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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Ethyl 4-(1,4,5-trimethyl-6-oxopyrimidin-2-yl)sulfanylbutanoate —— C13H20N2O3S
    Ethyl 4-(1,4,5-trimethyl-6-oxopyrimidin-2-yl)sulfanylbutanoate
    —— N-benzyl-N-ethyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H18N4O2S
    N-benzyl-N-ethyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C19H17N5O3S
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— N-cycloheptyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C16H20N4O2S
    N-cycloheptyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-methyl-N-[(2-methylphenyl)methyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H18N4O2S
    N-methyl-N-[(2-methylphenyl)methyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-phenethyl-2-((5-(pyridin-3-yl)-1,3,4-oxadiazol-2-yl)thio)acetamide —— C17H16N4O2S
    N-phenethyl-2-((5-(pyridin-3-yl)-1,3,4-oxadiazol-2-yl)thio)acetamide
    —— [(2R)-oxolan-2-yl]methyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H19N3O4S
    [(2R)-oxolan-2-yl]methyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (2S)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C20H26N4S2
    (2S)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— N-[2-(4-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20ClN3O2S
    N-[2-(4-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C20H26N4S2
    (2R)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— [(2R)-oxolan-2-yl]methyl 2-(4-methylphenyl)sulfanylacetate —— C14H18O3S
    [(2R)-oxolan-2-yl]methyl 2-(4-methylphenyl)sulfanylacetate
    —— (2R)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C20H26N4S2
    (2R)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— ethyl 5-[2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C21H23N3O4S
    ethyl 5-[2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— [(2S)-oxan-2-yl]methyl 2-phenylsulfanylacetate —— C14H18O3S
    [(2S)-oxan-2-yl]methyl 2-phenylsulfanylacetate
    —— (2S)-N-[(1S)-1-(2-bromophenyl)ethyl]-2-phenylsulfanylpropanamide —— C17H18BrNOS
    (2S)-N-[(1S)-1-(2-bromophenyl)ethyl]-2-phenylsulfanylpropanamide
    —— (2S)-N-[(1R)-1-(2-bromophenyl)ethyl]-2-phenylsulfanylpropanamide —— C17H18BrNOS
    (2S)-N-[(1R)-1-(2-bromophenyl)ethyl]-2-phenylsulfanylpropanamide
    —— (2R)-N-[(1S)-1-(2-bromophenyl)ethyl]-2-phenylsulfanylpropanamide —— C17H18BrNOS
    (2R)-N-[(1S)-1-(2-bromophenyl)ethyl]-2-phenylsulfanylpropanamide
    —— 3-pyridin-3-ylpropyl 4-phenylsulfanylbutanoate —— C18H21NO2S
    3-pyridin-3-ylpropyl 4-phenylsulfanylbutanoate
    —— (2R)-N-[(1R)-1-(2-bromophenyl)ethyl]-2-phenylsulfanylpropanamide —— C17H18BrNOS
    (2R)-N-[(1R)-1-(2-bromophenyl)ethyl]-2-phenylsulfanylpropanamide
    —— (2S)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C20H26N4S2
    (2S)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— 2-[[3-(4-fluorophenyl)-[1,2]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C20H21FN4OS2
    2-[[3-(4-fluorophenyl)-[1,2]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— 2-[[3-(4-fluorophenyl)-[1,2]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide —— C20H21FN4OS2
    2-[[3-(4-fluorophenyl)-[1,2]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide
    —— 2-[[3-(4-fluorophenyl)-[1,2]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C20H21FN4OS2
    2-[[3-(4-fluorophenyl)-[1,2]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— [(1S,3S)-3-methoxycyclohexyl] 3-phenylsulfanylpropanoate —— C16H22O3S
    [(1S,3S)-3-methoxycyclohexyl] 3-phenylsulfanylpropanoate
    —— [(1R,3S)-3-methoxycyclohexyl] 3-phenylsulfanylpropanoate —— C16H22O3S
    [(1R,3S)-3-methoxycyclohexyl] 3-phenylsulfanylpropanoate
    —— [(1S,3R)-3-methoxycyclohexyl] 3-phenylsulfanylpropanoate —— C16H22O3S
    [(1S,3R)-3-methoxycyclohexyl] 3-phenylsulfanylpropanoate
    —— [(1R,3R)-3-methoxycyclohexyl] 3-phenylsulfanylpropanoate —— C16H22O3S
    [(1R,3R)-3-methoxycyclohexyl] 3-phenylsulfanylpropanoate
    —— [(2S,6S)-2,6-dimethylmorpholin-4-yl]-[2-(2,4-dimethylphenyl)sulfanylpyridin-3-yl]methanone —— C20H24N2O2S
    [(2S,6S)-2,6-dimethylmorpholin-4-yl]-[2-(2,4-dimethylphenyl)sulfanylpyridin-3-yl]methanone
