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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylacetamide —— C15H20N4O2S
    2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylacetamide
    —— Methyl 3-[2,5-dimethyl-3-[2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetyl]pyrrol-1-yl]propanoate —— C17H20N2O4S
    Methyl 3-[2,5-dimethyl-3-[2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetyl]pyrrol-1-yl]propanoate
    —— N-tert-butyl-2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H24N4O2S
    N-tert-butyl-2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-N-propan-2-yl-1,3,4-thiadiazol-2-amine —— C12H13BrFN3S2
    5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-N-propan-2-yl-1,3,4-thiadiazol-2-amine
    —— 5-[2-(4-Chlorophenyl)sulfanylethylsulfanyl]-1,3,4-thiadiazol-2-amine —— C10H10ClN3S3
    5-[2-(4-Chlorophenyl)sulfanylethylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C18H29N5OS2
    2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— [(1R)-1-[4-butyl-5-[2-oxo-2-(thiophen-2-ylmethylamino)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C18H30N5OS2+
    [(1R)-1-[4-butyl-5-[2-oxo-2-(thiophen-2-ylmethylamino)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-butyl-5-[2-oxo-2-(thiophen-2-ylmethylamino)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C18H30N5OS2+
    [(1S)-1-[4-butyl-5-[2-oxo-2-(thiophen-2-ylmethylamino)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 4-[[4-Methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-5-phenylthieno[2,3-d]pyrimidine —— C16H10F3N5S2
    4-[[4-Methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-5-phenylthieno[2,3-d]pyrimidine
    —— 1-[2,5-Dimethyl-1-(2,2,2-trifluoroethyl)pyrrol-3-yl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)ethanone —— C12H12F3N3OS2
    1-[2,5-Dimethyl-1-(2,2,2-trifluoroethyl)pyrrol-3-yl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)ethanone
    —— 2-(4-chlorophenyl)sulfanylethyl 4-[(1R)-1-hydroxyethyl]-3,5-dimethyl-1H-pyrrole-2-carboxylate —— C17H20ClNO3S
    2-(4-chlorophenyl)sulfanylethyl 4-[(1R)-1-hydroxyethyl]-3,5-dimethyl-1H-pyrrole-2-carboxylate
    —— 2-(Furan-2-yl)-5-[3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propylsulfanyl]-1,3,4-oxadiazole —— C15H12N4O4S2
    2-(Furan-2-yl)-5-[3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propylsulfanyl]-1,3,4-oxadiazole
    —— N-[2-(4-methylphenyl)sulfanylethyl]-2-[(5-nitro-6-oxo-1H-pyrimidin-4-yl)oxy]acetamide —— C15H16N4O5S
    N-[2-(4-methylphenyl)sulfanylethyl]-2-[(5-nitro-6-oxo-1H-pyrimidin-4-yl)oxy]acetamide
    —— 2-[(5-nitro-6-oxo-1H-pyrimidin-4-yl)oxy]-N-(2-phenylsulfanylethyl)acetamide —— C14H14N4O5S
    2-[(5-nitro-6-oxo-1H-pyrimidin-4-yl)oxy]-N-(2-phenylsulfanylethyl)acetamide
    —— (5S)-N-[2-(4-chlorophenyl)sulfanylethyl]-5-methyl-4,5-dihydro-1,3-thiazol-2-amine —— C12H15ClN2S2
    (5S)-N-[2-(4-chlorophenyl)sulfanylethyl]-5-methyl-4,5-dihydro-1,3-thiazol-2-amine
    —— N-[4-(2,4-dimethylphenyl)sulfanylphenyl]-2-(2-oxo-1,3-thiazolidin-3-yl)acetamide —— C19H20N2O2S2
    N-[4-(2,4-dimethylphenyl)sulfanylphenyl]-2-(2-oxo-1,3-thiazolidin-3-yl)acetamide
    —— 2-(1-adamantyl)-N'-[2-(4-fluorophenyl)sulfanylacetyl]acetohydrazide —— C20H25FN2O2S
    2-(1-adamantyl)-N'-[2-(4-fluorophenyl)sulfanylacetyl]acetohydrazide
    —— N-[2-(furan-2-ylmethylsulfanyl)ethyl]-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide —— C20H20N2O2S2
    N-[2-(furan-2-ylmethylsulfanyl)ethyl]-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide
    —— 2-(benzotriazol-1-yl)-N-(2-phenylsulfanylphenyl)acetamide —— C20H16N4OS
    2-(benzotriazol-1-yl)-N-(2-phenylsulfanylphenyl)acetamide
    —— N-[(Z)-(2-phenylsulfanylphenyl)methylideneamino]-2-(4-propylphenoxy)acetamide —— C24H24N2O2S
    N-[(Z)-(2-phenylsulfanylphenyl)methylideneamino]-2-(4-propylphenoxy)acetamide
    —— (8R)-7-(4-chlorophenyl)-3,8-dimethyl-8H-[1,2,4]triazino[3,4-b][1,3,4]thiadiazin-4-one —— C13H11ClN4OS
    (8R)-7-(4-chlorophenyl)-3,8-dimethyl-8H-[1,2,4]triazino[3,4-b][1,3,4]thiadiazin-4-one
    —— (8S)-7-(4-chlorophenyl)-3,8-dimethyl-8H-[1,2,4]triazino[3,4-b][1,3,4]thiadiazin-4-one —— C13H11ClN4OS
    (8S)-7-(4-chlorophenyl)-3,8-dimethyl-8H-[1,2,4]triazino[3,4-b][1,3,4]thiadiazin-4-one
    —— 2-[(3aR,7aS)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-(2-phenylsulfanylphenyl)acetamide —— C22H22N2O3S
    2-[(3aR,7aS)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-(2-phenylsulfanylphenyl)acetamide
    —— 3-([1,2,4]Triazolo[4,3-a]pyridin-3-ylsulfanyl)-8-thia-4,6-diazatricyclo[7.5.0.02,7]tetradeca-1(9),2(7),3,5-tetraene —— C17H15N5S2
    3-([1,2,4]Triazolo[4,3-a]pyridin-3-ylsulfanyl)-8-thia-4,6-diazatricyclo[7.5.0.02,7]tetradeca-1(9),2(7),3,5-tetraene
    —— N-[(Z)-[5-(2,4-dinitrophenyl)sulfanylfuran-2-yl]methylideneamino]-N-methylmethanamine —— C13H12N4O5S
    N-[(Z)-[5-(2,4-dinitrophenyl)sulfanylfuran-2-yl]methylideneamino]-N-methylmethanamine
    —— 4-Methyl-3,5-dinitro-2-phenylsulfanylpyridine —— C12H9N3O4S
    4-Methyl-3,5-dinitro-2-phenylsulfanylpyridine
    —— [2-(2,4-Dichlorophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H16Cl2NS+
    [2-(2,4-Dichlorophenyl)sulfanylphenyl]methyl-dimethylazanium
    —— 1-[2-(2,4-dichlorophenyl)sulfanylphenyl]-N,N-dimethylmethanamine —— C15H15Cl2NS
    1-[2-(2,4-dichlorophenyl)sulfanylphenyl]-N,N-dimethylmethanamine
    —— (5E)-5-(furan-2-ylmethylidene)-2,4-diiminothiolane-3-carbonitrile —— C10H7N3OS
    (5E)-5-(furan-2-ylmethylidene)-2,4-diiminothiolane-3-carbonitrile
    —— (NE)-N-[1-[2-[5-amino-6-(dimethylamino)pyrimidin-4-yl]sulfanyl-5-nitrophenyl]ethylidene]hydroxylamine —— C14H16N6O3S
    (NE)-N-[1-[2-[5-amino-6-(dimethylamino)pyrimidin-4-yl]sulfanyl-5-nitrophenyl]ethylidene]hydroxylamine
    —— 4-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine —— C19H24N6OS2
    4-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine
    —— N'-[3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoyl]-1H-pyrrole-2-carbohydrazide —— C15H19N5O2S
    N'-[3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[3-(4-fluorophenyl)sulfanylpropanoyl]-1H-pyrrole-2-carbohydrazide —— C14H14FN3O2S
    N'-[3-(4-fluorophenyl)sulfanylpropanoyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1H-pyrrole-2-carbohydrazide —— C17H18N6O2S
    N'-[2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[3-(3,4-difluorophenyl)sulfanylpropanoyl]-1H-pyrrole-2-carbohydrazide —— C14H13F2N3O2S
    N'-[3-(3,4-difluorophenyl)sulfanylpropanoyl]-1H-pyrrole-2-carbohydrazide
    —— N-benzyl-5-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C19H16FN5OS2
    N-benzyl-5-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C14H18N4OS2
    (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— N-benzyl-5-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C19H16FN5OS2
    N-benzyl-5-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N'-[2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]-1H-pyrrole-2-carbohydrazide —— C15H16N6O3S
    N'-[2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[2-(2-methylphenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide —— C14H15N3O2S
    N'-[2-(2-methylphenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide
    —— N-benzyl-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C14H17N3OS2
    N-benzyl-5-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N'-[2-(4-bromophenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide —— C13H12BrN3O2S
    N'-[2-(4-bromophenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[2-(4-fluorophenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide —— C13H12FN3O2S
    N'-[2-(4-fluorophenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-1H-pyrrole-2-carbohydrazide —— C15H12ClN5O3S
    N'-[2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[3-(4-chlorophenyl)sulfanylpropanoyl]-1H-pyrrole-2-carbohydrazide —— C14H14ClN3O2S
    N'-[3-(4-chlorophenyl)sulfanylpropanoyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[2-(4-bromo-2,5-dimethylphenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide —— C15H16BrN3O2S
    N'-[2-(4-bromo-2,5-dimethylphenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide
    —— [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2-cyanophenyl)sulfanylbenzoate —— C19H18N2O3S
    [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— [(2S)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2-cyanophenyl)sulfanylbenzoate —— C19H18N2O3S
    [(2S)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— N-[3-(cyclohexyloxy)propyl]-3-[4,6-dimethyl-2-(methylsulfanyl)pyrimidin-5-yl]propanamide —— C19H31N3O2S
    N-[3-(cyclohexyloxy)propyl]-3-[4,6-dimethyl-2-(methylsulfanyl)pyrimidin-5-yl]propanamide
    —— N-(3-cyclohexyloxypropyl)-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H28N4O3S
    N-(3-cyclohexyloxypropyl)-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide