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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1S,2S)-2-methylcyclohexyl]-2-[(4-methylsulfanylphenyl)methylsulfanyl]acetamide —— C17H25NOS2
    N-[(1S,2S)-2-methylcyclohexyl]-2-[(4-methylsulfanylphenyl)methylsulfanyl]acetamide
    —— [(2S)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C18H20N2O3S
    [(2S)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C15H19N3O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— 2-[(4-methylsulfanylphenyl)methylsulfanyl]-N-(2-phenylethyl)acetamide —— C18H21NOS2
    2-[(4-methylsulfanylphenyl)methylsulfanyl]-N-(2-phenylethyl)acetamide
    —— [(2S)-1-(dimethylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C19H22N2O3S
    [(2S)-1-(dimethylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— 2-(3,4-dimethylphenyl)-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole —— C21H20N4O2S
    2-(3,4-dimethylphenyl)-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole
    —— [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C18H20N2O3S
    [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [(2R)-1-(dimethylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C17H17ClN2O3S
    [(2R)-1-(dimethylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— (4,6-Diamino-1,3,5-triazin-2-yl)methyl 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C16H13ClN6O2S
    (4,6-Diamino-1,3,5-triazin-2-yl)methyl 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— N-[(1R,2S)-2-methylcyclohexyl]-2-[(4-methylsulfanylphenyl)methylsulfanyl]acetamide —— C17H25NOS2
    N-[(1R,2S)-2-methylcyclohexyl]-2-[(4-methylsulfanylphenyl)methylsulfanyl]acetamide
    —— 2-[(3,4-Difluorophenyl)methylsulfanyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C13H8F2N2OS2
    2-[(3,4-Difluorophenyl)methylsulfanyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— (4,6-Diamino-1,3,5-triazin-2-yl)methyl 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C17H16N6O2S
    (4,6-Diamino-1,3,5-triazin-2-yl)methyl 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— 2-(3-Piperidin-1-ylpyrazin-2-yl)sulfanylacetohydrazide —— C11H17N5OS
    2-(3-Piperidin-1-ylpyrazin-2-yl)sulfanylacetohydrazide
    —— 2-(4-Pyrrolidin-1-ylpyrimidin-2-yl)sulfanylacetic acid —— C10H13N3O2S
    2-(4-Pyrrolidin-1-ylpyrimidin-2-yl)sulfanylacetic acid
    —— N-[(1R)-2-methyl-1-pyridin-4-ylpropyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H19N5OS
    N-[(1R)-2-methyl-1-pyridin-4-ylpropyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-2-methyl-1-pyridin-4-ylpropyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H19N5OS
    N-[(1S)-2-methyl-1-pyridin-4-ylpropyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2-methoxypyridin-4-yl)methyl]propanamide —— C16H17ClN2O2S
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2-methoxypyridin-4-yl)methyl]propanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(2-methoxypyridin-4-yl)methyl]propanamide —— C16H17ClN2O2S
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(2-methoxypyridin-4-yl)methyl]propanamide
    —— 2-[6-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetohydrazide —— C13H21N5OS
    2-[6-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]acetohydrazide —— C7H7F3N4O2S
    2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]acetohydrazide
    —— (3-Cyano-pyridin-2-ylsulfanyl)-acetic acid hydrazide —— C8H8N4OS
    (3-Cyano-pyridin-2-ylsulfanyl)-acetic acid hydrazide
    —— 2-[4-(3,5-Dimethylpyrazol-1-yl)pyrimidin-2-yl]sulfanylacetic acid —— C11H12N4O2S
    2-[4-(3,5-Dimethylpyrazol-1-yl)pyrimidin-2-yl]sulfanylacetic acid
    —— 2-[[5-[(5-Methylpyrazol-1-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetic acid —— C9H10N4O3S
    2-[[5-[(5-Methylpyrazol-1-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetic acid
    —— 2-(6-Thiomorpholin-4-ylpyrimidin-4-yl)sulfanylacetohydrazide —— C10H15N5OS2
    2-(6-Thiomorpholin-4-ylpyrimidin-4-yl)sulfanylacetohydrazide
    —— 2-[3-[(2-Fluorophenyl)methylamino]pyrazin-2-yl]sulfanylacetohydrazide —— C13H14FN5OS
    2-[3-[(2-Fluorophenyl)methylamino]pyrazin-2-yl]sulfanylacetohydrazide
    —— 2-(6-Thiomorpholin-4-ylpyrimidin-4-yl)sulfanylacetic acid —— C10H13N3O2S2
    2-(6-Thiomorpholin-4-ylpyrimidin-4-yl)sulfanylacetic acid
