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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]butanoic acid —— C11H16N2O3S
    (2R)-2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]butanoic acid
    —— 2-(1-methylimidazol-2-yl)sulfanyl-1-[(3R)-3-phenyl-3,4-dihydropyrazol-2-yl]ethanone —— C15H16N4OS
    2-(1-methylimidazol-2-yl)sulfanyl-1-[(3R)-3-phenyl-3,4-dihydropyrazol-2-yl]ethanone
    —— (2R)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C9H11N2O3S-
    (2R)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— (2R)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C10H13N2O3S-
    (2R)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— 2-(1-methylimidazol-2-yl)sulfanyl-1-[(3S)-3-phenyl-3,4-dihydropyrazol-2-yl]ethanone —— C15H16N4OS
    2-(1-methylimidazol-2-yl)sulfanyl-1-[(3S)-3-phenyl-3,4-dihydropyrazol-2-yl]ethanone
    —— (2R)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoic acid —— C10H14N2O3S
    (2R)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoic acid
    —— (2S)-2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]butanoic acid —— C11H16N2O3S
    (2S)-2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]butanoic acid
    —— 2-[2-(4-methylpiperazin-4-ium-1-yl)-2-oxoethyl]sulfanyl-4-propan-2-yl-1H-pyrimidin-6-one —— C14H23N4O2S+
    2-[2-(4-methylpiperazin-4-ium-1-yl)-2-oxoethyl]sulfanyl-4-propan-2-yl-1H-pyrimidin-6-one
    —— (2R)-2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]propanoic acid —— C10H14N2O3S
    (2R)-2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]propanoic acid
    —— (2R)-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)-1,4-dioxane-2-carboxamide —— C15H15N3O3S
    (2R)-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)-1,4-dioxane-2-carboxamide
    —— 5-[(2R)-butan-2-yl]sulfanyl-1,3,4-thiadiazol-2-amine —— C6H11N3S2
    5-[(2R)-butan-2-yl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— (2S)-2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]propanoic acid —— C10H14N2O3S
    (2S)-2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]propanoic acid
    —— 2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]acetate —— C9H11N2O3S-
    2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]acetate
    —— 1-[(2R)-2-ethylhexyl]-3-(2-methylsulfonylethyl)urea —— C12H26N2O3S
    1-[(2R)-2-ethylhexyl]-3-(2-methylsulfonylethyl)urea
    —— (2S)-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)-1,4-dioxane-2-carboxamide —— C15H15N3O3S
    (2S)-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)-1,4-dioxane-2-carboxamide
    —— 1-[(2R)-heptan-2-yl]-3-(2-methylsulfonylethyl)urea —— C11H24N2O3S
    1-[(2R)-heptan-2-yl]-3-(2-methylsulfonylethyl)urea
    —— 4-Amino-3-benzylsulfanyl-6-tert-butyl-1,2,4-triazin-5-one —— C14H18N4OS
    4-Amino-3-benzylsulfanyl-6-tert-butyl-1,2,4-triazin-5-one
    —— 1-(5-Methylisoxazol-3-yl)-3-(3-(phenylthio)propyl)urea —— C14H17N3O2S
    1-(5-Methylisoxazol-3-yl)-3-(3-(phenylthio)propyl)urea
    —— 2-((3-Methylbenzyl)thio)-5-(pyridin-4-yl)-1,3,4-oxadiazole —— C15H13N3OS
    2-((3-Methylbenzyl)thio)-5-(pyridin-4-yl)-1,3,4-oxadiazole
    —— 1-(5-Methylisoxazol-3-yl)-3-(3-((4-methylthiazol-2-yl)thio)propyl)urea —— C12H16N4O2S2
    1-(5-Methylisoxazol-3-yl)-3-(3-((4-methylthiazol-2-yl)thio)propyl)urea
    —— 1-(5-Methylisoxazol-3-yl)-3-(3-(pyrimidin-2-ylthio)propyl)urea —— C12H15N5O2S
    1-(5-Methylisoxazol-3-yl)-3-(3-(pyrimidin-2-ylthio)propyl)urea
    —— 1-(3-((4-Methylthiazol-2-yl)thio)propyl)-3-(pyrimidin-2-yl)urea —— C12H15N5OS2
    1-(3-((4-Methylthiazol-2-yl)thio)propyl)-3-(pyrimidin-2-yl)urea
    —— N,N-diisopropyl-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetamide —— C15H20N4O2S
    N,N-diisopropyl-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetamide
    —— 1-[3-(4-Methylpyrimidin-2-yl)sulfanylpropyl]-3-pyrimidin-2-ylurea —— C13H16N6OS
    1-[3-(4-Methylpyrimidin-2-yl)sulfanylpropyl]-3-pyrimidin-2-ylurea
    —— 3-propan-2-yl-5-[(1S)-1-[1-(2,2,2-trifluoroethyl)tetrazol-5-yl]sulfanylethyl]-1,2,4-oxadiazole —— C10H13F3N6OS
    3-propan-2-yl-5-[(1S)-1-[1-(2,2,2-trifluoroethyl)tetrazol-5-yl]sulfanylethyl]-1,2,4-oxadiazole
    —— 1-(3-((5-Methyl-1,3,4-thiadiazol-2-yl)thio)propyl)-3-(pyrimidin-2-yl)urea —— C11H14N6OS2
    1-(3-((5-Methyl-1,3,4-thiadiazol-2-yl)thio)propyl)-3-(pyrimidin-2-yl)urea
    —— 1-(3-Pyrimidin-2-ylsulfanylpropyl)-3-(1,3-thiazol-2-yl)urea —— C11H13N5OS2
    1-(3-Pyrimidin-2-ylsulfanylpropyl)-3-(1,3-thiazol-2-yl)urea
    —— N-[(4-methylphenyl)methyl]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C17H16N4O2S
    N-[(4-methylphenyl)methyl]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-(4-fluorobenzyl)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetamide —— C16H13FN4O2S
    N-(4-fluorobenzyl)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetamide
    —— 1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C15H18N4O3S
    1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— N-[(1S)-1-cyano-3-methylbutyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C14H20N4OS
    N-[(1S)-1-cyano-3-methylbutyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— 5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2,2,2-trifluoroethyl)tetrazole —— C11H10F4N4S
    5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2,2,2-trifluoroethyl)tetrazole
    —— 3-(4-Methyl-1,3-thiazol-2-YL)-1-[3-(pyrimidin-2-ylsulfanyl)propyl]urea —— C12H15N5OS2
    3-(4-Methyl-1,3-thiazol-2-YL)-1-[3-(pyrimidin-2-ylsulfanyl)propyl]urea
    —— 3-propan-2-yl-5-[(1R)-1-[1-(2,2,2-trifluoroethyl)tetrazol-5-yl]sulfanylethyl]-1,2,4-oxadiazole —— C10H13F3N6OS
    3-propan-2-yl-5-[(1R)-1-[1-(2,2,2-trifluoroethyl)tetrazol-5-yl]sulfanylethyl]-1,2,4-oxadiazole
    —— 5-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2,2,2-trifluoroethyl)tetrazole —— C11H10F4N4S
    5-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2,2,2-trifluoroethyl)tetrazole
    —— 3-cyclopentylsulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C12H19N3O2S
    3-cyclopentylsulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— (2R)-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-3-methyl-2-phenylsulfanylbutanamide —— C17H22N4OS
    (2R)-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-3-methyl-2-phenylsulfanylbutanamide
    —— 3-cyclopentylsulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C12H19N3O2S
    3-cyclopentylsulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— N-[(1R)-1-cyano-3-methylbutyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C14H20N4OS
    N-[(1R)-1-cyano-3-methylbutyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (2S)-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-3-methyl-2-phenylsulfanylbutanamide —— C17H22N4OS
    (2S)-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-3-methyl-2-phenylsulfanylbutanamide
    —— 4-[(4-chlorophenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C19H17ClN2O2S
    4-[(4-chlorophenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one
    —— 4-(ethylthio)-1-(furan-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C14H16N2O2S
    4-(ethylthio)-1-(furan-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— 4-[(2,5-dimethylphenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C21H22N2O2S
    4-[(2,5-dimethylphenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one
    —— N-cyclohexyl-2-[[1-(furan-2-ylmethyl)-2-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]sulfanyl]acetamide —— C20H25N3O3S
    N-cyclohexyl-2-[[1-(furan-2-ylmethyl)-2-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]sulfanyl]acetamide
    —— 4-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C19H16ClFN2O2S
    4-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one
    —— 4-[2-(azepan-1-yl)-2-oxoethyl]sulfanyl-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C20H25N3O3S
    4-[2-(azepan-1-yl)-2-oxoethyl]sulfanyl-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one
    —— N-benzyl-2-((1-(furan-2-ylmethyl)-2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide —— C21H21N3O3S
    N-benzyl-2-((1-(furan-2-ylmethyl)-2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide
    —— 4-[(2-fluorophenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C19H17FN2O2S
    4-[(2-fluorophenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one
    —— 2-((1-(furan-2-ylmethyl)-2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)-N-phenethylacetamide —— C22H23N3O3S
    2-((1-(furan-2-ylmethyl)-2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)-N-phenethylacetamide
    —— 4-[(2-chlorophenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one —— C19H17ClN2O2S
    4-[(2-chlorophenyl)methylsulfanyl]-1-(furan-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-2-one