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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(1S)-1-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C12H11N3OS3
    2-[(1S)-1-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-benzyl-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C17H14N4O2S2
    2-benzyl-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-(2-fluorophenyl)-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H11FN4O2S2
    2-(2-fluorophenyl)-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H18N4O3S3
    N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-(4-chlorophenyl)-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H11ClN4O2S2
    2-(4-chlorophenyl)-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— 2-[(1S)-1-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C16H15N5OS3
    2-[(1S)-1-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-[(1S)-1-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C16H15N5O2S2
    2-[(1S)-1-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-(4-chlorophenyl)-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H11ClN4O2S2
    2-(4-chlorophenyl)-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— [(1R)-2-(dimethylamino)-2-oxo-1-phenylethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C24H20N2O3S
    [(1R)-2-(dimethylamino)-2-oxo-1-phenylethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— N-benzyl-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C17H15N5OS3
    N-benzyl-5-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 2-(2-chlorophenyl)sulfanyl-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C15H18ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(2-chlorophenyl)sulfanyl-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C15H18ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(1S)-1-(2-chlorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C14H11ClN2OS2
    2-[(1S)-1-(2-chlorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-[(1R)-1-(2-chlorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C14H11ClN2OS2
    2-[(1R)-1-(2-chlorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 4-[4-(2,5-Dimethylphenyl)sulfanyl-3-nitrophenyl]sulfonylmorpholine —— C18H20N2O5S2
    4-[4-(2,5-Dimethylphenyl)sulfanyl-3-nitrophenyl]sulfonylmorpholine
    —— 2-[(1S)-1-(4-chlorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C14H11ClN2OS2
    2-[(1S)-1-(4-chlorophenyl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H32N4OS2
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[[5-(butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[[1-[(3-chlorophenyl)methyl]pyrrol-2-yl]methyl]-2-phenylsulfanyl-N-prop-2-enylacetamide —— C23H23ClN2OS
    N-[[1-[(3-chlorophenyl)methyl]pyrrol-2-yl]methyl]-2-phenylsulfanyl-N-prop-2-enylacetamide
    —— ethyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propanoate —— C7H11N3O2S2
    ethyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propanoate
    —— ethyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propanoate —— C7H11N3O2S2
    ethyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propanoate
    —— (2S)-N-cyclopropyl-2-(1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanylpentanamide —— C14H21N3O2S
    (2S)-N-cyclopropyl-2-(1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanylpentanamide
    —— (2R)-N-cyclopropyl-2-(1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanylpentanamide —— C14H21N3O2S
    (2R)-N-cyclopropyl-2-(1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanylpentanamide
    —— (2R)-N-[(1S,3R)-3-ethoxyspiro[3.5]nonan-1-yl]-2-propan-2-ylsulfonylpropanamide —— C17H31NO4S
    (2R)-N-[(1S,3R)-3-ethoxyspiro[3.5]nonan-1-yl]-2-propan-2-ylsulfonylpropanamide
    —— (2R)-N-[(1R,3S)-3-ethoxyspiro[3.5]nonan-1-yl]-2-propan-2-ylsulfonylpropanamide —— C17H31NO4S
    (2R)-N-[(1R,3S)-3-ethoxyspiro[3.5]nonan-1-yl]-2-propan-2-ylsulfonylpropanamide
    —— (2R)-N-[(1S,3S)-3-ethoxyspiro[3.5]nonan-1-yl]-2-propan-2-ylsulfonylpropanamide —— C17H31NO4S
    (2R)-N-[(1S,3S)-3-ethoxyspiro[3.5]nonan-1-yl]-2-propan-2-ylsulfonylpropanamide
