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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N,N-diethylacetamide —— C18H27N5O3S
    2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N,N-diethylacetamide
    —— 2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(2-methoxyethyl)acetamide —— C17H25N5O4S
    2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(2-methoxyethyl)acetamide
    —— 2-[7-(3,5-Dimethylphenyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylacetamide —— C18H19N5O3S
    2-[7-(3,5-Dimethylphenyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylacetamide
    —— 2-[1,3-dimethyl-7-(2-methylphenyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanyl-N-methylacetamide —— C18H19N5O3S
    2-[1,3-dimethyl-7-(2-methylphenyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanyl-N-methylacetamide
    —— 2-[7-(2-Fluorophenyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylacetamide —— C16H14FN5O3S
    2-[7-(2-Fluorophenyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylacetamide
    —— 1-[(1S)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C17H25N5OS
    1-[(1S)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-[(1R)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C17H25N5OS
    1-[(1R)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-[(1R)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C17H25N5OS
    1-[(1R)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 2-[7-(Methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylacetamide —— C12H15N5O4S
    2-[7-(Methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylacetamide
    —— 2-methoxyethyl (2R,5S)-2-ethyl-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C20H24N2O4S2
    2-methoxyethyl (2R,5S)-2-ethyl-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 2-[(2Z,5R)-2-[(Z)-(4-methylsulfanylphenyl)methylidenehydrazinylidene]-4-oxo-1,3-thiazolidin-5-yl]acetate —— C13H12N3O3S2-
    2-[(2Z,5R)-2-[(Z)-(4-methylsulfanylphenyl)methylidenehydrazinylidene]-4-oxo-1,3-thiazolidin-5-yl]acetate
    —— N-[(2R)-3-methylbutan-2-yl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C9H15N3OS2
    N-[(2R)-3-methylbutan-2-yl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— 2-[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C14H14N4OS2
    2-[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— 2-[(2E,5R)-2-[(Z)-(4-methylsulfanylphenyl)methylidenehydrazinylidene]-4-oxo-1,3-thiazolidin-5-yl]acetic acid —— C13H13N3O3S2
    2-[(2E,5R)-2-[(Z)-(4-methylsulfanylphenyl)methylidenehydrazinylidene]-4-oxo-1,3-thiazolidin-5-yl]acetic acid
    —— 2-(1,3,4-thiadiazol-2-ylsulfanyl)-N-[(1R)-1-thiophen-2-ylethyl]acetamide —— C10H11N3OS3
    2-(1,3,4-thiadiazol-2-ylsulfanyl)-N-[(1R)-1-thiophen-2-ylethyl]acetamide
    —— 2-methoxyethyl (2S,5S)-2-ethyl-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C20H24N2O4S2
    2-methoxyethyl (2S,5S)-2-ethyl-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 2-methoxyethyl (2R,5R)-2-ethyl-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C20H24N2O4S2
    2-methoxyethyl (2R,5R)-2-ethyl-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(2S)-3-methylbutan-2-yl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C9H15N3OS2
    N-[(2S)-3-methylbutan-2-yl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H14ClN3OS2
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-tert-butyl-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C8H13N3OS2
    N-tert-butyl-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C16H23N3OS2
    N-[(1S)-1-(1-adamantyl)ethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— 2-methoxyethyl (2S,5R)-2-ethyl-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C20H24N2O4S2
    2-methoxyethyl (2S,5R)-2-ethyl-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(1S)-1-(2-chlorophenyl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H14ClN3OS2
    N-[(1S)-1-(2-chlorophenyl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C15H16N4O2S2
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H16FN3OS2
    (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(2R)-3-methylbutan-2-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C10H17N3OS2
    N-[(2R)-3-methylbutan-2-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-propan-2-ylacetamide —— C8H13N3OS2
    2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-propan-2-ylacetamide
    —— N-[(2S)-butan-2-yl]-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H21N3O3S3
    N-[(2S)-butan-2-yl]-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C9H13N3O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C6H9N3OS2
    (2R)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(2R)-butan-2-yl]-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H21N3O3S3
    N-[(2R)-butan-2-yl]-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-(furan-2-ylmethyl)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C11H13N3O2S2
    (2R)-N-(furan-2-ylmethyl)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-benzyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H15N3OS2
    (2R)-N-benzyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H21N3OS2
    (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 3-methyl-7-{[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]methyl}-5H-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C11H10N4OS3
    3-methyl-7-{[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]methyl}-5H-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 1-(2-ethylsulfonylethyl)-3-[(2S)-1-methoxypropan-2-yl]urea —— C9H20N2O4S
    1-(2-ethylsulfonylethyl)-3-[(2S)-1-methoxypropan-2-yl]urea
    —— N-[(2S)-3-methylbutan-2-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C10H17N3OS2
    N-[(2S)-3-methylbutan-2-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(2S)-2-phenyl-2-pyrrolidin-1-ylethyl]-3-phenylsulfanylpropanamide —— C21H26N2OS
    N-[(2S)-2-phenyl-2-pyrrolidin-1-ylethyl]-3-phenylsulfanylpropanamide
    —— (2R)-N-cyclopropyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C9H13N3OS2
    (2R)-N-cyclopropyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 1-(2-ethylsulfonylethyl)-3-[(2R)-1-methoxypropan-2-yl]urea —— C9H20N2O4S
    1-(2-ethylsulfonylethyl)-3-[(2R)-1-methoxypropan-2-yl]urea
    —— (2S)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C6H9N3OS2
    (2S)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H21N3OS2
    (2S)-N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(2R)-2-phenyl-2-pyrrolidin-1-ylethyl]-3-phenylsulfanylpropanamide —— C21H26N2OS
    N-[(2R)-2-phenyl-2-pyrrolidin-1-ylethyl]-3-phenylsulfanylpropanamide
    —— N-(2-methoxyethyl)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C8H13N3O2S2
    N-(2-methoxyethyl)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H16FN3OS2
    (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— ethyl 2,5-dimethyl-4-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate —— C14H17N3O3S2
    ethyl 2,5-dimethyl-4-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate
    —— 2-[(2S)-2-(4-bromophenyl)sulfanylpropyl]guanidine —— C10H14BrN3S
    2-[(2S)-2-(4-bromophenyl)sulfanylpropyl]guanidine
    —— 2-[(2R)-2-(4-bromophenyl)sulfanylpropyl]guanidine —— C10H14BrN3S
    2-[(2R)-2-(4-bromophenyl)sulfanylpropyl]guanidine
    —— (2E,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(E)-furan-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C16H13F2N3O2S2
    (2E,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(E)-furan-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone —— C17H19N3OS
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(1-methylpyrazol-4-yl)pyrrolidin-1-yl]methanone