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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzyl-N-methylpropanamide —— C14H19N5OS
    (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzyl-N-methylpropanamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C9H15N5O3S2
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C16H23N5OS
    (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(1-cyanocyclohexyl)-N-methylacetamide —— C13H20N6OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(1-cyanocyclohexyl)-N-methylacetamide
    —— (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C6H11N5OS
    (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide —— C14H16F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzyl-N-(2-phenylethyl)acetamide —— C20H23N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzyl-N-(2-phenylethyl)acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(2-methylphenyl)methyl]acetamide —— C14H19N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(2-methylphenyl)methyl]acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(2-chlorophenyl)ethyl]acetamide —— C13H16ClN5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(2-chlorophenyl)ethyl]acetamide
    —— (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopentylpropanamide —— C11H19N5OS
    (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopentylpropanamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide —— C15H21N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C11H19N5O3S2
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)propanamide —— C11H15N5O2S
    (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)propanamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide —— C14H19N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-[(2S)-3-methyl-2-morpholin-4-ylbutyl]acetamide —— C18H27BrN2O2S
    2-(4-bromo-2-methylphenyl)sulfanyl-N-[(2S)-3-methyl-2-morpholin-4-ylbutyl]acetamide
    —— (2R)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)propanamide —— C11H15N5O2S
    (2R)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)propanamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide —— C14H19N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide —— C14H16F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide
    —— (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C16H20F3N5OS
    (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— 3-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-5-methyl-1,2,4-triazol-4-amine —— C11H13FN4S
    3-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-5-methyl-1,2,4-triazol-4-amine
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide —— C12H14ClN5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide
    —— 3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-5-methyl-1,2,4-triazol-4-amine —— C11H13FN4S
    3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-5-methyl-1,2,4-triazol-4-amine
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-[(2R)-3-methyl-2-morpholin-4-ylbutyl]acetamide —— C18H27BrN2O2S
    2-(4-bromo-2-methylphenyl)sulfanyl-N-[(2R)-3-methyl-2-morpholin-4-ylbutyl]acetamide
    —— 1-[(2R)-2-benzylpyrrolidin-1-yl]-2-(2-methylphenyl)sulfanylethanone —— C20H23NOS
    1-[(2R)-2-benzylpyrrolidin-1-yl]-2-(2-methylphenyl)sulfanylethanone
    —— N-cyclopropyl-N-[5-[(1R)-1-phenylethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide —— C15H17N3OS2
    N-cyclopropyl-N-[5-[(1R)-1-phenylethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide
    —— N-cyclopropyl-N-[5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide —— C15H17N3OS2
    N-cyclopropyl-N-[5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide
    —— (2-Amino-2-oxoethyl) 3-phenylsulfanylpropanoate —— C11H13NO3S
    (2-Amino-2-oxoethyl) 3-phenylsulfanylpropanoate
    —— [2-[[(1R)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C19H20ClNO3S
    [2-[[(1R)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C17H20N2O3S
    [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— [2-(6-Amino-2,4-dioxo-1-propylpyrimidin-5-yl)-2-oxoethyl] 3-phenylsulfanylpropanoate —— C18H21N3O5S
    [2-(6-Amino-2,4-dioxo-1-propylpyrimidin-5-yl)-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C15H19NO3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— [(2R)-1-amino-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C12H15NO3S
    [(2R)-1-amino-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— (2S)-2-[[5-[(3S,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C17H23N5OS
    (2S)-2-[[5-[(3S,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C19H20FNO3S
    [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— (2S)-2-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C17H23N5OS
    (2S)-2-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C15H19NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— [(2S)-1-amino-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C12H15NO3S
    [(2S)-1-amino-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— [2-(1-Adamantylamino)-2-oxoethyl] 3-phenylsulfanylpropanoate —— C21H27NO3S
    [2-(1-Adamantylamino)-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— (2S)-2-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C25H32FN5O2S
    (2S)-2-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C15H19NO5S2
    [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C15H19NO3S
    [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— [2-[[(1R)-1-(1-adamantyl)ethyl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C23H31NO3S
    [2-[[(1R)-1-(1-adamantyl)ethyl]amino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— (2S)-N-benzyl-2-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide —— C25H33N5O2S
    (2S)-N-benzyl-2-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide
    —— (3R,5S)-1-[4-(furan-2-ylmethyl)-5-propan-2-ylsulfanyl-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine —— C17H26N4OS
    (3R,5S)-1-[4-(furan-2-ylmethyl)-5-propan-2-ylsulfanyl-1,2,4-triazol-3-yl]-3,5-dimethylpiperidine
    —— (2S)-2-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C17H23N5OS
    (2S)-2-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— (2S)-2-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C25H32FN5O2S
    (2S)-2-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C24H23NO3S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— (2S)-N-benzyl-2-[[5-[(3S,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide —— C25H33N5O2S
    (2S)-N-benzyl-2-[[5-[(3S,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide
    —— ethyl 2,5-dimethyl-4-[2-(3-phenylsulfanylpropanoyloxy)acetyl]-1H-pyrrole-3-carboxylate —— C20H23NO5S
    ethyl 2,5-dimethyl-4-[2-(3-phenylsulfanylpropanoyloxy)acetyl]-1H-pyrrole-3-carboxylate
    —— [2-[(1-Methylpyrrole-2-carbonyl)amino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C17H18N2O4S
    [2-[(1-Methylpyrrole-2-carbonyl)amino]-2-oxoethyl] 3-phenylsulfanylpropanoate