    —— 5-[(2,4-Difluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C9H7F2N3S2
    5-[(2,4-Difluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 5-[(2,5-Difluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C9H7F2N3S2
    5-[(2,5-Difluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2R)-N'-[2-(4-chlorophenyl)sulfanylacetyl]-2-methyl-3-(1,3,5-trimethylpyrazol-4-yl)propanehydrazide —— C18H23ClN4O2S
    (2R)-N'-[2-(4-chlorophenyl)sulfanylacetyl]-2-methyl-3-(1,3,5-trimethylpyrazol-4-yl)propanehydrazide
    —— (2S)-N'-[2-(4-chlorophenyl)sulfanylacetyl]-2-methyl-3-(1,3,5-trimethylpyrazol-4-yl)propanehydrazide —— C18H23ClN4O2S
    (2S)-N'-[2-(4-chlorophenyl)sulfanylacetyl]-2-methyl-3-(1,3,5-trimethylpyrazol-4-yl)propanehydrazide
    —— 5-[(3,5-Dimethylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C11H13N3S2
    5-[(3,5-Dimethylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-[(1S,5R,6R)-7,7-dimethyl-2-oxabicyclo[3.2.0]heptan-6-yl]-2-(4-methylphenyl)sulfanylacetamide —— C17H23NO2S
    N-[(1S,5R,6R)-7,7-dimethyl-2-oxabicyclo[3.2.0]heptan-6-yl]-2-(4-methylphenyl)sulfanylacetamide
    —— 2-(4-methylphenyl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]pyridine-3-carboxamide —— C23H24N2OS
    2-(4-methylphenyl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]pyridine-3-carboxamide
    —— N-[(1R)-1-(4-fluorophenyl)ethyl]-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide —— C21H19FN2OS
    N-[(1R)-1-(4-fluorophenyl)ethyl]-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide
    —— N-[(1S,5R,6S)-7,7-dimethyl-2-oxabicyclo[3.2.0]heptan-6-yl]-2-(4-methylphenyl)sulfanylacetamide —— C17H23NO2S
    N-[(1S,5R,6S)-7,7-dimethyl-2-oxabicyclo[3.2.0]heptan-6-yl]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(1S,5S,6S)-7,7-dimethyl-2-oxabicyclo[3.2.0]heptan-6-yl]-2-(4-methylphenyl)sulfanylacetamide —— C17H23NO2S
    N-[(1S,5S,6S)-7,7-dimethyl-2-oxabicyclo[3.2.0]heptan-6-yl]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(1S,5S,6R)-7,7-dimethyl-2-oxabicyclo[3.2.0]heptan-6-yl]-2-(4-methylphenyl)sulfanylacetamide —— C17H23NO2S
    N-[(1S,5S,6R)-7,7-dimethyl-2-oxabicyclo[3.2.0]heptan-6-yl]-2-(4-methylphenyl)sulfanylacetamide
    —— N-cycloheptyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H24N4OS2
    N-cycloheptyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-(3-methylphenyl)-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C17H15N5OS3
    N-(3-methylphenyl)-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 1-[4-(2,5-dimethylphenyl)sulfanylphenyl]-3-[[(2R)-oxolan-2-yl]methyl]thiourea —— C20H24N2OS2
    1-[4-(2,5-dimethylphenyl)sulfanylphenyl]-3-[[(2R)-oxolan-2-yl]methyl]thiourea
    —— 1-[4-(2,5-dimethylphenyl)sulfanylphenyl]-3-[[(2S)-oxolan-2-yl]methyl]thiourea —— C20H24N2OS2
    1-[4-(2,5-dimethylphenyl)sulfanylphenyl]-3-[[(2S)-oxolan-2-yl]methyl]thiourea
    —— 5-[(1-butyltetrazol-5-yl)methylsulfanyl]-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine —— C15H19N7S2
    5-[(1-butyltetrazol-5-yl)methylsulfanyl]-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— 3,3-Dimethyl-1-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]butan-2-one —— C14H16N2OS3
    3,3-Dimethyl-1-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]butan-2-one
    —— (2S)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C13H16N4OS2
    (2S)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-(4-butylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide —— C15H20N4OS2
    2-[[5-(4-butylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— (2R)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C13H16N4OS2
    (2R)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (1R,2R,3S)-2,3-dimethyl-N-[2-(4-methylphenyl)sulfanylethyl]-1-oxo-1,4-thiazinane-4-carboxamide —— C16H24N2O2S2
    (1R,2R,3S)-2,3-dimethyl-N-[2-(4-methylphenyl)sulfanylethyl]-1-oxo-1,4-thiazinane-4-carboxamide
    —— (1S,2S,3S)-2,3-dimethyl-N-[2-(4-methylphenyl)sulfanylethyl]-1-oxo-1,4-thiazinane-4-carboxamide —— C16H24N2O2S2
    (1S,2S,3S)-2,3-dimethyl-N-[2-(4-methylphenyl)sulfanylethyl]-1-oxo-1,4-thiazinane-4-carboxamide