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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H21ClN4OS
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H26N4OS
    N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[5-cyclopropyl-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C17H22N4O3S
    2-[[5-cyclopropyl-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H21ClN4OS
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1R,2S,3R)-2,3-dimethylcyclohexyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H26N4OS
    N-[(1R,2S,3R)-2,3-dimethylcyclohexyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (1S)-1-[4-butyl-5-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C20H27ClN6OS
    (1S)-1-[4-butyl-5-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H19ClN4OS
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H21ClN4O2S
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide —— C14H27N5OS
    2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide
    —— N-[(1S,2S,3R)-2,3-dimethylcyclohexyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H26N4OS
    N-[(1S,2S,3R)-2,3-dimethylcyclohexyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H19ClN4OS
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide —— C14H27N5OS
    2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide
    —— (2R)-N-(1-cyanocyclohexyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H23N5OS
    (2R)-N-(1-cyanocyclohexyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-2-[[4-benzyl-5-(5-bromofuran-2-yl)-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one —— C19H18BrN3O2S
    (2R)-2-[[4-benzyl-5-(5-bromofuran-2-yl)-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one
    —— (2S)-2-[[4-benzyl-5-(5-bromofuran-2-yl)-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one —— C19H18BrN3O2S
    (2S)-2-[[4-benzyl-5-(5-bromofuran-2-yl)-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one
    —— (2R)-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C15H15F2N3OS3
    (2R)-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (S)-cyclohexyl-[4-(trifluoromethylsulfanyl)phenyl]methanol —— C14H17F3OS
    (S)-cyclohexyl-[4-(trifluoromethylsulfanyl)phenyl]methanol
    —— (2S)-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C15H15F2N3OS3
    (2S)-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— 3-[[(5-bromofuran-2-yl)methyl-methylamino]methyl]-5-methylsulfanyl-1,3,4-thiadiazole-2-thione —— C10H12BrN3OS3
    3-[[(5-bromofuran-2-yl)methyl-methylamino]methyl]-5-methylsulfanyl-1,3,4-thiadiazole-2-thione
    —— N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H21N3OS3
    N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H14ClN3OS3
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (R)-cyclohexyl-[4-(trifluoromethylsulfanyl)phenyl]methanol —— C14H17F3OS
    (R)-cyclohexyl-[4-(trifluoromethylsulfanyl)phenyl]methanol
    —— (R)-cyclopentyl-[4-(trifluoromethylsulfanyl)phenyl]methanol —— C13H15F3OS
    (R)-cyclopentyl-[4-(trifluoromethylsulfanyl)phenyl]methanol
    —— (2S)-N-(1-cyanocyclohexyl)-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H18N4OS3
    (2S)-N-(1-cyanocyclohexyl)-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H14ClN3OS3
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (S)-cyclopentyl-[4-(trifluoromethylsulfanyl)phenyl]methanol —— C13H15F3OS
    (S)-cyclopentyl-[4-(trifluoromethylsulfanyl)phenyl]methanol
    —— N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H21N3OS3
    N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H21N3OS3
    N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-(1-cyanocyclohexyl)-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H18N4OS3
    (2R)-N-(1-cyanocyclohexyl)-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]acetamide —— C18H23N3OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]acetamide
    —— (2R)-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]-2-phenylsulfanylpropanamide —— C17H25NOS
    (2R)-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]-2-phenylsulfanylpropanamide
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H18ClN3OS
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (2R)-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-phenylsulfanylpropanamide —— C17H25NOS
    (2R)-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-phenylsulfanylpropanamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]acetamide —— C18H23N3OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]acetamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H18ClN3OS
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (2R)-N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-phenylsulfanylpropanamide —— C17H25NOS
    (2R)-N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-phenylsulfanylpropanamide
    —— 4-[2-(4-Chlorophenyl)sulfanylethyl]morpholin-4-ium —— C12H17ClNOS+
    4-[2-(4-Chlorophenyl)sulfanylethyl]morpholin-4-ium
    —— 1-[3-(4-Chlorophenyl)sulfanylpropyl]-4-methylpiperazine-1,4-diium —— C14H23ClN2S+2
    1-[3-(4-Chlorophenyl)sulfanylpropyl]-4-methylpiperazine-1,4-diium
    —— ethyl (3S)-1-[2-(4-bromophenyl)sulfanylpyridine-3-carbonyl]piperidine-3-carboxylate —— C20H21BrN2O3S
    ethyl (3S)-1-[2-(4-bromophenyl)sulfanylpyridine-3-carbonyl]piperidine-3-carboxylate
    —— (2S)-N-[(4-ethylcyclohexyl)methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H26N4OS
    (2S)-N-[(4-ethylcyclohexyl)methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R,6S)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholin-4-ium —— C14H22NOS+
    (2R,6S)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholin-4-ium
    —— (2R,6R)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholine —— C14H21NOS
    (2R,6R)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholine
    —— (2R,6S)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholine —— C14H21NOS
    (2R,6S)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholine
    —— 2-(4-methylphenyl)sulfanylethyl-[[(2S)-oxolan-2-yl]methyl]azanium —— C14H22NOS+
    2-(4-methylphenyl)sulfanylethyl-[[(2S)-oxolan-2-yl]methyl]azanium
    —— (2R,6R)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholin-4-ium —— C14H22NOS+
    (2R,6R)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholin-4-ium
    —— (2S,6S)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholin-4-ium —— C14H22NOS+
    (2S,6S)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholin-4-ium
    —— 4-[4-(4-Methylphenyl)sulfanylbutyl]morpholin-4-ium —— C15H24NOS+
    4-[4-(4-Methylphenyl)sulfanylbutyl]morpholin-4-ium
    —— (2S,6S)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholine —— C14H21NOS
    (2S,6S)-2,6-dimethyl-4-(2-phenylsulfanylethyl)morpholine
    —— (2R,6S)-2,6-dimethyl-4-[2-(4-methylphenyl)sulfanylethyl]morpholin-4-ium —— C15H24NOS+
    (2R,6S)-2,6-dimethyl-4-[2-(4-methylphenyl)sulfanylethyl]morpholin-4-ium
    —— 4-[3-(4-Methylphenyl)sulfanylpropyl]morpholin-4-ium —— C14H22NOS+
    4-[3-(4-Methylphenyl)sulfanylpropyl]morpholin-4-ium