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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-fluorophenyl)-5-[(1R)-1-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1,3,4-oxadiazole —— C16H11FN4O3S
    2-(4-fluorophenyl)-5-[(1R)-1-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1,3,4-oxadiazole
    —— (2R)-N,N-dimethyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C12H14N4O2S
    (2R)-N,N-dimethyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C19H22N4O2S
    (2R)-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— 2-(4-Chlorophenyl)sulfanylethyl 2,2-dioxo-3,4-dihydropyrido[2,1-c][1,2,4]thiadiazine-9-carboxylate —— C16H15ClN2O4S2
    2-(4-Chlorophenyl)sulfanylethyl 2,2-dioxo-3,4-dihydropyrido[2,1-c][1,2,4]thiadiazine-9-carboxylate
    —— (2R)-N-ethyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C12H14N4O2S
    (2R)-N-ethyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C13H14FN3O2S
    (2S)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— (2S)-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C19H22N4O2S
    (2S)-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— (2S)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-ethylpropanamide —— C14H17N3O2S
    (2S)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-ethylpropanamide
    —— (2S)-N-ethyl-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C13H14FN3O2S
    (2S)-N-ethyl-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-1-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol —— C17H25N4O2S2+
    (2R)-1-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol
    —— (2S)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C13H14FN3O2S
    (2S)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— (3S,4R)-4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1,1-dioxothiolan-3-ol —— C14H17N3O3S3
    (3S,4R)-4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1,1-dioxothiolan-3-ol
    —— (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C13H14FN3O2S
    (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— N-(4-ethylphenyl)-5-(2-pyridin-2-ylethylsulfanyl)-1,3,4-thiadiazol-2-amine —— C17H18N4S2
    N-(4-ethylphenyl)-5-(2-pyridin-2-ylethylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— (3R,4R)-4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1,1-dioxothiolan-3-ol —— C14H17N3O3S3
    (3R,4R)-4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1,1-dioxothiolan-3-ol
    —— (2S)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]pentanedinitrile —— C16H17N5S2
    (2S)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]pentanedinitrile
    —— [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate —— C14H19NO3S
    [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate
    —— (2S)-1-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol —— C17H25N4O2S2+
    (2S)-1-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol
    —— N-(4-ethylphenyl)-5-(2-pyridin-4-ylethylsulfanyl)-1,3,4-thiadiazol-2-amine —— C17H18N4S2
    N-(4-ethylphenyl)-5-(2-pyridin-4-ylethylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— Methyl 3-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C14H17N3O2S2
    Methyl 3-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— (3R,4S)-4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1,1-dioxothiolan-3-ol —— C14H17N3O3S3
    (3R,4S)-4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1,1-dioxothiolan-3-ol
    —— 3-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methyl-4-oxopentan-2-yl)propanamide —— C19H26N4O2S2
    3-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methyl-4-oxopentan-2-yl)propanamide
    —— (2R)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]pentanedinitrile —— C16H17N5S2
    (2R)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]pentanedinitrile
    —— (2S)-N,N-dimethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H15N3OS3
    (2S)-N,N-dimethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-ethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H15N3OS3
    (2S)-N-ethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C11H14N4OS2
    (2R)-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-(4-fluorophenyl)-5-[(1R)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole —— C16H12FN5OS2
    2-(4-fluorophenyl)-5-[(1R)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole
    —— (2R)-N,N-dimethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H15N3OS3
    (2R)-N,N-dimethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-3-phenyl-1,3,4-thiadiazole-2-thione —— C19H16N4OS3
    5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-3-phenyl-1,3,4-thiadiazole-2-thione
    —— (2R)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol —— C15H21N4O2S2+
    (2R)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol
    —— 2-(4-methylphenyl)-5-[(1S)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole —— C17H15N5OS2
    2-(4-methylphenyl)-5-[(1S)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole
    —— (3S,4R)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1,1-dioxothiolan-3-ol —— C12H13N3O3S3
    (3S,4R)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1,1-dioxothiolan-3-ol
    —— (2S)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]pentanedinitrile —— C14H13N5S2
    (2S)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]pentanedinitrile
    —— (2S)-N,N-dimethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C11H14N4OS2
    (2S)-N,N-dimethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (3S,4S)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1,1-dioxothiolan-3-ol —— C12H13N3O3S3
    (3S,4S)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1,1-dioxothiolan-3-ol
    —— (3R,4S)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1,1-dioxothiolan-3-ol —— C12H13N3O3S3
    (3R,4S)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1,1-dioxothiolan-3-ol
    —— (2S)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol —— C15H21N4O2S2+
    (2S)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-morpholin-4-ium-4-ylpropan-2-ol
    —— 2-(4-fluorophenyl)-5-[(1S)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole —— C16H12FN5OS2
    2-(4-fluorophenyl)-5-[(1S)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole
    —— (2S)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(thiophen-2-ylmethoxy)propan-2-ol —— C16H17N3O2S3
    (2S)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(thiophen-2-ylmethoxy)propan-2-ol
    —— (2R)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(thiophen-2-ylmethoxy)propan-2-ol —— C16H17N3O2S3
    (2R)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(thiophen-2-ylmethoxy)propan-2-ol
    —— (2R)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-morpholin-4-ylpropan-2-ol —— C15H20N4O2S2
    (2R)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-morpholin-4-ylpropan-2-ol
    —— (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]pentanedinitrile —— C14H13N5S2
    (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]pentanedinitrile
    —— (2R)-N,N-dimethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C11H14N4OS2
    (2R)-N,N-dimethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 3-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C11H12N4OS2
    3-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-phenyl-5-(2-pyridin-2-ylethylsulfanyl)-1,3,4-thiadiazol-2-amine —— C15H14N4S2
    N-phenyl-5-(2-pyridin-2-ylethylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— (3R,4R)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1,1-dioxothiolan-3-ol —— C12H13N3O3S3
    (3R,4R)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1,1-dioxothiolan-3-ol
    —— [(2R)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C18H23N3O3S2
    [(2R)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— (2R)-2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C14H17FN4OS
    (2R)-2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— (2S)-2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C14H17FN4OS
    (2S)-2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— [(2S)-1-(cycloheptylamino)-1-oxopropan-2-yl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C20H31N3O3S
    [(2S)-1-(cycloheptylamino)-1-oxopropan-2-yl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate