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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C15H17FN2OS2
    (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— 2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(1-cyanocyclopentyl)acetamide —— C16H15BrN4O2S
    2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(1-cyanocyclopentyl)acetamide
    —— 2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C14H10BrN3O2S
    2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C15H16BrN3O2S
    (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylpropanamide —— C16H18BrN3O2S
    (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopentylpropanamide
    —— (2R)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(methylcarbamoyl)propanamide —— C13H13BrN4O3S
    (2R)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(methylcarbamoyl)propanamide
    —— (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C15H17FN2OS2
    (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— 2-(2-Bromophenyl)-5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazole —— C16H13BrN2OS
    2-(2-Bromophenyl)-5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazole
    —— 1-{2-[5-(2-Bromophenyl)-1,3,4-oxadiazol-2-ylthio]acetyl}pyrrolidin-2-one —— C14H12BrN3O3S
    1-{2-[5-(2-Bromophenyl)-1,3,4-oxadiazol-2-ylthio]acetyl}pyrrolidin-2-one
    —— (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C11H8BrN3OS
    (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H22N2OS2
    N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 2-(2-chlorophenyl)sulfanyl-N-ethyl-N-[(2R)-1-methylsulfonylpropan-2-yl]acetamide —— C14H20ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-ethyl-N-[(2R)-1-methylsulfonylpropan-2-yl]acetamide
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C12H15N3OS2
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-cyclopentyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C12H18N2OS2
    (2R)-N-cyclopentyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C7H10N2OS2
    (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide —— C13H19N3OS2
    (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide
    —— N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H22N2OS2
    N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-cyclopropyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C9H12N2OS2
    N-cyclopropyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C15H17FN2OS2
    (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— methyl 2,4-dimethyl-5-[(2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C15H18N2O3S2
    methyl 2,4-dimethyl-5-[(2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— N-(1-cyanocyclohexyl)-N-methyl-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C12H16N4OS2
    N-(1-cyanocyclohexyl)-N-methyl-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C11H16N2O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-(2-phenylethyl)acetamide —— C14H16N2OS2
    2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-(2-phenylethyl)acetamide
    —— (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C15H17FN2OS2
    (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— ethyl 2,4-dimethyl-5-[(2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C16H20N2O3S2
    ethyl 2,4-dimethyl-5-[(2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H22N2OS2
    N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-(4-methylcyclohexyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C13H20N2OS2
    N-(4-methylcyclohexyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— ethyl 2,5-dimethyl-4-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate —— C15H18N2O3S2
    ethyl 2,5-dimethyl-4-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate
    —— 2-((1,3,4-Thiadiazol-2-yl)thio)-1-(1h-pyrrol-2-yl)ethan-1-one —— C8H7N3OS2
    2-((1,3,4-Thiadiazol-2-yl)thio)-1-(1h-pyrrol-2-yl)ethan-1-one
    —— methyl 2,4-dimethyl-5-[(2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C15H18N2O3S2
    methyl 2,4-dimethyl-5-[(2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— 2-(2-chlorophenyl)sulfanyl-N-ethyl-N-[(2S)-1-methylsulfonylpropan-2-yl]acetamide —— C14H20ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-ethyl-N-[(2S)-1-methylsulfonylpropan-2-yl]acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C11H16N2O3S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide —— C16H20N2OS2
    2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide
    —— (2R)-N-(furan-2-ylmethyl)-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide —— C10H11N3O2S2
    (2R)-N-(furan-2-ylmethyl)-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide
    —— N-(2-methoxyethyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C9H14N2O2S2
    N-(2-methoxyethyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— [(1S)-1-(5-ethylsulfanyl-1,3,4-oxadiazol-2-yl)ethyl]azanium —— C6H12N3OS+
    [(1S)-1-(5-ethylsulfanyl-1,3,4-oxadiazol-2-yl)ethyl]azanium
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C18H26N2OS2
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-(furan-2-ylmethyl)-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C9H9N3O2S2
    N-(furan-2-ylmethyl)-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— [(1S)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylbutyl]azanium —— C14H19FN3OS+
    [(1S)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylbutyl]azanium
    —— [(1S)-1-[5-(2-methylprop-2-enylsulfanyl)-1,3,4-oxadiazol-2-yl]ethyl]azanium —— C8H14N3OS+
    [(1S)-1-[5-(2-methylprop-2-enylsulfanyl)-1,3,4-oxadiazol-2-yl]ethyl]azanium
    —— (2R)-N-[[(1R,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide —— C17H26N4OS
    (2R)-N-[[(1R,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide
    —— 4-(2-methoxyethyl)-3-[(1S)-2,2,2-trifluoro-1-phenylethyl]sulfanyl-1,2,4-triazole —— C13H14F3N3OS
    4-(2-methoxyethyl)-3-[(1S)-2,2,2-trifluoro-1-phenylethyl]sulfanyl-1,2,4-triazole
    —— 4-(2-methoxyethyl)-3-[(1R)-2,2,2-trifluoro-1-phenylethyl]sulfanyl-1,2,4-triazole —— C13H14F3N3OS
    4-(2-methoxyethyl)-3-[(1R)-2,2,2-trifluoro-1-phenylethyl]sulfanyl-1,2,4-triazole
    —— [(1S)-1-[5-[(3-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethyl]azanium —— C11H13FN3OS+
    [(1S)-1-[5-[(3-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethyl]azanium
    —— N-[(1S)-1-cyclopropylethyl]-2-[(5-cyclopropyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C14H19F3N4OS
    N-[(1S)-1-cyclopropylethyl]-2-[(5-cyclopropyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— 5-Benzyl-2-ethylsulfanyl-3,6-dimethylpyrimidin-4-one —— C15H18N2OS
    5-Benzyl-2-ethylsulfanyl-3,6-dimethylpyrimidin-4-one
    —— 2-[(4-Chlorophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one —— C15H17ClN2OS
    2-[(4-Chlorophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one
    —— 2-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanyl-N,N-bis(prop-2-enyl)acetamide —— C21H25N3O2S
    2-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanyl-N,N-bis(prop-2-enyl)acetamide
    —— Ethyl 4-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylbutanoate —— C19H23FN2O3S
    Ethyl 4-[5-[(4-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylbutanoate
    —— [(2S)-1-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)methyl]pyrrolidin-2-yl]methanol —— C9H15N3OS2
    [(2S)-1-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)methyl]pyrrolidin-2-yl]methanol