    —— [(2S,6R)-2,6-dimethylmorpholin-4-yl]-[2-(2,4-dimethylphenyl)sulfanylpyridin-3-yl]methanone —— C20H24N2O2S
    [(2S,6R)-2,6-dimethylmorpholin-4-yl]-[2-(2,4-dimethylphenyl)sulfanylpyridin-3-yl]methanone
    —— [2-(4-bromophenyl)sulfanylpyridin-3-yl]-[(2S,6S)-2,6-dimethylmorpholin-4-yl]methanone —— C18H19BrN2O2S
    [2-(4-bromophenyl)sulfanylpyridin-3-yl]-[(2S,6S)-2,6-dimethylmorpholin-4-yl]methanone
    —— [2-(4-bromophenyl)sulfanylpyridin-3-yl]-[(2R,6S)-2,6-dimethylmorpholin-4-yl]methanone —— C18H19BrN2O2S
    [2-(4-bromophenyl)sulfanylpyridin-3-yl]-[(2R,6S)-2,6-dimethylmorpholin-4-yl]methanone
    —— [(2R,6R)-2,6-dimethylmorpholin-4-yl]-[2-(2,4-dimethylphenyl)sulfanylpyridin-3-yl]methanone —— C20H24N2O2S
    [(2R,6R)-2,6-dimethylmorpholin-4-yl]-[2-(2,4-dimethylphenyl)sulfanylpyridin-3-yl]methanone
    —— [2-(4-bromophenyl)sulfanylpyridin-3-yl]-[(2R,6R)-2,6-dimethylmorpholin-4-yl]methanone —— C18H19BrN2O2S
    [2-(4-bromophenyl)sulfanylpyridin-3-yl]-[(2R,6R)-2,6-dimethylmorpholin-4-yl]methanone
    —— N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H26N4OS2
    N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— ethyl (2R)-2-[1,4-dimethyl-5-[(2-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylpropanoate —— C19H24N2O3S
    ethyl (2R)-2-[1,4-dimethyl-5-[(2-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylpropanoate
    —— 2-[[4-(2-Methoxyethyl)-5-propyl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C10H16N3O3S-
    2-[[4-(2-Methoxyethyl)-5-propyl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 1-[(1R)-1-(furan-2-yl)ethyl]-1-methyl-3-(2-phenylsulfanylethyl)urea —— C16H20N2O2S
    1-[(1R)-1-(furan-2-yl)ethyl]-1-methyl-3-(2-phenylsulfanylethyl)urea
    —— 1-[(1S)-1-(furan-2-yl)ethyl]-1-methyl-3-(2-phenylsulfanylethyl)urea —— C16H20N2O2S
    1-[(1S)-1-(furan-2-yl)ethyl]-1-methyl-3-(2-phenylsulfanylethyl)urea
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]propanamide —— C13H18ClNO2S
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]propanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]propanamide —— C13H18ClNO2S
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]propanamide
    —— (2S)-N-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methyl]-2-phenylsulfanyl-N-propan-2-ylpropanamide —— C21H22ClN3O2S
    (2S)-N-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methyl]-2-phenylsulfanyl-N-propan-2-ylpropanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]propanamide —— C13H18ClNO2S
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]propanamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]propanamide —— C13H18ClNO2S
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]propanamide
    —— Ethyl 2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylacetate —— C17H19FN2O3S
    Ethyl 2-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylacetate
    —— 1-[(1S)-1-(4-methylsulfanylphenyl)ethyl]-3-[2-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)ethyl]urea —— C17H24N4O2S
    1-[(1S)-1-(4-methylsulfanylphenyl)ethyl]-3-[2-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)ethyl]urea
    —— 1-[(2S)-1-imidazol-1-ylpropan-2-yl]-3-[(1-phenylsulfanylcyclopropyl)methyl]urea —— C17H22N4OS
    1-[(2S)-1-imidazol-1-ylpropan-2-yl]-3-[(1-phenylsulfanylcyclopropyl)methyl]urea
    —— 1-[(2R)-1-imidazol-1-ylpropan-2-yl]-3-[(1-phenylsulfanylcyclopropyl)methyl]urea —— C17H22N4OS
    1-[(2R)-1-imidazol-1-ylpropan-2-yl]-3-[(1-phenylsulfanylcyclopropyl)methyl]urea
    —— 2-[(4-Chlorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(2-methylphenyl)methyl]pyrimidin-4-one —— C21H21ClN2OS
    2-[(4-Chlorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(2-methylphenyl)methyl]pyrimidin-4-one
    —— 3-(4-chlorophenyl)sulfanyl-N-[(2R)-2-(4-fluorophenyl)-2-morpholin-4-ylethyl]propanamide —— C21H24ClFN2O2S
    3-(4-chlorophenyl)sulfanyl-N-[(2R)-2-(4-fluorophenyl)-2-morpholin-4-ylethyl]propanamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[(2S)-2-(4-fluorophenyl)-2-morpholin-4-ylethyl]propanamide —— C21H24ClFN2O2S
    3-(4-chlorophenyl)sulfanyl-N-[(2S)-2-(4-fluorophenyl)-2-morpholin-4-ylethyl]propanamide