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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(4-amino-2-bromobenzyl)thio]-4H-1,2,4-triazol-4-amine —— C9H10BrN5S
    3-[(4-amino-2-bromobenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— 3-[(4-amino-2-bromobenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine —— C10H9BrF3N5S
    3-[(4-amino-2-bromobenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine
    —— 3-[(4-amino-2-bromobenzyl)thio]-5-methyl-4H-1,2,4-triazol-4-amine —— C10H12BrN5S
    3-[(4-amino-2-bromobenzyl)thio]-5-methyl-4H-1,2,4-triazol-4-amine
    —— (3-bromo-4-{[(5-ethyl-4H-1,2,4-triazol-3-yl)thio]methyl}phenyl)amine —— C11H13BrN4S
    (3-bromo-4-{[(5-ethyl-4H-1,2,4-triazol-3-yl)thio]methyl}phenyl)amine
    —— 3-[(4-amino-2-bromobenzyl)thio]-5-ethyl-4H-1,2,4-triazol-4-amine —— C11H14BrN5S
    3-[(4-amino-2-bromobenzyl)thio]-5-ethyl-4H-1,2,4-triazol-4-amine
    —— 2-(3-chloropyrazin-2-yl)sulfanyl-N,N-dimethylbenzamide —— C13H12ClN3OS
    2-(3-chloropyrazin-2-yl)sulfanyl-N,N-dimethylbenzamide
    —— (4S)-N,N,6-trimethyl-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyrimidine-5-carboxamide —— C15H19N3O2S
    (4S)-N,N,6-trimethyl-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyrimidine-5-carboxamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide —— C15H17FN4O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H15FN4O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H15FN4O3S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide —— C15H17FN4O3S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-tert-butylacetamide —— C16H29N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-tert-butylacetamide
    —— 2-[[4-Amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C12H19N5S
    2-[[4-Amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-benzylacetamide —— C19H27N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-benzylacetamide
    —— (2S)-2-(3,4-difluorophenyl)sulfanyl-N-[(2R)-pentan-2-yl]propanamide —— C14H19F2NOS
    (2S)-2-(3,4-difluorophenyl)sulfanyl-N-[(2R)-pentan-2-yl]propanamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylethyl)acetamide —— C20H29N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylethyl)acetamide
    —— 2-[[4-Amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C21H28N6OS
    2-[[4-Amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylacetamide —— C14H25N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylacetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide —— C19H26FN5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide
    —— (2R)-N-(2-methylbutan-2-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H20N4OS2
    (2R)-N-(2-methylbutan-2-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopentylacetamide —— C17H29N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopentylacetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-benzyl-N-methylacetamide —— C20H29N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-benzyl-N-methylacetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide —— C19H33N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylacetamide —— C18H31N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylacetamide
    —— methyl (2S)-2-phenyl-3-phenylsulfanylpropanoate —— C16H16O2S
    methyl (2S)-2-phenyl-3-phenylsulfanylpropanoate
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C14H22F3N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— 3-(2-Cyclohexylethyl)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C19H24N6OS
    3-(2-Cyclohexylethyl)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— N-hydroxy-N-[(1S)-1-phenyl-2-phenylsulfanylethyl]formamide —— C15H15NO2S
    N-hydroxy-N-[(1S)-1-phenyl-2-phenylsulfanylethyl]formamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propylacetamide —— C15H27N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propylacetamide
    —— (2R)-2-(3,4-difluorophenyl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide —— C14H19F2NOS
    (2R)-2-(3,4-difluorophenyl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide
    —— N-hydroxy-N-[(1R)-1-phenyl-2-phenylsulfanylethyl]formamide —— C15H15NO2S
    N-hydroxy-N-[(1R)-1-phenyl-2-phenylsulfanylethyl]formamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-(3-chlorophenyl)ethyl]acetamide —— C20H28ClN5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-(3-chlorophenyl)ethyl]acetamide
    —— (2R)-2-(3,4-difluorophenyl)sulfanyl-N-[(2R)-pentan-2-yl]propanamide —— C14H19F2NOS
    (2R)-2-(3,4-difluorophenyl)sulfanyl-N-[(2R)-pentan-2-yl]propanamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-chlorophenyl)methyl]acetamide —— C19H26ClN5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-chlorophenyl)methyl]acetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C20H29N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— (2S)-2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C13H21N5S
    (2S)-2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— N-(1-adamantylmethyl)-2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C23H37N5OS
    N-(1-adamantylmethyl)-2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C15H27N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C19H33N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C19H33N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— (2R)-2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylpropanamide —— C16H27N5OS
    (2R)-2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylpropanamide
    —— (2R)-2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C13H21N5S
    (2R)-2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylacetamide —— C15H25N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylacetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylpropyl)acetamide —— C16H29N5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylpropyl)acetamide
    —— (2S)-1-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol —— C16H23N4O2S2+
    (2S)-1-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol
    —— (2S)-3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-methylpropanenitrile —— C13H14N4S2
    (2S)-3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-methylpropanenitrile
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)propanamide —— C17H20ClN3O2S
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethyl-N-(2-methylprop-2-enyl)propanamide
    —— (2S)-1-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ylpropan-2-ol —— C16H22N4O2S2
    (2S)-1-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ylpropan-2-ol
    —— (2S)-2-(3,4-difluorophenyl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide —— C14H19F2NOS
    (2S)-2-(3,4-difluorophenyl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide
    —— methyl (2R)-2-phenyl-3-phenylsulfanylpropanoate —— C16H16O2S
    methyl (2R)-2-phenyl-3-phenylsulfanylpropanoate