    —— 2-[6-[(2-Chlorophenyl)methylamino]pyrimidin-4-yl]sulfanylacetohydrazide —— C13H14ClN5OS
    2-[6-[(2-Chlorophenyl)methylamino]pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-[6-[(3S)-3-methylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetohydrazide —— C12H19N5OS
    2-[6-[(3S)-3-methylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-[6-(3,5-Dimethylpyrazol-1-yl)pyrimidin-4-yl]sulfanylacetohydrazide —— C11H14N6OS
    2-[6-(3,5-Dimethylpyrazol-1-yl)pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-[6-[(2-Chlorophenyl)methylsulfanyl]pyrimidin-4-yl]sulfanylacetohydrazide —— C13H13ClN4OS2
    2-[6-[(2-Chlorophenyl)methylsulfanyl]pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-[6-(3-Methyl-4,5,6,7-tetrahydroindazol-1-yl)pyrimidin-4-yl]sulfanylacetohydrazide —— C14H18N6OS
    2-[6-(3-Methyl-4,5,6,7-tetrahydroindazol-1-yl)pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-[6-(4-Methylpiperidin-1-yl)pyrimidin-4-yl]sulfanylacetohydrazide —— C12H19N5OS
    2-[6-(4-Methylpiperidin-1-yl)pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-[6-[(3R)-3-methylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetohydrazide —— C12H19N5OS
    2-[6-[(3R)-3-methylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-(6-Piperidin-1-ylpyrimidin-4-yl)sulfanylacetic acid —— C11H15N3O2S
    2-(6-Piperidin-1-ylpyrimidin-4-yl)sulfanylacetic acid
    —— 2-[6-[(2-Chlorophenyl)methylamino]pyrimidin-4-yl]sulfanylacetic acid —— C13H12ClN3O2S
    2-[6-[(2-Chlorophenyl)methylamino]pyrimidin-4-yl]sulfanylacetic acid
    —— 2-[6-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetohydrazide —— C13H21N5OS
    2-[6-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetohydrazide
    —— 2-[6-[(3S)-3-methylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetic acid —— C12H17N3O2S
    2-[6-[(3S)-3-methylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetic acid
    —— 2-[6-[(2-Chlorophenyl)methylsulfanyl]pyrimidin-4-yl]sulfanylacetic acid —— C13H11ClN2O2S2
    2-[6-[(2-Chlorophenyl)methylsulfanyl]pyrimidin-4-yl]sulfanylacetic acid
    —— 2-[6-(3,5-Dimethylpyrazol-1-yl)pyrimidin-4-yl]sulfanylacetic acid —— C11H12N4O2S
    2-[6-(3,5-Dimethylpyrazol-1-yl)pyrimidin-4-yl]sulfanylacetic acid
    —— 2-[(2-Morpholin-4-yl-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)sulfanyl]acetic acid —— C11H12N4O3S2
    2-[(2-Morpholin-4-yl-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)sulfanyl]acetic acid
    —— 1-[6-(2,5-Dimethylphenyl)sulfanylpyrimidin-4-yl]piperidine-4-carbohydrazide —— C18H23N5OS
    1-[6-(2,5-Dimethylphenyl)sulfanylpyrimidin-4-yl]piperidine-4-carbohydrazide
    —— 2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetic acid —— C13H19N3O2S
    2-[6-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-4-yl]sulfanylacetic acid
    —— 2-[4-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-2-yl]sulfanylacetic acid —— C13H19N3O2S
    2-[4-[(3R,5R)-3,5-dimethylpiperidin-1-yl]pyrimidin-2-yl]sulfanylacetic acid
    —— 2-[6-(3-Methyl-4,5,6,7-tetrahydroindazol-1-yl)pyrimidin-4-yl]sulfanylacetic acid —— C14H16N4O2S
    2-[6-(3-Methyl-4,5,6,7-tetrahydroindazol-1-yl)pyrimidin-4-yl]sulfanylacetic acid
    —— 2-[4-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-2-yl]sulfanylacetic acid —— C13H19N3O2S
    2-[4-[(3S,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-2-yl]sulfanylacetic acid
    —— 6-(2,3-dimethylphenyl)-2-methylsulfanyl-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C14H13N3O2S2
    6-(2,3-dimethylphenyl)-2-methylsulfanyl-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 2-ethylsulfanyl-6-(4-methylphenyl)-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C14H13N3O2S2
    2-ethylsulfanyl-6-(4-methylphenyl)-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 3-Chloro-6-[(2,4-dimethylphenyl)methylsulfanyl]pyridazine —— C13H13ClN2S
    3-Chloro-6-[(2,4-dimethylphenyl)methylsulfanyl]pyridazine
    —— 6-(4-methylphenyl)-2-methylsulfanyl-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C13H11N3O2S2
    6-(4-methylphenyl)-2-methylsulfanyl-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 2-[4-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-2-yl]sulfanylacetic acid —— C13H19N3O2S
    2-[4-[(3R,5S)-3,5-dimethylpiperidin-1-yl]pyrimidin-2-yl]sulfanylacetic acid