyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole
    —— (2R)-N-[[(3S)-1,1-dioxothiolan-3-yl]methyl]-2-phenylsulfanylbutanamide —— C15H21NO3S2
    (2R)-N-[[(3S)-1,1-dioxothiolan-3-yl]methyl]-2-phenylsulfanylbutanamide
    —— N-(4-ethylphenyl)-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H19N3S3
    N-(4-ethylphenyl)-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 3-[(1R)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C16H19N5O2S
    3-[(1R)-1-(5-ethyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C21H28N4OS2
    (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 1-(2,5-Dimethyl-1-propylpyrrol-3-yl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C21H26N4OS2
    1-(2,5-Dimethyl-1-propylpyrrol-3-yl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N-(4-ethylphenyl)-5-[2-(2-fluorophenyl)sulfanylethylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H18FN3S3
    N-(4-ethylphenyl)-5-[2-(2-fluorophenyl)sulfanylethylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(4-ethylphenyl)-5-[(3-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H19N3S2
    N-(4-ethylphenyl)-5-[(3-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2S)-N-cyclopentyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H24N4OS2
    (2S)-N-cyclopentyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-(4-ethylphenyl)-5-[(2-thiophen-2-yl-1,3-oxazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H16N4OS3
    N-(4-ethylphenyl)-5-[(2-thiophen-2-yl-1,3-oxazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— Butyl 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H21N3O2S2
    Butyl 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— N-[(3-chlorophenyl)methyl]-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H19ClN4OS2
    N-[(3-chlorophenyl)methyl]-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-N-cyclopentyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H24N4OS2
    (2R)-N-cyclopentyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-benzyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H22N4OS2
    (2S)-N-benzyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-benzyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C21H24N4OS2
    (2S)-N-benzyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— 4-[[5-(4-Ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one —— C18H19N3OS3
    4-[[5-(4-Ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one
    —— 5-[(4-chlorophenyl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine —— C17H16ClN3S2
    5-[(4-chlorophenyl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine
    —— ethyl (2R)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-phenylacetate —— C20H21N3O2S2
    ethyl (2R)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-phenylacetate
    —— 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C16H22N4O2S2
    2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— (2R)-N-benzyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C21H24N4OS2
    (2R)-N-benzyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(4-methylcyclohexyl)acetamide —— C19H26N4OS2
    2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(4-methylcyclohexyl)acetamide
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 4-chlorobenzoate —— C21H16ClNO3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 4-chlorobenzoate
    —— [2-[4-(4-Bromophenyl)sulfanylanilino]-2-oxoethyl] butanoate —— C18H18BrNO3S
    [2-[4-(4-Bromophenyl)sulfanylanilino]-2-oxoethyl] butanoate
    —— (3-Methyl-5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 2-(2,5-dimethylphenyl)sulfanylacetate —— C18H18N2O3S2
    (3-Methyl-5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 2-(2,5-dimethylphenyl)sulfanylacetate
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]acetamide —— C18H25BrN2O2S2
    2-(4-bromo-2-methylphenyl)sulfanyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]acetamide
    —— [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C18H24BrNO3S
    [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]acetamide —— C18H25BrN2O2S2
    2-(4-bromo-2-methylphenyl)sulfanyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]acetamide
    —— [2-[(1-Methylpyrrole-2-carbonyl)amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C18H20N2O4S
    [2-[(1-Methylpyrrole-2-carbonyl)amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-oxo-2-(1H-pyrrol-2-yl)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C16H17NO3S
    [2-oxo-2-(1H-pyrrol-2-yl)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(4-Methylphenyl)-1,3-thiazol-4-yl]methyl 2-(2,5-dimethylphenyl)sulfanylacetate —— C21H21NO2S2
    [2-(4-Methylphenyl)-1,3-thiazol-4-yl]methyl 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[(1R)-1-(1-adamantyl)ethyl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C24H33NO3S
    [2-[[(1R)-1-(1-adamantyl)ethyl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— methyl 5-[(2S)-2-[2-(2,5-dimethylphenyl)sulfanylacetyl]oxypropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C21H25NO5S
    methyl 5-[(2S)-2-[2-(2,5-dimethylphenyl)sulfanylacetyl]oxypropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— [2-(1-Adamantyl)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C22H28O3S
    [2-(1-Adamantyl)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate