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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl 2-[2-[2-[2-(2-fluorophenyl)ethylamino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H18FN3O4S
    methyl 2-[2-[2-[2-(2-fluorophenyl)ethylamino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[[5-(4-fluorophenyl)-4-methyl-1,2-oxazol-3-yl]methylsulfanyl]-6-oxo-1H-pyrimidin-4-yl]acetate —— C18H16FN3O4S
    methyl 2-[2-[[5-(4-fluorophenyl)-4-methyl-1,2-oxazol-3-yl]methylsulfanyl]-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2S)-1-(azepan-1-yl)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C16H23N3O4S
    methyl 2-[2-[(2S)-1-(azepan-1-yl)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[[(2S)-oxolan-2-yl]methylsulfanyl]-1H-pyrimidin-4-yl]acetate —— C12H16N2O4S
    methyl 2-[6-oxo-2-[[(2S)-oxolan-2-yl]methylsulfanyl]-1H-pyrimidin-4-yl]acetate
    —— (3-Cyano-4-imino-2-oxopentyl) 2-(2,5-difluorophenyl)sulfanylacetate —— C14H12F2N2O3S
    (3-Cyano-4-imino-2-oxopentyl) 2-(2,5-difluorophenyl)sulfanylacetate
    —— methyl 2-[2-[(1S)-1-cyano-2-(4-methylphenyl)ethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H17N3O3S
    methyl 2-[2-[(1S)-1-cyano-2-(4-methylphenyl)ethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— [5-(furan-2-yl)-1,2-oxazol-3-yl]methyl 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C17H13N3O5S
    [5-(furan-2-yl)-1,2-oxazol-3-yl]methyl 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— methyl 2-[2-[2-[[(1S)-3-methyl-1-phenylbutyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C20H25N3O4S
    methyl 2-[2-[2-[[(1S)-3-methyl-1-phenylbutyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C14H19N3O4S
    methyl 2-[2-[2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2R)-1-[(4-fluorophenyl)methylamino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H18FN3O4S
    methyl 2-[2-[(2R)-1-[(4-fluorophenyl)methylamino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[(2R)-1-oxo-1-(prop-2-enylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C13H17N3O4S
    methyl 2-[6-oxo-2-[(2R)-1-oxo-1-(prop-2-enylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[2-oxo-2-(2-oxo-1,3-oxazolidin-3-yl)ethyl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C12H13N3O6S
    methyl 2-[6-oxo-2-[2-oxo-2-(2-oxo-1,3-oxazolidin-3-yl)ethyl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[(2R)-1-oxo-1-(propylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C13H19N3O4S
    methyl 2-[6-oxo-2-[(2R)-1-oxo-1-(propylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H15FN4O4S
    methyl 2-[2-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2R)-1-[di(propan-2-yl)amino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C16H25N3O4S
    methyl 2-[2-[(2R)-1-[di(propan-2-yl)amino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C18H23N3O4S
    methyl 2-[2-[2-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C18H18N4O4S
    methyl 2-[2-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methylsulfanyl]-6-oxo-1H-pyrimidin-4-yl]acetate —— C16H25N3O4S
    methyl 2-[2-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methylsulfanyl]-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[(2-thiophen-3-yl-1,3-thiazol-4-yl)methylsulfanyl]-1H-pyrimidin-4-yl]acetate —— C15H13N3O3S3
    methyl 2-[6-oxo-2-[(2-thiophen-3-yl-1,3-thiazol-4-yl)methylsulfanyl]-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[(2-fluorophenyl)methyl-methylamino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H18FN3O4S
    methyl 2-[2-[2-[(2-fluorophenyl)methyl-methylamino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[(2S)-1-oxo-1-[[(1S)-1-phenylbutyl]amino]propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C20H25N3O4S
    methyl 2-[6-oxo-2-[(2S)-1-oxo-1-[[(1S)-1-phenylbutyl]amino]propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C13H17N3O4S
    methyl 2-[6-oxo-2-[(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H17ClN2O5S
    methyl 2-[2-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2S)-1-[2-cyanoethyl(methyl)amino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C14H18N4O4S
    methyl 2-[2-[(2S)-1-[2-cyanoethyl(methyl)amino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2S)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H22N4O4S
    methyl 2-[2-[(2S)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[[4-(2-methylbutan-2-yl)cyclohexyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C20H31N3O4S
    methyl 2-[2-[2-[[4-(2-methylbutan-2-yl)cyclohexyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[(2S)-1-oxo-1-(2-phenylethylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C18H21N3O4S
    methyl 2-[6-oxo-2-[(2S)-1-oxo-1-(2-phenylethylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[bis[(2R)-butan-2-yl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H27N3O4S
    methyl 2-[2-[2-[bis[(2R)-butan-2-yl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2R)-1-(2-methylpropylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C14H21N3O4S
    methyl 2-[2-[(2R)-1-(2-methylpropylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2S)-1-(methoxycarbonylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C12H15N3O6S
    methyl 2-[2-[(2S)-1-(methoxycarbonylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2S)-1-(cycloheptylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H25N3O4S
    methyl 2-[2-[(2S)-1-(cycloheptylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[cyclohexen-1-yl(ethyl)amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H23N3O4S
    methyl 2-[2-[2-[cyclohexen-1-yl(ethyl)amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[(1-propyltetrazol-5-yl)methylsulfanyl]-1H-pyrimidin-4-yl]acetate —— C12H16N6O3S
    methyl 2-[6-oxo-2-[(1-propyltetrazol-5-yl)methylsulfanyl]-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[2-oxo-2-(pentylamino)ethyl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C14H21N3O4S
    methyl 2-[6-oxo-2-[2-oxo-2-(pentylamino)ethyl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[6-oxo-2-[(2R)-1-oxo-1-(propan-2-ylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C13H19N3O4S
    methyl 2-[6-oxo-2-[(2R)-1-oxo-1-(propan-2-ylamino)propan-2-yl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H15FN4O4S
    methyl 2-[2-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2R)-1-[(2-chlorophenyl)methylamino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H18ClN3O4S
    methyl 2-[2-[(2R)-1-[(2-chlorophenyl)methylamino]-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-(2-acetamidoethylsulfanyl)-6-oxo-1H-pyrimidin-4-yl]acetate —— C11H15N3O4S
    methyl 2-[2-(2-acetamidoethylsulfanyl)-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2S)-1-(ethylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C12H17N3O4S
    methyl 2-[2-[(2S)-1-(ethylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[[(1R)-1-(2,4-difluorophenyl)ethyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H17F2N3O4S
    methyl 2-[2-[2-[[(1R)-1-(2,4-difluorophenyl)ethyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2S)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C15H17N3O5S
    methyl 2-[2-[(2S)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2R)-1-(ethylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C12H17N3O4S
    methyl 2-[2-[(2R)-1-(ethylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H14ClN3O3S2
    methyl 2-[2-[[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[2-(cyclohexen-1-yl)ethylamino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H23N3O4S
    methyl 2-[2-[2-[2-(cyclohexen-1-yl)ethylamino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C13H17N3O4S
    methyl 2-[2-[(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— [2-(azocan-1-yl)-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C18H23N3O4S
    [2-(azocan-1-yl)-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— methyl 2-[6-oxo-2-[2-oxo-2-(2-thiophen-2-ylethylamino)ethyl]sulfanyl-1H-pyrimidin-4-yl]acetate —— C15H17N3O4S2
    methyl 2-[6-oxo-2-[2-oxo-2-(2-thiophen-2-ylethylamino)ethyl]sulfanyl-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[[(1R)-3-methyl-1-phenylbutyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C20H25N3O4S
    methyl 2-[2-[2-[[(1R)-3-methyl-1-phenylbutyl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C15H21N3O5S
    methyl 2-[2-[2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate
    —— methyl 2-[2-[2-[bis[(2S)-butan-2-yl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate —— C17H27N3O4S
    methyl 2-[2-[2-[bis[(2S)-butan-2-yl]amino]-2-oxoethyl]sulfanyl-6-oxo-1H-pyrimidin-4-yl]acetate